An ensemble of spin defect centers or other atom-like quantum systems in a solid-state host can be used as a compact alternative for an atomic clock thanks to an architecture that overcomes magnetic and temperature-induced systematics. A polariton-stabilized solid-state spin clock hybridizes a microwave resonator with a magnetic-field-insensitive spin transition within the ground state of a spin defect center (e.g., a nitrogen vacancy center in diamond). Detailed numerical and analytical modeling of this polariton-stabilized solid-state spin clock indicates a potential fractional frequency instability below 10.sup.-13 over a 1-second measurement time, assuming present-day experimental parameters. This stability is a significant improvement over the state-of-the-art in miniaturized atomic vapor clocks.

An ensemble of spin defect centers or other atom-like quantum systems in a solid-state host can be used as a compact alternative for an atomic clock thanks to an architecture that overcomes magnetic and temperature-induced systematics. A polariton-stabilized solid-state spin clock hybridizes a microwave resonator with a magnetic-field-insensitive spin transition within the ground state of a spin defect center (e.g., a nitrogen vacancy center in diamond). Detailed numerical and analytical modeling of this polariton-stabilized solid-state spin clock indicates a potential fractional frequency instability below 10.sup.-13 over a 1-second measurement time, assuming present-day experimental parameters. This stability is a significant improvement over the state-of-the-art in miniaturized atomic vapor clocks.

In a general aspect, a vapor cell is presented that includes a dielectric body. The dielectric body has a surface that defines an opening to a cavity in the dielectric body. The vapor cell also includes a vapor or a source of the vapor in the cavity of the dielectric body. An optical window covers the opening of the cavity and has a surface bonded to the surface of the dielectric body to form a seal around the opening. The seal includes metal-oxygen bonds formed by reacting a first plurality of hydroxyl ligands on the surface of the dielectric body with a second plurality of hydroxyl ligands on the surface of the optical window.

One embodiment includes a vapor cell for an atomic physics-based sensor system. The vapor cell includes a cell wall formed from an approximately transparent material. The cell wall can enclose an alkali metal vapor and can include an inner surface and an outer surface. The vapor cell can also include at least one structural feature provided on at least one of the inner surface and the outer surface of the cell wall and extending along a portion of the respective at least one of the inner surface and the outer surface.

One embodiment includes a vapor cell for an atomic physics-based sensor system. The vapor cell includes a cell wall formed from an approximately transparent material. The cell wall can enclose an alkali metal vapor and can include an inner surface and an outer surface. The vapor cell can also include at least one structural feature provided on at least one of the inner surface and the outer surface of the cell wall and extending along a portion of the respective at least one of the inner surface and the outer surface.

A miniature atomic clock with pulse mode operation. The clock includes: a local oscillator; a dual-frequency laser source; a pulsing element to pulse the output signal from the source according to a Ramsey-type interrogation sequence having pulses with duration T1 separated by intervals with duration T2; an alkaline vapour microcell; a photodiode; a feedback control loop for controlling the microwave frequency of the local oscillator; and a feedback control loop for controlling the optical frequency of the source by using a pulse control block receiving the output signal from the photodiode and the interrogation sequence, and providing a correction signal to the source. During the period T1, the block extracts an error signal from the output signal received from the photodiode and generates the correction signal from the error signal. During the period T2, the block resets the error signal to zero and generates the correction signal by extrapolation.

The invention relates to a coherent population trapping (CPT) phase modulation and demodulation method and a system for implementing the method of this invention. The method comprises the following steps: Generating a coherent bichromatic light, in which the relative phase between the two frequency components is modulated with proper modulation depth. The phase modulated coherent bichromatic light interacts with a quantum resonance system, and prepares it alternately into two inverted CPT states. Detecting the transmitted light with a photodetector, two inverted dispersive CPT signals in two detection windows are observed. With synchronous phase demodulation, a CPT error signal is obtained, which is used for locking the local oscillator to implement a CPT atomic clock.

The invention relates to a differential detection of double-modulation (DM) CPT method and a system for implementing the method of this invention. The method comprises the following steps: Generating a coherent bichromatic light, in which the polarization and the relative phase are synchronously modulated. The DM light interacts with a quantum resonance system and prepares it into a CPT state. Then the polarization of coherent bichromatic light is switched from circular polarization to linear polarization. After interacting with the CPT state prepared in the previous stage, the constructive and destructive quantum interference occur simultaneously. The polarization of the transmitted light from the quantum resonance system is converted and spatially separated. Then two CPT signals, detected by balanced photodetectors, are observed with constructive and destructive interference respectively. Finally, a differential CPT signal with high signal-to-noise ratio is obtained by subtracting the above-mentioned two CPT signals.

Provided is an atomic vapor cell, for atomic or molecular spectroscopy, optical pumping, and/or spin-based atomic sensing, that includes a host substrate and defined there within a buried or non-buried chamber laser written in the host substrate without the need of a mask or photoresist, with either planar or three-dimensional geometry, and intended to contain an atomic vapor.

Also provided are an integrated atomic/photonic device and an apparatus, in both cases including the presently disclosed atomic vapor cell, and a method for fabricating the presently disclosed atomic vapor cell.

Disclosed is a device for interaction between a laser beam and a hyperfine energy transition of a chemical species. The device further includes an electro-optic modulator with a single sideband with an input optical waveguide suitable for receiving a source laser beam and an output optical waveguide suitable for generating an output laser beam and an electronic system suitable for generating and applying, simultaneously, a first modulated electrical signal, sin(Ω.sub.1t)) to a first hyperfrequency pulse on a first high-frequency electrode of the electro-optic modulator and, respectively, another modulated electrical signal, cos(Ω.sub.1t)) to the first pulse on another high-frequency electrode of the electro-optic modulator, in such a way as to frequency-switch the output laser beam to a first optical frequency offset from the first pulse with respect to the initial optical frequency.