The present disclosure provides a method for detecting thermal sealing defects of a container during its transportation along a process line. The method is particularly suitable for containers caped with a cap liner and sealed with an inner seal. The method makes use of a high frequency heat (e.g. by a high frequency heat induction unit) to cause eddy current in the inner seal after which there is sensing by an IR imager of radiation emitted from the conductive innerseal to generate sensed IR image data indicative of the sensed radiation. The sensing is characterized by at least one of (i) a time window of a sensing session of between 50 msec to 300 msec during which said container is being transported through the FOV; and (ii) a sensing range of a wavelength spectrum region from 2 μm to 6 μm. The IR data is then processed so as to generate output data indicative of the presence or absence of at least one defect in the sealing of the container by said innerseal.

The present disclosure provides a method for detecting thermal sealing defects of a container during its transportation along a process line. The method is particularly suitable for containers caped with a cap liner and sealed with an inner seal. The method makes use of a high frequency heat (e.g. by a high frequency heat induction unit) to cause eddy current in the inner seal after which there is sensing by an IR imager of radiation emitted from the conductive innerseal to generate sensed IR image data indicative of the sensed radiation. The sensing is characterized by at least one of (i) a time window of a sensing session of between 50 msec to 300 msec during which said container is being transported through the FOV; and (ii) a sensing range of a wavelength spectrum region from 2 μm to 6 μm. The IR data is then processed so as to generate output data indicative of the presence or absence of at least one defect in the sealing of the container by said innerseal.

A method for determining the total organic carbon in a sample which includes mixing the sample with a reagent containing at least one acid effective for reacting with inorganic carbon-containing materials in the sample, and at least one oxidizing agent effective for oxidizing organic carbon-containing materials in the sample in the presence of ultraviolet radiation, and detecting the carbon dioxide generated, is described. The at least one acid may include phosphoric acid, while the oxidizing agent may include sodium persulfate. In accordance with an embodiment of the inventive concept, the sample is first injected into a reaction chamber, which is continuously flushed with carbon dioxide free gas with no UV light present, and CO.sub.2 generated from any inorganic carbon in the sample as carbonates is flowed through the detector, and may be recorded. Subsequent to this step, the UV light is passed through the reaction chamber and CO.sub.2 generated from the reaction of the at least one oxidizing agent with the organic material in the solution in the presence of ultraviolet radiation, is flowed through the detector, which may be a non-dispersive infrared detector, after the reaction chamber is sparged using a carbon dioxide free gas, and recorded.

Pressure variations within a solid propellant rocket motor produce like variations in the optical radiance of the motor exhaust plume. The periodicity of the variation is related to the length L of the rocket motor or speed of sound in the rocket motor combustion chamber to length ratio a/L. The optical radiance is collected and converted to electrical signals that are sampled at or above the Nyquist rate. An array of single-pixel photo detectors is well suited to provide amplitude data at high sample rates. The sampled data from the one or more detectors is assembled to form a high fidelity time sequence. A window of sampled data is processed to form a signal frequency spectrum. The mode structure in the frequency spectrum is related to the rocket motor length or speed of sound in the rocket motor chamber to length ratio. The rocket motor length or speed of sound to length ratio is used alone or in combination with other information to either classify or identify the rocket motor.

Pressure variations within a solid propellant rocket motor produce like variations in the optical radiance of the motor exhaust plume. The periodicity of the variation is related to the length L of the rocket motor or speed of sound in the rocket motor combustion chamber to length ratio a/L. The optical radiance is collected and converted to electrical signals that are sampled at or above the Nyquist rate. An array of single-pixel photo detectors is well suited to provide amplitude data at high sample rates. The sampled data from the one or more detectors is assembled to form a high fidelity time sequence. A window of sampled data is processed to form a signal frequency spectrum. The mode structure in the frequency spectrum is related to the rocket motor length or speed of sound in the rocket motor chamber to length ratio. The rocket motor length or speed of sound to length ratio is used alone or in combination with other information to either classify or identify the rocket motor.

Mechanical properties of materials fabricated with additive manufacturing process are determined through optical monitoring in real time. A plasma generated in a zone where a laser interacts with deposited material is monitored using optical emission spectroscopy to generate one or more plasma spectral lines. The emission lines are analyzed to determine the hardness, micro-hardness, yield/residual stress, tensile strength, or other mechanical characteristics of the material. The composition may be an alloy such as an aluminum-magnesium alloy, including 7000 series aluminum alloys. The mechanical property may be derived from a change in a ratio of the plasma spectral lines, including a change in a ratio of ionic and neutral magnesium (Mg) associated with a 7000 series aluminum alloy. The apparatus and methods are extendable to other alloys and compositions.

The present disclosure is directed to a system and a method for hydride generation. In some embodiments, the system includes an assembly for introducing hydride generation reagents into a mixing path or mixing container, where the assembly includes first chamber configured to contain a first hydride generation reagent and a second chamber configured to contain a second hydride generation reagent. A first plunger is configured to translate within the first chamber and cause a displacement of the first hydride generation reagent, and a second plunger is configured to translate within the second chamber and cause a displacement of the second hydride generation reagent. The assembly further includes base coupling the first plunger and the second plunger together.

A method for preparing a sample of organic material for laser induced breakdown spectroscopy (LIBS) may include obtaining granular organic material, forming a portion of the granular organic material into a sample pellet, and searing the organic material. The searing may include searing only an exposed end surface of the sample pellet on which LIBS analysis is to be performed. The method may include pressing the seared sample pellet to consolidate the material comprising the seared end surface.

Systems and methods for laser stimulated lock-in thermography (LLT) crack detection are provided. The system includes a spatial light modulator and a controller. The spatial light modulator reflects a laser beam to focus the laser beam onto a sample for detection of a crack, hole or scratch. The controller is coupled to the spatial light modulator and controls operation of the spatial light modulator to switch focus of the laser beam onto the sample between a plurality of LLT focus configurations for detection of the crack, hole or scratch on the sample. The method includes using a first one of the plurality of LLT configurations for coarse scanning of the sample to detect a crack, hole or scratch on the sample and, when a crack, hole or scratch is detected on the sample, switching to a second one of the plurality of LLT configurations for fine scanning of the crack, hole or scratch on the sample to determine one or more parameters of the crack, hole or scratch on the sample.

Systems and methods for laser stimulated lock-in thermography (LLT) crack detection are provided. The system includes a spatial light modulator and a controller. The spatial light modulator reflects a laser beam to focus the laser beam onto a sample for detection of a crack, hole or scratch. The controller is coupled to the spatial light modulator and controls operation of the spatial light modulator to switch focus of the laser beam onto the sample between a plurality of LLT focus configurations for detection of the crack, hole or scratch on the sample. The method includes using a first one of the plurality of LLT configurations for coarse scanning of the sample to detect a crack, hole or scratch on the sample and, when a crack, hole or scratch is detected on the sample, switching to a second one of the plurality of LLT configurations for fine scanning of the crack, hole or scratch on the sample to determine one or more parameters of the crack, hole or scratch on the sample.