Provided are various gloves and protective articles with improved donning characteristics. The glove comprises an interior surface, and a polymer system coating the interior surface. The polymer system comprises one or more first polymers, each including an average particle size between 100 nanometers (nm) to 400 nm. The polymer system further comprises one or more second polymers, each including an average particle size in excess of 500 nm. The one or more first polymers may comprise a combination of one or more polymers including: butadiene based polymer and copolymer latices, isoprene based polymer and copolymer latices, copolymer latices prepared from styrene and acrylic monomers, and polyurethane copolymers. The one or more second polymers may include vinyl acetate polymers. The glove may be an elastomeric rubber glove coated with the polymer system in an amount between 0.0004 grams and 0.0016 grams on a dry basis.

An elastomeric article is formed from a blend of nitrile rubber and polychloroprene rubber. The elastomeric article can be a glove, such as a medical exam glove. The elastomeric article is softer than a conventional nitrile elastomeric article. The elastomeric article is formed from a blended rubber latex emulsion of nitrile and polychloroprene. The blended rubber latex emulsion may be free of sulfur and vulcanization accelerators.

An improved glove has both anatomically correlating stress relief zones and/or reinforced zones to add support in areas opposite the stress relief zones to keep bunching or slipping of the glove from interfering with the bending of the user's joints. The glove may have corrugated relief zones over some or all of the joints and knuckles of the hand, wherein the relief zones are formed of peaks and valleys. A relief zone can also be provided over the webbing between the thumb and the palm. The vertical or longitudinal relief zones provide for improved glove quality while keeping manufacturing difficulty and costs at a minimum.

The invention provides a novel hydrophilic polymer and rubber polymer microparticles blend coating formulation and compositions thereof for rubber gloves to improve wet donning properties for easy application. More particularly, the invention relates to a novel hydrophilic polymer and rubber polymer microparticles blend coating formulation and compositions thereof, and their use on gloves to form hydrophilic and flexible coatings with durable lubricity. The gloves of the invention exhibit good donnability, tensile strength, elongation to break, and stress at 500% elongation.

Provided are compositions and associated methods for producing elastomeric rubber gloves with improved strength and flexibility at desirable glove palm thicknesses. An example elastomeric rubber glove comprises a substrate formed from a composition comprising a synthetic rubber latex, and an ionic liquid. The ionic liquid may comprise a combination of one or more alkyl imidazole ionic salts. The composition may comprise one or more metal oxides, including at least one of zinc oxide, magnesium oxide, cadmium oxide, and aluminum oxide. The synthetic rubber latex compositions were found to yield a material with strength and flexibility characteristics comparable to natural latex gloves of a greater thickness. The described gloves may also be cured without the addition of Sulphur and other vulcanization or rubber accelerators, further reducing the risk of allergies and costs of production.

Provided is a method of producing a glove, the method including: (1) the step of immersing a glove forming mold in a liquid coagulant containing calcium ions so as to allow the coagulant to adhere to the glove forming mold; (2) the step of adjusting the pH to be 9 or higher using an ammonium compound or an amine compound and leaving a glove emulsion composition to stand with stirring; (3) the dipping step of immersing the glove forming mold, to which the coagulant has thus adhered in the step (1), in the glove emulsion composition; (4) the gelling step of leaving the glove forming mold, to which the glove emulsion composition has thus adhered, to stand at a temperature for a period that satisfy specific conditions; (5) the leaching step of removing impurities from a cured film precursor thus formed on the glove forming mold; (6) the beading step of, after the leaching step, winding the cuff portion of the resulting glove; (7) the precuring step of heating and drying the cured film precursor that has been subjected to the beading step; and (8) the curing step of heating the cured film precursor at a specific temperature for a specific period to obtain a cured film.

The present invention relates to a method of preparing reduced graphene oxide, incorporation of the reduced graphene oxide into polyisoprene latex to provide a polyisoprene latex graphene composite and elastomeric articles prepared using the polyisoprene latex-graphene composite. In particular, the reduction of graphene oxide is accomplished without the use of strong reducing agents and organic solvents and incorporation of the reduced graphene oxide into polyisoprene latex is accomplished using room temperature latex mixing method or hot maturation. The resultant composite exhibits good colloid stability, and polyisoprene latex films produced the composite exhibit good mechanical properties with improved ageing resistance.

Provided is, a glove production method including: (1) the step of immersing a glove forming mold in a liquid coagulant containing calcium ions so as to allow the coagulant to adhere to the glove forming mold; (2) the dispersion step of leaving a dip molding composition to stand with stirring; (3) the dipping step; (4) the gelling step; (5) the leaching step; (6) the beading step; (7) the precuring step; and (8) the curing step, in which method the steps (3) to (8) are performed in the order mentioned, and the dip molding composition has a specific formulation.

Gloves comprising a polymeric coating or layer, optionally including a fabric liner, and at least one reinforcement, disposed on a part(s) of the polymeric coating or layer and/or ac part(s) of the fabric liner, and methods of making the gloves are disclosed.

Provided is a dip molding composition including, at least: an elastomer that contains a (meth)acrylonitrile-derived structural unit, an unsaturated carboxylic acid-derived structural unit, and a butadiene-derived structural unit in a polymer main chain; an epoxy crosslinking agent; water; and a pH modifier, in which dip molding composition the elastomer contains the (meth)acrylonitrile-derived structural unit in an amount of 20 to 40% by weight, the unsaturated carboxylic acid-derived structural unit in an amount of 1 to 10% by weight, and the butadiene-derived structural unit in an amount of 50 to 75% by weight, and the epoxy crosslinking agent includes an epoxy crosslinking agent containing an epoxy compound having three or more epoxy groups in one molecule and has a dissolution rate in water of 10 to 70% as determined by a specific measurement method.