Disclosed are systems and methods for providing an adiabatic power compensation differential scanning calorimeter to minimize a temperature difference between a sample and a reference. For instance, methods can include providing ramp-up heating power to heat a sample container and a reference container based on a preprogrammed temperature ramp rate; minimizing a temperature difference among the sample container, the reference container, and at least one furnace; providing compensating heat to the sample container and the reference container when a self-heating activity of the sample material is detected; providing container-only compensating heat to the sample container to block heat transfer from the sample material to the sample container once the self-heating activity of the sample material is detected; and providing compensating heat to the reference container to facilitate container-only compensating heat calculation and control.

Described is a calorimeter that includes a thermal column, a sample container, a reference container, a thermal shield, a diffusion-bonded block and a thermal plate. One or more heat flux sensors are disposed between the thermal column and the sample container and between the thermal column and the reference container. The thermal shield is in thermal communication with the thermal column and is separated from and substantially encloses the sample container, reference container and thermal column. The diffusion-bonded block includes a first metallic layer having a first thermal conductivity, a second metallic layer having a second thermal conductivity and a third metallic layer having a third thermal conductivity. The second thermal conductivity is different from the first and third thermal conductivities. The first metallic layer is in thermal communication with the base of the thermal column and the third metallic layer is in thermal communication with the thermal plate.

Described is a calorimeter that includes a thermal column, a sample container, a reference container, a thermal shield, a diffusion-bonded block and a thermal plate. One or more heat flux sensors are disposed between the thermal column and the sample container and between the thermal column and the reference container. The thermal shield is in thermal communication with the thermal column and is separated from and substantially encloses the sample container, reference container and thermal column. The diffusion-bonded block includes a first metallic layer having a first thermal conductivity, a second metallic layer having a second thermal conductivity and a third metallic layer having a third thermal conductivity. The second thermal conductivity is different from the first and third thermal conductivities. The first metallic layer is in thermal communication with the base of the thermal column and the third metallic layer is in thermal communication with the thermal plate.

A calorimeter for measuring a heat flux of a sample comprises a container, a first heat sink and a second heat sink whereby the sample is arranged in the container. The first heat sink and the second heat sink are arranged at a distance from each other on the container. The first heat sink comprises a first heat transducer element and the second heat sink comprises a second heat transducer element. Each of the first and second heat transducer elements comprise a heat receiving surface and a heat absorbing surface for generating an electromotive force equivalent to the heat flux to or from the respective heat sink to be sent to a detecting unit for obtaining an electrical potential representing the heat flux leaving or traversing the container.

A calorimeter for measuring a heat flux of a sample comprises a container, a first heat sink and a second heat sink whereby the sample is arranged in the container. The first heat sink and the second heat sink are arranged at a distance from each other on the container. The first heat sink comprises a first heat transducer element and the second heat sink comprises a second heat transducer element. Each of the first and second heat transducer elements comprise a heat receiving surface and a heat absorbing surface for generating an electromotive force equivalent to the heat flux to or from the respective heat sink to be sent to a detecting unit for obtaining an electrical potential representing the heat flux leaving or traversing the container.

The present invention discloses a multi-screen supporting device in a high-temperature adiabatic calorimeter, and belongs to a calorimeter device in calorimetry. The multi-screen supporting device comprises a vacuum tank, three layers of protecting screens, two layers of thermal insulation screens, a protecting screen supporter for supporting and fixing the protecting screens, a thermal insulation screen supporter for supporting and fixing the thermal insulation screens, and a connecting piece for connecting and fixing the protecting screen supporter and the thermal insulation screen supporter. The multi-screen supporting mode in the high-temperature calorimeter solves the problems of time consumption for disassembling and assembling, low multi-screen assembling coaxiality and reduced experimental repeatability caused by many parts moved in each disassembling and assembling in the existing high-temperature calorimeter. The multi-screen supporting mode is easy in part processing, high in disassembling and assembling efficiency and convenient in operation, and effectively improves the experimental repeatability.

The present invention discloses a multi-screen supporting device in a high-temperature adiabatic calorimeter, and belongs to a calorimeter device in calorimetry. The multi-screen supporting device comprises a vacuum tank, three layers of protecting screens, two layers of thermal insulation screens, a protecting screen supporter for supporting and fixing the protecting screens, a thermal insulation screen supporter for supporting and fixing the thermal insulation screens, and a connecting piece for connecting and fixing the protecting screen supporter and the thermal insulation screen supporter. The multi-screen supporting mode in the high-temperature calorimeter solves the problems of time consumption for disassembling and assembling, low multi-screen assembling coaxiality and reduced experimental repeatability caused by many parts moved in each disassembling and assembling in the existing high-temperature calorimeter. The multi-screen supporting mode is easy in part processing, high in disassembling and assembling efficiency and convenient in operation, and effectively improves the experimental repeatability.

A generated-heat-quantity measuring method is a method that measures a generated heat quantity of a heat generating component mounted on a substrate. The generated-heat-quantity measuring method includes: measuring a first heat quantity transferred between a heat transfer component and the heat generating component, a first component temperature of the heat generating component, and a first substrate temperature of the substrate; calculating a first thermal resistance between the heat generating component and the substrate in accordance with the first heat quantity, the first component temperature, and the first substrate temperature; causing the heat generating component to generate heat and measuring a second component temperature of the heat generating component and a second substrate temperature of the substrate; and calculating a second heat quantity flowing from the heat generating component to the substrate in accordance with the second component temperature, the second substrate temperature, and the first thermal resistance.

It is an object of the present invention to provide a calorific value measuring device and a calorific value measuring method which enable highly reliable measurement of the calorific value of a by-product gas produced in a steelmaking process. In the present invention, with a by-product gas produced in a steelmaking process being employed as an object gas of which calorific value is to be measured, the refractive index and the sonic speed of the by-product gas are measured so as to compute a refractive index equivalent calorific value Q.sub.O from the value of the refractive index as well as a sonic speed equivalent calorific value Q.sub.S from the value of the sonic speed. On the basis of the concentration X.sub.CO of carbon monoxide gas contained in the by-product gas, an error calorific value Q.sub.CO is computed by Equation (1) below using a value selected within a range of 0.08 to 0.03 as a calorific value equivalent coefficient . On the basis of the refractive index equivalent calorific value Q.sub.O, the sonic speed equivalent calorific value Q.sub.S and the error calorific value Q.sub.CO which have been computed, the calorific value Q of the by-product gas is determined by Equation (2) below using a value selected within a range of 1.1 to 4.2 as a correction factor . $\begin{array}{cc}{Q}_{\mathrm{CO}}=X_{\mathrm{CO}}.Math.& \mathrm{Equation}\left(1\right)\\ Q=Q_0-\frac{Q_0-Q_S}{1-}-Q_C\end{array}$

It is an object of the present invention to provide a calorific value measuring device and a calorific value measuring method which enable highly reliable measurement of the calorific value of a by-product gas produced in a steelmaking process. In the present invention, with a by-product gas produced in a steelmaking process being employed as an object gas of which calorific value is to be measured, the refractive index and the sonic speed of the by-product gas are measured so as to compute a refractive index equivalent calorific value Q.sub.O from the value of the refractive index as well as a sonic speed equivalent calorific value Q.sub.S from the value of the sonic speed. On the basis of the concentration X.sub.CO of carbon monoxide gas contained in the by-product gas, an error calorific value Q.sub.CO is computed by Equation (1) below using a value selected within a range of 0.08 to 0.03 as a calorific value equivalent coefficient . On the basis of the refractive index equivalent calorific value Q.sub.O, the sonic speed equivalent calorific value Q.sub.S and the error calorific value Q.sub.CO which have been computed, the calorific value Q of the by-product gas is determined by Equation (2) below using a value selected within a range of 1.1 to 4.2 as a correction factor . $\begin{array}{cc}{Q}_{\mathrm{CO}}=X_{\mathrm{CO}}.Math.& \mathrm{Equation}\left(1\right)\\ Q=Q_0-\frac{Q_0-Q_S}{1-}-Q_C\end{array}$