In this process and apparatus for cryogenic separation of air, the separation column system comprises a high-pressure column, a low-pressure column and a crude argon column. A mixed gas stream produced by mixing gaseous oxygen and a gas stream from the evaporation space of the argon top condenser, is work expanded in a mixed gas turbine.

A hydrogen feed stream is introduced into a primary refrigeration system of a precooling system and cooling the hydrogen stream to a first precooling temperature. From there, the precooled hydrogen stream is then introduced to a secondary refrigeration system of the precooling system and cooling the precooled hydrogen stream to a second temperature. Next, the cooled hydrogen stream is then liquefied in the liquefaction system to produce liquid hydrogen.

An integrated industrial unit is provided, which can include: a nitrogen source configured to provide liquid nitrogen; a hydrogen source; a hydrogen liquefaction unit, wherein the hydrogen liquefaction unit comprises a precooling system, and a liquefaction system; and a liquid hydrogen storage tank, wherein the precooling system is configured to receive the gaseous hydrogen from the hydrogen source and cool the gaseous hydrogen to a temperature between 75 K and 100 K, wherein the precooling system comprises a primary refrigeration system and a secondary refrigeration system, wherein the liquefaction system is in fluid communication with the precooling system and is configured to liquefy the gaseous hydrogen received from the precooling system to produce liquid hydrogen, wherein the liquid hydrogen storage tank is in fluid communication with the liquefaction system and is configured to store the liquid hydrogen received from the liquefaction system.

A hydrogen feed stream is introduced into a primary refrigeration system of a precooling system and cooling the hydrogen stream to a first precooling temperature. From there, the precooled hydrogen stream is then introduced to a secondary refrigeration system of the precooling system and cooling the precooled hydrogen stream to a second temperature. Next, the cooled hydrogen stream is then liquefied in the liquefaction system to produce liquid hydrogen. The refrigeration is provided by expansion of a pressurized gaseous nitrogen stream and vaporization of a liquid nitrogen stream that is sourced from a nearby air separation unit.

An apparatus for the separation of air by cryogenic distillation comprises a column system, a heat exchanger, a turbine, means for sending compressed and purified air at a first pressure to be cooled at the first pressure in the heat exchanger, means for sending a first gaseous stream having a nitrogen content at least that of air to be cooled and liquefied or pseudo liquefied in the heat exchanger to form a liquefied stream, means for sending at least part of the liquefied stream to be warmed and vaporized in the heat exchanger to a first intermediate temperature of the heat exchanger to form a vaporized stream, means for removing the vaporized stream from an intermediate section of the heat exchanger, a conduit for sending the vaporized stream to be expanded, in the turbine to form an expanded stream, a conduit for sending at least part of the expanded stream to the column system, a conduit for sending a second gaseous stream having the same nitrogen content as the first stream to be cooled in the heat exchanger, means for removing at least part of the second gaseous stream from an intermediate section of the heat exchanger at a second intermediate temperature and sending the second gaseous stream to the turbine to be expanded with the vaporized stream.

Xenon and/or krypton is separated from a liquid oxygen stream comprising oxygen and xenon and/or krypton in a process comprising providing at least a portion of the liquid oxygen stream as a reflux liquid to the top of a rare gas recovery column operated at a pressure of between 5 to 25 bara, vaporizing a reboiler liquid in the reboiling zone in the bottom of the rare gas recovery column to produce a mixture of a rising vapor and a xenon and/or krypton-enriched liquid stream; and contacting the rising vapor with the reflux liquid in at least one distillation zone of the column to effect stripping xenon and/or krypton from the rising vapor to the reflux liquid. The process provides a recovery of xenon of greater than 90% and a krypton recovery of 15% to 90%.

A method for operating a heat exchanger, in which a first operating mode is carried out in first time periods, and a second operating mode is carried out in second time periods that alternate with the first time periods; in the first operating mode a first fluid flow is formed at a first temperature, is fed into the heat exchanger in a first region at the first temperature, and is partially or completely cooled in the heat exchanger; in the first operating mode a second fluid flow is formed at a second temperature, is fed into the heat exchanger in a second region at the second temperature, and is partially or completely heated in the heat exchanger; and in the second operating mode the feeding of the first fluid flow and of the second fluid flow into the heat exchanger is partially or completely halted.

A method for configuring a control system for a process plant using a dynamic model of the process plant, the dynamic model being based on at least one of thermo fluidic correlations, thermo dynamic correlations, phenomenological correlations, and equations, and being based on geometry and/or topology of components of the process plant, the dynamic model receiving process parameters as input values, the dynamic model being adapted to represent a transition from one to another state of the process plant and the dynamic model covering the entire operating range of the process plant wherein the dynamic model is used in an offline mode, in which the dynamic model is used in stand-alone fashion, wherein, based on input and output values of the dynamic model, a behaviour of the process plant is predicted, and wherein, based on the predicted behaviour of the process plant, the control system is configured.

A method for operating a process plant using a dynamic model of the process plant, the dynamic model being based on at least one of thermo fluidic correlations, thermo dynamic correlations, phenomenological correlations, and equations, and being based on geometry and/or topology of components of the process plant, the dynamic model receiving process parameters as input values, the dynamic model being adapted to represent a transition from one to another state of the process plant, wherein the dynamic model is used in an online mode, in which the dynamic model is used in parallel with the operation of the process plant, wherein signals from a control system of the process plant, the signals representing values of at least one first process parameter, are received and fed into the dynamic model.

An air separation device according to the present invention is an air separation device in which air is distilled at a low temperature, and includes a high-pressure column which separates high-pressure raw material air into high-pressure nitrogen gas and high-pressure oxygen-enriched liquefied air; a low-pressure column which separates the high-pressure oxygen-enriched liquefied air into low-pressure nitrogen gas, low-pressure liquefied oxygen, and argon-enriched liquefied oxygen; an argon column which separates the argon-enriched liquefied oxygen having a pressure higher than the pressure into argon gas and medium-pressure liquefied oxygen; a first indirect heat-exchanger which heat-exchanges between the argon gas and the low-pressure liquefied oxygen; a second indirect heat-exchanger which heat-exchanges between the high-pressure nitrogen gas and the medium-pressure liquefied oxygen; a first gas-liquid separation chamber which separates the low-pressure oxygen gas which has been vaporized by the first indirect heat-exchanger and the low-pressure liquefied oxygen which has not been vaporized; a second gas-liquid separation chamber which separates the medium-pressure oxygen gas which has been vaporized by the second indirect heat-exchanger and the medium-pressure liquefied oxygen which has not been vaporized; a first passage which communicates the gas phase of the low-pressure column and the gas phase of the second gas-liquid separation chamber; a second passage which communicates the liquid phase of the low-pressure column and the second gas-liquid separation chamber; a first opening/closing mechanism located on the first passage; and a second opening/closing mechanism located on the second passage.