A nitrogen liquefier configured to be integrated with an argon and nitrogen producing cryogenic air separation unit and method of nitrogen liquefaction are provided. The integrated nitrogen liquefier and associated methods may be operated in at least three distinct modes including: (i) a nil liquid nitrogen mode; (ii) a low liquid nitrogen mode; and (iii) a high liquid nitrogen mode. The present systems and methods are further characterized in an oxygen enriched stream from the lower pressure column of the air separation unit is an oxygen enriched condensing medium used in the argon condenser.

The present disclosure provides a method for cryogenic air separation. In the method, part (b2) of the air (b) is compressed in warm booster (7), cooled in heat exchanger (2) and then divided in two, one part (c1) being compressed in a cold booster(9) driven by one turboexpander (11) in which the other part (c2) of air (c) is expanded, and another part of the feed air is not boosted but is expanded in another turboexpander (6) which drives the warm booster (7). The present disclosure also provides an apparatus for cryogenic air separation.

A method and apparatus for purifying air via a pre-purification unit (PPU) of an air separation unit (ASU) system can include passing air through a first adsorber of the PPU to purify the air for operation of the ASU system while it is at or below a first pre-selected operational capacity. In response to the operational capacity of the ASU system needing to be increased to a level above the first pre-selected operational capacity threshold, a second adsorber can be brought on-line in parallel with the first adsorber or in series with the first adsorber to provide improved purification capacity to account for the increased demand for purification capacity resulting from the increased operational capacity of the ASU system. This second adsorber can be different from the first adsorber (e.g. different in size, adsorption capacity for impurities within air, and/or configuration, etc.).

A method for cryogenic separation of air uses an air separation plant, wherein, in a mass transfer column, a liquid first fluid and a gaseous second fluid are subjected to mass transfer with one another. A gaseous third fluid is removed from the column and is at least partly discharged from the air separation plant. A liquid fourth fluid is removed from the column and is at least partly fed into a low-pressure column. The first fluid is formed using at least a part of an oxygen-rich liquid removed from the low-pressure column. The second fluid is formed using an oxygen-enriched liquid removed from a high-pressure column. The oxygen-enriched liquid removed from the high-pressure column and bottom liquid of the mass transfer column are mixed and partly evaporated in a condenser-evaporator. A liquid fifth fluid is removed from the mass transfer column between a feed point for the first fluid and a feed point for the oxygen-enriched liquid, and is at least partly fed into the low-pressure column. The fifth fluid or a fraction thereof is fed into the low-pressure column below the fourth fluid or a fraction thereof.

A system includes a heat exchanger including a first inlet for receiving a first pressurized gas stream and a first outlet for outputting a chilled gas stream produced by the heat exchanger cooling the first pressurized gas stream. The system also includes a turbo expander connected to the first outlet of the heat exchanger for receiving the chilled gas stream from the heat exchanger and producing a partially liquified gas stream, the partially liquified gas stream comprising vapors and LNG. The system further includes at least one separator connected to the turbo expander, wherein the partially liquified gas stream is fed into the at least one separator, and the at least one separator separates the vapors from the LNG.

An air separation apparatus and process, which produces gaseous oxygen and/or nitrogen products at an elevated pressure through internal compression of respective liquid products, are disclosed. Split-core main heat exchangers are employed to warm up product streams generated in an air rectification unit against 1) a main feed air stream in the low-pressure heat exchanger and 2) at least one boosted pressure air stream in the high-pressure exchanger. Because the boosted pressure air stream is at a higher pressure and temperature than the main feed air stream, after separate heat exchange in the split main heat exchangers, the subsidiary waste nitrogen stream exiting the high-pressure heat exchanger is also warmer than the subsidiary waste nitrogen stream exiting the low-pressure heat exchanger. The warmer waste nitrogen stream is fed into the air purification unit for regeneration purposes and the cooler waste nitrogen stream is introduced into the nitrogen water tower to perform cooling duty. The two subsidiary waste nitrogen streams are also connected on the warm side of the main heat exchangers to allow flexible distribution of the flow.

A nitrogen liquefier configured to be integrated with an argon and nitrogen producing cryogenic air separation unit and method of nitrogen liquefaction are provided. The integrated nitrogen liquefier and associated methods may be operated in at least three distinct modes including: (i) a nil liquid nitrogen mode; (ii) a low liquid nitrogen mode; and (iii) a high liquid nitrogen mode. The present systems and methods are further characterized in an oxygen enriched stream from the lower pressure column of the air separation unit is an oxygen enriched condensing medium used in the argon condenser.

A method for operating a heat exchanger, in which a first operating mode is carried out in first time periods, and a second operating mode is carried out in second time periods that alternate with the first time periods; in the first operating mode a first fluid flow is formed at a first temperature level, is fed into the heat exchanger in a first region at the first temperature level, and is partially or completely cooled in the heat exchanger; in the first operating mode a second fluid flow is formed at a second temperature level, is fed into the heat exchanger in a second region at the second temperature level, and is partially or completely heated in the heat exchanger. A corresponding arrangement and a system with such an arrangement are also covered by the present invention.

An air separation process having a first booster air compressor comprising a first outlet stream and a second booster air compressor comprising a second outlet stream. Wherein the first booster air compressor and the second booster air compressor are in parallel, and the second booster air compressor is driven by a nitrogen turboexpander. The first outlet stream and/or the second outlet stream may be at least partially condensed by heat exchange with a vaporizing low pressure oxygen stream, and the low-pressure gaseous oxygen pressure is in the range of 1.1 bara to 3 bara.

A process for recovering at least one fluid (e.g. argon gas and/or nitrogen gas, etc.) from a feed gas (e.g. air) can include utilization of a compression system, primary heat exchanger unit, plant processing units to separate and recover at least one desired fluid (e.g. nitrogen gas, argon gas, etc.). In some embodiments, the process can be configured so that fluid flows output from a low pressure column and/or high pressure column of the plant can provide a condensation duty or refrigeration duty that is utilized to process certain fluid flows for recovery of argon and/or nitrogen gases. Some embodiments can be configured to provide an improved recovery of argon and/or nitrogen as well as an improvement in operational efficiency by reducing an amount of power (e.g. electrical power) needed to recover the nitrogen and/or argon.