Polarizable diamond materials and methods for obtaining nuclear magnetic resonance spectra of samples external to the diamond materials are described. The diamond materials can include .sup.12C, .sup.13C, substitutional nitrogen, and nitrogen vacancy defects in a crystalline lattice, wherein the substitutional nitrogen concentration is between 10 ppm and 200 ppm, the nitrogen vacancy concentration is between 10 ppb and 10 ppm, and the .sup.13C concentration is greater than 1.1% and not more than 25%. Methods for obtaining nuclear magnetic resonance spectra can include optically pumping a diamond material to generate electron spin hyperpolarization in nitrogen vacancy centers, transferring the electron spin hyperpolarization to nuclei of the sample, and generating a nuclear magnetic resonance spectrum by applying a magnetic field to the sample, exciting the sample with a radio frequency pulse, and detecting a nuclear magnetic resonance response from the sample.

A system for hyperpolarizing a substance is provided. The system includes a cryostat and a polarizer. The cryostat is operative to generate radicals within the substance by exposing the substance to electromagnetic radiation. The polarizer is operative to hyperpolarize the substance via the radicals. Once the substance is polarized, the radicals contained within the substance are quenched by adjusting a temperature of the substance to greater than or equal to a melting point of the substance. In embodiments, the polarizer may then rapidly freeze the substance.

Attenuation of microwaves is reduced or prevented when vacuum windows are provided in microwave waveguides of a DNP-NMR probe. A DNP-NMR probe has an inner container and an outer container. The inner container has therein a sample tube containing a sample to which radicals are added. The outer container keeps a space between the outer container and the inner container in the outer container in a vacuum state. The outer container has an outer container waveguide that has a vacuum window at an inner end portion and guides microwaves. The inner container has a vacuum window facing the vacuum window of the outer container waveguide through vacuum, and guides microwaves transmitted from the outer container waveguide to the sample. The window-to-window distance between the vacuum window of the outer container and the vacuum window of the inner container is adjusted by means of adjustment bolts.

A coil facility for a magnetic resonance installation and a magnetic resonance installation having such a coil facility are provided. The coil facility in this case includes a double-resonant transmit resonator for two frequencies and a first receiver and a second receiver, each for one of the two frequencies. The coil facility has an actuator system for effecting a relative spatial transposition of the transmit resonator, the first receiver, and the second receiver into various settings. In a first setting, only the first receiver, and in a second setting, only the second receiver, for receiving corresponding MR signals is arranged in an examination space that is at least sectionally surrounded by the transmit resonator.

A coil facility for a magnetic resonance installation and a magnetic resonance installation having such a coil facility are provided. The coil facility in this case includes a double-resonant transmit resonator for two frequencies and a first receiver and a second receiver, each for one of the two frequencies. The coil facility has an actuator system for effecting a relative spatial transposition of the transmit resonator, the first receiver, and the second receiver into various settings. In a first setting, only the first receiver, and in a second setting, only the second receiver, for receiving corresponding MR signals is arranged in an examination space that is at least sectionally surrounded by the transmit resonator.

A system for hyperpolarizing a substance is provided. The system includes a cryostat and a polarizer. The cryostat is operative to generate radicals within the substance by exposing the substance to electromagnetic radiation. The polarizer is operative to hyperpolarize the substance via the radicals. Once the substance is polarized, the radicals contained within the substance are quenched by adjusting a temperature of the substance to greater than or equal to a melting point of the substance. In embodiments, the polarizer may then rapidly freeze the substance.

A method tor the preparation of a highly polarized nuclear spins containing sample of an organic or inorganic material, containing H or OH groups or adsorbed water molecules. Such highly polarized nuclear spins containing samples can be subjected to nuclear magnetic resonance (NMR) measurement and/or can be thawed and immediately administered to an individual undergoing a magnetic resonance imaging (MRI) scan. The method is based on generating unstable radicals on the surface of the sample in the presence of ionized environment followed by cooling the sample to cryogenic temperatures. A device for carrying out a particular step of said method is also discloses.

A method tor the preparation of a highly polarized nuclear spins containing sample of an organic or inorganic material, containing H or OH groups or adsorbed water molecules. Such highly polarized nuclear spins containing samples can be subjected to nuclear magnetic resonance (NMR) measurement and/or can be thawed and immediately administered to an individual undergoing a magnetic resonance imaging (MRI) scan. The method is based on generating unstable radicals on the surface of the sample in the presence of ionized environment followed by cooling the sample to cryogenic temperatures. A device for carrying out a particular step of said method is also discloses.

A composition containing (1) a porous material and (2) a polarization source for dynamic nuclear polarization containing a molecule capable of being in an excited triplet state. According to the composition, a dynamic nuclear polarization system that has a long spin-lattice relaxation time and can readily introduce the polarization object thereto can be provided.

A composition containing (1) a porous material and (2) a polarization source for dynamic nuclear polarization containing a molecule capable of being in an excited triplet state. According to the composition, a dynamic nuclear polarization system that has a long spin-lattice relaxation time and can readily introduce the polarization object thereto can be provided.