The present invention relates to an iodine (I.sub.2) or bromine (Br.sub.2) adsorbent including a zeolite having a Si/Al ratio of 15 or greater; an I.sub.2 or Br.sub.2 carrier including the I.sub.2 or Br.sub.2 adsorbent; a column filled with the I.sub.2 or Br.sub.2 adsorbent; a article composed of the I.sub.2 or Br.sub.2 adsorbent or having the I.sub.2 or Br.sub.2 adsorbent attached thereto; a method for adsorbing or removing I.sub.2 or Br.sub.2 using the I.sub.2 or Br.sub.2 adsorbent; an iodine- or bromine-containing zeolite composite including a porous zeolite and iodine (I.sub.2) or bromine (Br.sub.2) confined in the pores of the zeolite; a semiconductor material including the iodine- or bromine-containing zeolite composite; and a method for preparing an iodine- or bromine-containing product using the iodine- or bromine-containing zeolite composite.

A process for selectively separating a metallic constituent from other metals and other materials accompanying the metallic constituent in a mixture is described. The process comprises the step of providing the mixture in an aqueous solution such that the metallic constituent forms a complex anion in the solution. One or more of the other metals forms a cation or a complex cation in the solution. Another step includes contacting the solution with one or more additives to form layered double hydroxide (LDH) material in situ such that the complex anion is intercalated within interlayers of the LDH material and wherein one or more of the other metals are incorporated into the LDH material's crystal structure or matrix. Another step involves the addition of an LDH to an aqueous solution. The process involves selectively recovering the metallic constituent from the interlayer of the LDH by subjecting the LDH to a recovery treatment step(s) and as required, methods to modify the LDH to facilitate metal separation and recovery or contaminant stabilisation.

Methods are provided for characterizing samples containing chemical elements such as rare earth elements, actinides, and heavy transition metals by treating the samples to form volatile complexes of the elements (e.g., -diketonate complexes or other organic ligand complexes of the elements) and then analyzing the complexes, for example, via gas-phase thermochromatography. Also provided are methods for separating and/or recovering such chemical elements. The methods produce less waste and can be performed more rapidly than conventional liquid extraction methods and can provide separated elements of high purity (e.g., 99.9999% purity).

Methods are provided for characterizing samples containing chemical elements such as rare earth elements, actinides, and heavy transition metals by treating the samples to form volatile complexes of the elements (e.g., -diketonate complexes or other organic ligand complexes of the elements) and then analyzing the complexes, for example, via gas-phase thermochromatography. Also provided are methods for separating and/or recovering such chemical elements. The methods produce less waste and can be performed more rapidly than conventional liquid extraction methods and can provide separated elements of high purity (e.g., 99.9999% purity).

There is provided an adhesion restraint method of a radionuclide to a carbon steel material of an atomic energy plant, in which an adhesion restraint effect of the radionuclide to the carbon steel material can continue for a longer term. A film forming apparatus is connected to a carbon steel purification system pipe of a BWR plant. A nickel formate aqueous solution and hydrazine are injected into a circulation pipe of the film forming apparatus. An aqueous solution including nickel formate and hydrazine is guided into a purification system pipe subjected to chemical decontamination, and a nickel metal film is formed on an inner surface of the pipe. A platinum ion aqueous solution and hydrazine are injected into the circulation pipe, and an aqueous solution including a platinum ion and hydrazine is supplied to the purification system pipe so as to adhere platinum to the surface of a nickel metal film. The film forming apparatus is detached from the purification system pipe, and the BWR plant is started. Reactor water of 200 C. or higher is guided into the purification system pipe, and thus the nickel metal film is converted into a nickel ferrite film which is not melted even by the adhering platinum and is stable.

A method for treating before calcination a nitric aqueous solution comprising at least one radionuclide and ruthenium is provided. The method comprises a step for adding to the solution a compound selected from lignins, lignocelluloses, optionally as salts and mixtures thereof.

A method for treating before calcination a nitric aqueous solution comprising at least one radionuclide and ruthenium is provided. The method comprises a step for adding to the solution a compound selected from lignins, lignocelluloses, optionally as salts and mixtures thereof.

A method of using hydrogen- or lithium-containing manganese oxide having a spinel crystal structure as a tritium adsorbent to trap tritium from tritium-containing water makes it possible to inexpensively separate tritium from water.

A method of using hydrogen- or lithium-containing manganese oxide having a spinel crystal structure as a tritium adsorbent to trap tritium from tritium-containing water makes it possible to inexpensively separate tritium from water.

Disclosed are an apparatus and a method for supplying a pulse to solvent extraction column (hereinafter, pulsed column). More particularly, the present invention relates to a low cost apparatus with a simple method for stably supplying a pulse to a pulsed column, which is employed as unit equipment in a solvent extraction process. The apparatus for supplying a pulse to the pulsed column having a first solvent inlet and a second solvent outlet at the low part of the pulsed column, and a second solvent inlet and a first solvent outlet at the top part of the pulsed column thereof, includes: a diaphragm pump actuated by using electric power or compressed air, and having a discharge part and a suction part, in which one of the discharge part and the suction part is blinded while the remaining one thereof is connected to the pulsed column via a pulse supply line.