This disclosure describes fuel-cladding chemical interaction (FCCI) resistant nuclear fuel elements and their manufacturing techniques. The nuclear fuel elements include two or more layers of different materials (i.e., adjacent barriers are of different base materials) provided on a steel cladding to reduce the effects of FCCI between the cladding and the nuclear material. Depending on the embodiment, a layer may be the structural element (i.e., a layer thick enough to provide more than 50% of the strength of the overall component consisting of the cladding and the barriers) or may be more appropriately described as a liner or coating that is applied in some fashion to a surface of the structural component (e.g., to the cladding, or to a structural form of the fuel).

A nuclear fuel cladding is provided. The nuclear fuel cladding includes a base cladding; and at least one nanomaterial layer deposited on a surface of the base cladding, the nanomaterial layer having an average grain size of between 5 to 400 nanometers. A method of manufacturing nuclear fuel cladding is also provided. The method includes depositing nanoparticles on a base cladding to form at least one nanomaterial layer, the nanoparticles having an average grain size of between 5 to 400 nanometers.

A nuclear fuel cladding is provided. The nuclear fuel cladding includes a base cladding; and at least one nanomaterial layer deposited on a surface of the base cladding, the nanomaterial layer having an average grain size of between 5 to 400 nanometers. A method of manufacturing nuclear fuel cladding is also provided. The method includes depositing nanoparticles on a base cladding to form at least one nanomaterial layer, the nanoparticles having an average grain size of between 5 to 400 nanometers.

Nuclear fuel elements may include: a fuel zone including fuel particles disposed in parallel layers in a matrix including graphite powder; and a shell comprising graphite and surrounding the fuel zone. The fuel particles may include fissile particles, burnable poison particles, breeder particles, or a combination thereof. The fuel zone may include a central region and a peripheral region surrounding the central region, and a fuel particle density of the peripheral region may be greater than a fuel particle density of the central region.

Nuclear fuel elements may include: a fuel zone including fuel particles disposed in parallel layers in a matrix including graphite powder; and a shell comprising graphite and surrounding the fuel zone. The fuel particles may include fissile particles, burnable poison particles, breeder particles, or a combination thereof. The fuel zone may include a central region and a peripheral region surrounding the central region, and a fuel particle density of the peripheral region may be greater than a fuel particle density of the central region.

A method of mass producing nuclear fuel elements may include: forming a graphite base portion of the fuel elements; repeatedly performing a sequence of operations comprising depositing a uniform graphite layer over a previous layer, depositing a layer of particles on the uniform graphite layer within a fuel zone diameter, so that the particles are spaced apart in a predefined pattern, and applying a binder using additive manufacturing methods to bind each layer with successively increasing and then decreasing diameters to form a central portion of fuel elements including a fuel-containing fuel zone; and repeatedly performing a sequence of operations comprising forming a uniform graphite layer on a previous layer and applying a binder using additive manufacturing methods to bind each layer with successively decreasing diameters to form a cap portion of fuel elements. The particles may include one or more of a nuclear fuel material, burnable poison material, or breeder material. The fuel particles may be tri-structural-isotropic (TRISO) particles that do not have an overcoat.

A method of mass producing nuclear fuel elements may include: forming a graphite base portion of the fuel elements; repeatedly performing a sequence of operations comprising depositing a uniform graphite layer over a previous layer, depositing a layer of particles on the uniform graphite layer within a fuel zone diameter, so that the particles are spaced apart in a predefined pattern, and applying a binder using additive manufacturing methods to bind each layer with successively increasing and then decreasing diameters to form a central portion of fuel elements including a fuel-containing fuel zone; and repeatedly performing a sequence of operations comprising forming a uniform graphite layer on a previous layer and applying a binder using additive manufacturing methods to bind each layer with successively decreasing diameters to form a cap portion of fuel elements. The particles may include one or more of a nuclear fuel material, burnable poison material, or breeder material. The fuel particles may be tri-structural-isotropic (TRISO) particles that do not have an overcoat.

The invention relates to compositions and methods for coating a zirconium alloy cladding of a fuel element for a nuclear water reactor. The coating includes a first tier or layer and a second tier or layer. The first layer includes an elemental metal and the second layer is an oxidation-resistant layer that includes elemental chromium. The first layer serves as an intermediate layer between the zirconium alloy substrate and the second layer. This intermediate layer can be effective to improve adhesion of the second layer to the zirconium alloy substrate. The multilayer coating forms a protective layer which provides improved capability for the zirconium alloy cladding to withstand normal and accident conditions to which it is exposed in the nuclear reactor.

The invention relates to compositions and methods for coating a zirconium alloy cladding of a fuel element for a nuclear water reactor. The coating includes a first tier or layer and a second tier or layer. The first layer includes an elemental metal and the second layer is an oxidation-resistant layer that includes elemental chromium. The first layer serves as an intermediate layer between the zirconium alloy substrate and the second layer. This intermediate layer can be effective to improve adhesion of the second layer to the zirconium alloy substrate. The multilayer coating forms a protective layer which provides improved capability for the zirconium alloy cladding to withstand normal and accident conditions to which it is exposed in the nuclear reactor.

Pre-ceramic particle solutions can prepared by a Coordinated-PDC process, a Direct-PDC process or a Coordinated-Direct-PDC process. The pre-ceramic particle solution includes a polymer selected from the group consisting of (i) an organic polymer including a metal or metalloid cation, (ii) a first organometallic polymer and (iii) a second organometallic polymer including a metal or metalloid cation different from a metal in the second organometallic polymer, a plurality of particles selected from the group consisting of (a) a ceramic fuel particle and (b) a moderator particle, a dispersant, and a polymerization initiator. The pre-ceramic particle solution can be supplied to an additive manufacturing process, such as digital light projection, and made into a structure (which is pre-ceramic particle green body) that can then be debinded to form a polymer-derived ceramic sintered body. In some embodiments, the polymer-derived ceramic sintered body is a component or structure for fission reactors.