The present disclosure relates to an electrophotographic printing method comprising electrophotographically printing a liquid electrophotographic composition onto a substrate. The liquid electrophotographic composition comprises a charge adjuvant and a copolymer of a) ethylene and b) methacrylic acid and/or acrylic acid, wherein 80 to 95 weight % of the units of said copolymer are derived from ethylene. The printed substrate is then subjected to electron beam (EB) radiation.

Printable compositions comprising a liquid carrier; and a radiation curable polyurethane dispersed in the liquid carrier are described, as well as methods of preparing the printable compositions and methods of printing using the printable compositions.

Described herein is a method for priming a polymeric print substrate for subsequently receiving a liquid electrophotographic (LEP) ink in which a surface of a polymeric print substrate is coated with a first primer using an analogue printing technique and a second primer is digitally printed to the surface of the polymeric print substrate coated with the first primer.

Described herein is a process for preparing a flexible printed material. The process may comprise providing a flexible print substrate comprising a primer on a surface of the print substrate, the primer comprising a primer resin; printing an ink composition comprising a thermoplastic resin onto the primer on the surface of the print substrate; and depositing a cross-linking composition comprising a cross-linker onto the printed ink composition disposed on the primer such that the thermoplastic resin of the ink composition is crosslinked and the primer resin of the primer is crosslinked.

An electrophotographic photosensitive member comprising a support, an electroconductive layer, an undercoat layer, a charge generating layer, and a hole transporting layer in this order, wherein when an ionization potential of the electroconductive layer is defined as IPc, the IPc is 5.4 to 5.8 eV, and when an ionization potential of the undercoat layer is defined as IPu, the IPu is 6.0 eV or more, wherein the undercoat layer comprises an electron transporting compound and a compound (?), and when an ionization potential of the compound (?) is defined as IP?, the IPc, the IPu, and the IP? satisfy relation (1):

IPu?IPc>IP??IPc(1).

Here is provided a method of printing on a substrate, the method comprising: providing a substrate, wherein the substrate has been primed by a primer composition comprising water, an epoxide crosslinker, polyethyleneimine and a glycol co-solvent, the primer composition having formed a primer layer on the substrate, and printing an electrostatic ink on the primer layer. A fluid set comprising the primer composition and an electrostatic ink is also described herein.

Provided is an electrophotographic apparatus including: an electrophotographic photosensitive member; and an intermediate transfer belt that is allowed to be brought into abutment against the electrophotographic photosensitive member, wherein the electrophotographic photosensitive member contains polytetrafluoroethylene particles, a binding material, and a polymer A including a specific structural unit, and wherein the intermediate transfer belt contains a perfluoropolyether, a binding material, and a polymer B including a specific structural unit.

The present disclosure relates to a process for printing a substrate. The process comprises applying an analogue primer over a print substrate. A transparent electrophotographic composition comprising a coupling agent is electrophotographically printed on the primer as a coupling layer. An electrophotographic ink composition is then printed on the coupling layer to form an image layer. The coupling layer is disposed between the primer and image layer and in contact with each of the primer and image layer.

Described herein is a process for preparing a flexible printed material. The process may comprise providing a flexible print substrate comprising a primer on a surface of the print substrate, the primer comprising a primer resin; printing an ink composition comprising a thermoplastic resin onto the primer on the surface of the print substrate; and depositing a cross-linking composition comprising a cross-linker onto the printed ink composition disposed on the primer such that the thermoplastic resin of the ink composition is crosslinked and the primer resin of the primer is crosslinked.

A method for determining coat weight of a transparent primer coating for liquid electrophotographic printing processes is described, in which an optical brightening agent is added to an aqueous transparent primer composition in an amount of less than 0.1 wt. % based on the total solids content of the primer composition to produce a test composition, the test composition is applied onto a test substrate to produce a transparent primer coating, the fluorescence of the transparent primer coating is measured, and the coat weight of the transparent primer coating based on the fluorescence of the transparent primer coating is determined.