The production of NH.sub.3, Urea, UAN, and DAP, starting from inherently intermittent renewable energy, such as photovoltaic and wind power, is made economical by use of molten salt thermal energy storage (ESS) and water electrolyzer (WE) concentrated oxygen. The process inputs and equipment apply air; hydrogen-containing fuel, such as biomass; WE (concentrated O.sub.2 and H.sub.2 producing); thermal ESS equipped with a turbine and generator to steady the electricity input to the WE; and an ammonia plant. The thermal ESS enables minimally sized process equipment including, the WE, the air separation unit and less hydrogen storage. The concentrated oxygen from the water electrolyzer uniquely enables high-temperature thermal ESS input, water and CO2 collection and other fertilizer products, including Urea, UAN and DAP. DAP production is facilitated by using WE high-purity O.sub.2 oxidation and ammonium nitrate is similarly facilitated by anhydrous NH.sub.3 oxidation.

A system which integrates a power production system and an energy storage system represented by gas liquefaction systems is provided.

A system that integrates a power production system and an energy storage system represented by gas liquefaction systems is provided.

A natural gas power generation process with zero carbon emission is described. The process includes pressurizing air and introducing the pressurized air into an air separation facility to obtain liquid oxygen and liquid nitrogen. The liquid oxygen is used for gasification and power generation The liquid nitrogen is applied as a coolant of flue gas, and then for gasification and power generation.

The present disclosure relates to systems and methods that provide power generation using predominantly CO.sub.2 as a working fluid. In particular, the present disclosure provides for the use of a portion of the heat of compression from a CO.sub.2 compressor as the additive heating necessary to increase the overall efficiency of a power production system and method.

A system and method for supplying an energy grid with energy from an intermittent renewable energy source having a production unit for producing Hydrogen, Nitrogen, and Oxygen. The production unit is operated by using energy provided by the renewable energy source. An Oxygen storage receives and stores Oxygen produced by the production unit, a mixing unit receives and mixes the Hydrogen and the Nitrogen produced by the production unit to form a Hydrogen-Nitrogen-mixture, an Ammonia source receives and processes the Hydrogen-Nitrogen-mixture for generating a gas mixture containing Ammonia, an Ammonia power generator generates energy for the energy grid. The Ammonia power generator is fluidly connected to the Ammonia storage vessel, is configured to combust the received Ammonia in a combustion chamber to generate the energy, and is fluidly connected to the Oxygen storage to introduce Oxygen into the combustion chamber for combustion of Ammonia.

The present invention relates to a cryogenic air separation process that provides high pressure oxygen for an oxy-fired combustion of a fuel (e.g., a carbonaceous fuel). The air separation process can be directly integrated into a closed cycle power production process utilizing a working fluid, such as CO.sub.2. Beneficially, the air separation process can eliminate the need for inter-cooling between air compression stages and rather provide for recycling the adiabatic heat of compression into a process step in further methods wherein an additional heat supply is beneficial.

The present disclosure relates to systems and methods that provide power generation using predominantly CO.sub.2 as a working fluid. In particular, the present disclosure provides for the use of a portion of the heat of compression from a CO.sub.2 compressor as the additive heating necessary to increase the overall efficiency of a power production system and method.

A method of temperature balancing for thermal integration of an air separation unit (ASU) with an oxycombustion power generation system, including compressing air through a plurality of compression stages, and routing a first stage compressed air stream through a first heat exchanger in heat exchange communication with a subsequent stage compressed air stream to lower the first stage compressed air stream temperature and increase the temperature of a subsequent stage compressed air stream.

The production of NH.sub.3, Urea, UAN, and DAP, starting from inherently intermittent renewable energy, such as photovoltaic and wind power, is made economical by use of molten salt thermal energy storage (ESS) and water electrolyzer (WE) concentrated oxygen. The process inputs and equipment apply air; hydrogen-containing fuel, such as biomass; WE (concentrated O.sub.2 and H.sub.2 producing); thermal ESS equipped with a turbine and generator to steady the electricity input to the WE; and an ammonia plant. The thermal ESS enables minimally sized process equipment including, the WE, the air separation unit and less hydrogen storage. The concentrated oxygen from the water electrolyzer uniquely enables high-temperature thermal ESS input, water and CO.sub.2 collection and other fertilizer products, including Urea, UAN and DAP. DAP production is facilitated by using WE high-purity O.sub.2 oxidation and ammonium nitrate is similarly facilitated by anhydrous NH.sub.3 oxidation.