Closed-loop refrigeration cycles for liquid oxygen densification are disclosed. The disclosed refrigeration cycles may be turbine-based refrigeration cycles or a Joule-Thompson (JT) expansion valve based refrigeration cycles and include a refrigerant or working fluid comprising a mixture of neon or helium together with nitrogen and/or oxygen.

A system and method for increasing the efficiency of natural gas liquefaction processes by using a hybrid cooling system and method. More specifically, a system and method for converting a transcritical precooling refrigeration process to a subcritical process. In one embodiment, the refrigerant is cooled to sub-critical temperature using an economizer. In another embodiment, the refrigerant is cooled to a sub-critical temperature using an auxiliary heat exchanger. Optionally, the economizer or auxiliary heat exchanger can be bypassed when ambient temperatures are sufficiently low to cool the refrigerant to a sub-critical temperature. In another embodiment, the refrigerant is isentropically expanded.

A method for liquefying a feed gas stream. A refrigerant stream is cooled and expanded to produce an expanded, cooled refrigerant stream. Part or all of the expanded, cooled refrigerant stream is mixed with a make-up refrigerant stream in a separator, thereby condensing heavy hydrocarbon components from the make-up refrigerant stream and forming a gaseous expanded, cooled refrigerant stream. The gaseous expanded, cooled refrigerant stream passes through a heat exchanger zone to form a warm refrigerant stream. The feed gas stream is passed through the heat exchanger zone to cool at least part of the feed gas stream by indirect heat exchange with the expanded, cooled refrigerant stream, thereby forming a liquefied gas stream. The warm refrigerant stream is compressed to produce the compressed refrigerant stream.

A method for liquefying a feed gas stream. A compressed first refrigerant stream is cooled and expanded to produce an expanded first refrigerant stream. The feed gas stream is cooled to within a first temperature range by exchanging heat only with the expanded first refrigerant stream to form a liquefied feed gas stream and a warmed first refrigerant stream. A compressed second refrigerant stream is provided is cooled to produce a cooled second refrigerant stream. At least a portion of the cooled second refrigerant stream is further cooled by exchanging heat with the expanded first refrigerant stream, and then is expanded to form an expanded second refrigerant stream. The liquefied feed gas stream is cooled to within a second temperature range by exchanging heat with the expanded second refrigerant stream to form a sub-cooled LNG stream and a first warmed, second refrigerant stream.

A method is disclosed for start-up of a system for liquefying a feed gas stream comprising natural gas. The system has a feed gas compression and expansion loop, and a refrigerant system comprising a primary cooling loop and a sub-cooling loop. The feed gas compression and expansion loop is started up. The refrigerant system is pressurized. Circulation in the primary cooling loop is started and established. Circulation in the sub-cooling loop is started and established. A flow rate of the feed gas stream and circulation rates of the primary cooling loop and the sub-cooling loop are ramped up.

A device for refrigerating and/or liquefying a working gas comprising helium, the device comprising a looped working circuit for the working gas includes, in series, a compression station, a cold box, a heat exchange system exchanging heat between the cooled working gas and a user, the device further comprising an additional pre-cooling system comprising at least one tank of auxiliary cryogenic fluid, such as liquid nitrogen, the cold box comprising a first cooling stage of the working gas comprising a first exchanger disposed at the output of the compression station as well as a second heat exchanger and a third heat exchanger, the first heat exchanger being of the aluminum plate-fin type, the second heat exchanger being of the tube or welded plate type, characterized in that the second and third heat exchangers are connected both serially and in parallel on the working circuit downstream of the first heat exchanger.

Refrigeration device comprising a working circuit in a loop for the working gas and comprising, in series: a compression station, a cold box, a system for the exchange of heat between the cooled working gas and a point of use, a system for the additional pre-cooling of the working gas leaving the compression station comprising an auxiliary cryogenic fluid volume, the cold box comprising a first cooling stage for the working gas comprising a first and a second heat exchanger, these being connected both in series and in parallel to the working circuit at the outlet of the compression station, the first cooling stage also comprising a third heat exchanger selectively exchanging heat with the auxiliary fluid, characterized in that the third heat exchanger is connected both in series and in parallel to the first and to the second heat exchangers, the working circuit comprising a recuperation pipe fitted with at least one valve and which connects the outlet of the third heat exchanger to the second heat exchanger.

A thermodynamic system containing a working fluid is disclosed. The thermodynamic system comprises at least a working fluid collection vessel (11) adapted to contain a liquid phase and a gaseous phase of the working fluid in thermodynamic equilibrium. A chilling arrangement (51) is functionally coupled to the fluid collection vessel (11) and adapted to remove heat from the working fluid collected in the working fluid collection vessel (11) and thereby reduce pressure in said thermodynamic system. Also disclosed are methods for depressurizing a thermodynamic system containing a working fluid in liquid/gas equilibrium.

A method and system for liquefying a methane-rich high-pressure feed gas stream using a first heat exchanger zone and a second heat exchanger zone. The feed gas stream is mixed with a refrigerant stream to form a second gas stream, which is compressed, cooled, and directed to a second heat exchanger zone to be additionally cooled below ambient temperature. It is then expanded to a pressure less than 2,000 psia and no greater than the pressure to which the second gas stream was compressed, and then separated into a first expanded refrigerant stream and a chilled gas stream. The first expanded refrigerant stream is expanded and then passed through the first heat exchanger zone such that it has a temperature that is cooler, by at least 5 F., than the highest fluid temperature within the first heat exchanger zone.

A device for refrigerating and/or liquefying a working gas comprising helium, the device comprising a looped working circuit for the working gas includes, in series, a compression station, a cold box, a heat exchange system exchanging heat between the cooled working gas and a user, the device further comprising an additional pre-cooling system comprising at least one tank of auxiliary cryogenic fluid, such as liquid nitrogen, the cold box comprising a first cooling stage of the working gas comprising a first exchanger disposed at the output of the compression station as well as a second heat exchanger and a third heat exchanger, the first heat exchanger being of the aluminum plate-fin type, the second heat exchanger being of the tube or welded plate type, characterized in that the second and third heat exchangers are connected both serially and in parallel on the working circuit downstream of the first heat exchanger.