F25J3/04218

METHOD FOR FLEXIBLE RECOVERY OF ARGON FROM A CRYOGENIC AIR SEPARATION UNIT
20220146195 · 2022-05-12 ·

A method for flexible production of argon from a cryogenic air separation unit is provided. The disclosed cryogenic air separation unit is capable of operating in a ‘no-argon’ or ‘low-argon’ mode when argon demand is low or non-existent and then switching to operating in a ‘high-argon’ mode when argon is needed. The recovery of the argon products from the air separation unit is adjusted by varying the percentages of dirty shelf nitrogen and clean shelf nitrogen in the reflux stream directed to the lower pressure column. The cryogenic air separation unit and associated method also provides an efficient argon production/rejection process that minimizes the power consumption when the cryogenic air separation unit is operating in a ‘no-argon’ or ‘low-argon’ mode yet maintains the capability to produce higher volumes of argon products at full design capacity to meet argon product demands.

PRODUCT GAS SUPPLY QUANTITY ADJUSTMENT DEVICE AND AIR SEPARATION APPARATUS COMPRISING SAME

A supply quantity adjustment device 500 comprises: a total demand quantity calculation unit 502 that calculates a total demand quantity used at a supply destination, based on plant information; an excess/deficit information setting unit 503 that compares the total demand quantity and a flow rate set value and sets a first calculated pressure value; a backup coefficient setting unit that sets a backup coefficient set value based on a reference gasholder pressure, the first calculated pressure value, a reference backup pressure set value, and a measured gasholder pressure value; and a production coefficient setting unit that compares a production pressure set value obtained by adding the reference gasholder pressure and a first pressure output value with the measured gasholder pressure value, and sets a production coefficient so as to modify a variation in the quantity of product gas produced by the air separation apparatus.

METHOD AND APPARATUS FOR IMPROVING EFFICIENCY OF A FRONT-END PURIFICATION UNIT OF AN AIR SEPARATION PLANT

A method and apparatus for reducing heat bumps following regeneration of adsorbers in an air separation unit is provided. Certain embodiments of the current invention utilize the two waste streams available at very different temperatures from the two main exchangers (low-pressure and high-pressure core exchangers) for regeneration of the front-end purification adsorbers in the air separation unit (ASU) to reduce its energy consumption without compromising the stability of process. Certain embodiments help to eliminate/minimize high air temperature disturbance (heat bump) for the process downstream of the front-end purification unit during the transition from offline to online.

CRYOGENIC RECTIFICATION PROCESS-BASED METHOD FOR PRODUCING AIR PRODUCT, AND AIR SEPARATION SYSTEM

The present invention discloses a cryogenic rectification process-based method for producing an air product, and an air separation system. By adding an air product outlet line and a liquid air booster pump to an existing cryogenic rectification process apparatus, the existing rectification apparatus is used to prepare oxygen-enriched liquid air by pressurizing, cooling and liquefying feed air; and moreover, a high-pressure or ultra-high-pressure air product can be prepared according to customer requirements by adjusting the ratio of the feed air to the oxygen-enriched liquid air, and pressurizing the mixture to a target pressure by the liquid air booster pump before being vaporized via heat exchange with a gas or liquid product produced by rectification through a heat exchange apparatus. According to the present invention, when gas or liquid products of oxygen and nitrogen are produced by means of rectification, a high-pressure or ultra-high-pressure air product can be provided according to customer requirements, and there is no need to provide an additional air compressor or passively increase the discharge pressure of the air booster, so that the production costs are greatly reduced and the energy efficiency level is improved. The method of the present invention can also improve the stability of devices, especially when a small amount of high-pressure/ultra-high-pressure air product needs to be produced.

UTILIZATION OF NITROGEN-ENRICHED STREAMS PRODUCED IN AIR SEPARATION UNITS COMPRISING SPLIT-CORE MAIN HEAT EXCHANGERS

An air separation apparatus and process, which produces gaseous oxygen and/or nitrogen products at an elevated pressure through internal compression of respective liquid products, are disclosed. Split-core main heat exchangers are employed to warm up product streams generated in an air rectification unit against 1) a main feed air stream in the low-pressure heat exchanger and 2) at least one boosted pressure air stream in the high-pressure exchanger. Because the boosted pressure air stream is at a higher pressure and temperature than the main feed air stream, after separate heat exchange in the split main heat exchangers, the subsidiary waste nitrogen stream exiting the high-pressure heat exchanger is also warmer than the subsidiary waste nitrogen stream exiting the low-pressure heat exchanger. The warmer waste nitrogen stream is fed into the air purification unit for regeneration purposes and the cooler waste nitrogen stream is introduced into the nitrogen water tower to perform cooling duty. The two subsidiary waste nitrogen streams are also connected on the warm side of the main heat exchangers to allow flexible distribution of the flow.

Process and apparatus for separating air using a split heat exchanger

Process and apparatus for the separation of a compressed feed air stream to produce an oxygen product using a distillation column having a lower-pressure column and a higher-pressure column, a higher-pressure heat exchanger and a lower-pressure heat exchanger where the gaseous nitrogen expander receives a nitrogen-enriched fraction from a position intermediate the warmer end and the colder end of the higher-pressure heat exchanger.

CRYOGENIC DISTILLATION METHOD AND APPARATUS FOR PRODUCING PRESSURIZED AIR BY MEANS OF EXPANDER BOOSTER IN LINKAGE WITH NITROGEN EXPANDER FOR BRAKING

Provided are a method and apparatus for producing nitrogen and oxygen by means of cryogenic distillation of air. Nitrogen products are extracted only from the top of a tower. If a customer needs nitrogen with lower pressure, part of pure nitrogen that is partially located at a first nitrogen product pressure is reheated in a main heat exchanger, then decompressed to a second nitrogen product pressure by means of a nitrogen expander, further reheated by means of the main heat exchanger, and output as a low-pressure nitrogen product. The nitrogen expander can be braked by an expander booster for compressing air. By means of the method, nitrogen with different pressures can be suitably produced, and the energy consumption for producing the pressurized air can be reduced by utilizing the expansion work of nitrogen.

Cryogenic air separation method for producing oxygen at high pressures
10746461 · 2020-08-18 · ·

The present invention relates to a cryogenic air separation process that provides high pressure oxygen for an oxy-fired combustion of a fuel (e.g., a carbonaceous fuel). The air separation process can be directly integrated into a closed cycle power production process utilizing a working fluid, such as CO.sub.2. Beneficially, the air separation process can eliminate the need for inter-cooling between air compression stages and rather provide for recycling the adiabatic heat of compression into a process step in further methods wherein an additional heat supply is beneficial.

AIR SEPARATION METHOD AND APPARATUS
20200149808 · 2020-05-14 ·

A method and apparatus for separating air in which an oxygen-rich liquid stream is pumped and then heated within a heat exchanger to produce an oxygen product through indirect heat exchange with first and second boosted pressure air streams. The first boosted pressure air stream is cold compressed at an intermediate temperature of the heat exchanger, reintroduced into the heat exchanger at a warmer temperature and then fully cooled and liquefied. The second boosted pressure air stream, after having been partially cooled, is expanded to produce an exhaust stream that is in turn introduced into a lower pressure column producing the oxygen-rich liquid. The second boosted pressure air stream is partially cooled to a temperature no greater than the intermediate temperature at which the cold compression occurs so that both the first and second boosted pressure air streams are able to take part in the heating of the oxygen-rich stream.

Process for increasing low pressure pure nitrogen production by revamping original apparatus for cryogenic air separation

The object of the present invention is to provide a different solution for revamping existing producing apparatuses so as to increase the production of low pressure pure nitrogen while controlling as far as possible the capital and operation expenditures. The revamping solution comprises increasing the diameter and/or height of a pure nitrogen column to thereby improve the production capacity thereof; choosing to switch the conduits where the waste liquid nitrogen and pure liquid nitrogen are passed through in the subcooler according to the increment of the low pressure pure nitrogen production; adding an additional heat exchanger to conduct a heat exchange between a portion of the medium pressure air and the increased low pressure pure nitrogen; or simultaneously switching the main parts of the conduits which transfer the pure liquid nitrogen and waste liquid nitrogen from a first column of higher pressure to a second column of lower pressure while performing the above revamping. The stepwise revamping solution of the present invention can be used not only to control the cost but also increase the low pressure pure nitrogen production while ensuring a stable operation of the air separation unit.