Patent classifications
G01N24/081
Characterizing Effects Of CO2 Chemical Reaction With Rock Minerals During Carbon Capture And Sequestration
A method for measuring a carbon capture and sequestration site. The method may comprise acquiring one or more core samples from a carbon capture and sequestration site, performing a nuclear magnetic resonance (NMR) measurement on the one or more core samples to form a first NMR measurementperforming a surface roughness measurement on the one or more core samples to determine a Rs,.sub.before wherein the Rs,.sub.before is a surface roughness of the one or more core samples before the one or more core samples are aged in a cell, and determining at least one property of the one or more core samples from at least the first NMR measurement and the Rs,.sub.before.
SYSTEMS AND METHODS FOR DETERMINING SURFACTANT IMPACT ON RESERVOIR WETTABILITY
Implementations described and claimed herein provide systems and methods for determining surfactant impact on reservoir wettability. In one implementation, a nuclear magnetic resonance T1 measurement of a sample is obtained before surfactant imbibition is applied to the sample, and a second nuclear magnetic T2 measurement of the sample is made after forced imbibition of the surfactant. Moreover, another nuclear magnetic resonance T1 measurement (e.g., omitting surfactant imbibition) can be obtained simultaneously with the nuclear magnetic resonance T2 measurement using a twin core sample. The nuclear magnetic resonance T1 measurement and the nuclear magnetic resonance T2 measurement are captured under simulated reservoir conditions. A fluid typing map is generated using the nuclear magnetic resonance T1 measurement and the nuclear magnetic resonance T2 measurement. An impact of the surfactant on fluid producibility is determined based on the fluid typing map.
Measuring Gas in Shale Reservoirs
Methods for determining a volume of stored gas within a rock sample includes loading a rock sample into an overburden cell. A hydrocarbon gas at a gas pressure is applied to the rock sample and a confining fluid at a confining pressure is applied to the overburden cell. The confining pressure and the gas pressure are increased until a first pressure and temperature condition is met. With the rock sample maintained at the first temperature and pressure condition, a nuclear magnetic resonance spectrometer is used to scan the rock sample and measure a hydrocarbon gas volume within the rock sample. This measured hydrocarbon gas volume is then corrected using a Real Gas Index to determine the volume of stored gas within the rock sample.
Magnetic resonance transmitter
A transmitter for a magnetic resonance (MR) system, such as nuclear magnetic resonance (NMR) system, is described herein. The transmitter includes a coil for applying NMR pulse sequences to a substance. The coil includes a first coil section and a second coil section. The first coil section and second coil section pass current in opposite polarity. The transmitter may also include a transmitter circuit for generating the NMR pulse sequences and providing the NMR pulse sequences to the coil. The transmitter circuit includes a first switch that selectively powers the first coil section and a second switch that selectively powers the second coil section. Operation of the first switch and the second switch generates the NMR pulse sequences.
Methods for quantitative characterization of asphaltenes in solutions using two-dimensional low-field NMR measurement
A method for determining the concentration of asphaltenes in a solution is described. A model is first established for estimating the concentration of asphaltenes in a solution based on multiple samples of solutions of asphaltenes in the solvent in which the concentrations are known. The multiple samples have varying concentrations of asphaltenes. The diffusivity and relaxation time are measured for each sample using two-dimensional NMR. The ratio of diffusivity to relaxation time for each sample is then calculated. A linear equation is determined to fit the relationship between the ratio of diffusivity to relaxation time and the asphaltene concentration by weight for the multiple samples, thus creating the model. For a given solution sample for which the concentration of asphaltenes is desired to be determined, diffusivity and relaxation time are determined using two-dimensional NMR, and the ratio of diffusivity to relaxation time is calculated. This ratio is then used with the model, so that the linear equation can be solved for the asphaltene concentration in the given solution sample.
Nuclear magnetic resonance systems and methods for characterization of borehole materials
An apparatus (and method) for automated NMR relaxation measurements on borehole materials (e.g., drill cuttings, sidewall cores and whole cores) includes a sample cassette and a sample transfer system operating synchronized with the NMR experiment. The apparatus implements an automatic calibration, adaptive data stacking and automated measurements of the sample volume for irregular shaped samples. The measurements throughput may be increased by creating more than one excitation/detection volume during a measurement cycle. The NMR surface data may be interpreted together with other bulk sensitive measurement data (e.g. natural gamma ray spectroscopy) or/and downhole data to evaluate earth formations while drilling an oil well.
System and Method for Predicting Viscosity of Heavy Oil Formations
This disclosure describes systems and methods to predict viscosity of heavy oil in a geological formation, even when the geological formation also contains water such as clay-bound water, using a downhole nuclear magnetic resonance (NMR) tool. The downhole NMR tools may obtain responses include distributions of a first relaxation time T1, a second relaxation time T2, or diffusion, or a combination of these. The responses of the NMR measurements that are due to water are separated from the responses of the NMR measurements that are due to heavy oil. The responses of the NMR measurements due to heavy oil are then related to likely values of viscosity of the heavy oil based on empirical or simulated measurements.
System and method for alkylation process analysis
A method and apparatus is provided for concentration determination of at least one component in an acid catalyst for hydrocarbon conversion containing an unknown concentration of an acid, an acid-soluble-oil (ASO), and water. An instrument configured for measuring a property of the acid catalyst, has responsivities to concentrations of one of the acid, ASO, and water, substantially independent of the concentrations of the others of the acid catalyst, ASO, and water. A temperature detector is configured to generate temperature data for the acid catalyst. A processor is configured to capture data generated by the temperature detector and the instrument, and to use the data in combination with a model to determine a temperature compensated concentration of the one of the acid, the ASO, and the water. Optionally, one or more other instruments configured for measuring other properties of the liquid mixture may also be used.
Methods of nuclear magnetic resonance measurement of crushed porous media
A method of a nuclear magnetic resonance measurement of a crushed porous media sample, including where the crushed pieces of the sample are not smaller than the pore size of the porous media, the surfaces of the sample are wet with a liquid and the pores of the sample are saturated with a fluid, subjecting the sample to a centrifugal force, performing a nuclear magnetic resonance measurement of the sample, and determining a petrophysical property of the sample from data acquired from the acquisition scan.
Nuclear magnetic flowmeter and method for operating a nuclear magnetic flowmeter
A nuclear magnetic flowmeter (1) for determining the flow of a medium flowing through a measuring tube (2), having a magnetic field generator (3) having permanent magnets for generating a magnetic field interfusing the medium over a magnetic field section L.sub.M, having a pre-magnetization section L.sub.VM located within the magnetic field section L.sub.M and having a measuring device also located in the magnetic field section L.sub.M including a coil-shaped antenna (4) with the length L.sub.1 serving as a measuring antenna. At least one coil-shaped antenna (5) is provided in the pre-magnetization section L.sub.VM for generating a pulse or pulse sequence spoiling the magnetization of the medium in the direction of the magnetic field.