A device and method is described for analysing the elemental composition of a liquid sample utilizing a combination of electrochemical pre-concentration followed by spectrochemical analysis of analytes in a single device. The device consists of two electrodes for the purpose of pre-concentration of the analyte ions by electrodeposition, a DC power supply/potentiostat/galvanostat, a high voltage power supply capable of creating an electrical discharge such as arc, spark, glow discharge or plasma, a spectrometer capable of recording a spectrum generated during such discharges as well as a pump(s) for pumping the analyte containing solution. Such a device is autonomous, field-deployable and capable of providing online analysis.

An aspect of some embodiments of the present invention relates to a plasma chamber for containing a solution electrode glow discharge (SEGD) apparatus, the plasma chamber comprising a hollow body and a lens. The hollow body is configured to enclose a plasma generated between a solid electrode and a solution electrode, and includes at least one viewing port for letting light generated from the plasma leave the hollow body. The lens is disposed at or near the viewing port, the lens being configured to collect light from the plasma and direct the light onto a light receiving unit.

An aspect of some embodiments of the present invention relates to a plasma chamber for containing a solution electrode glow discharge (SEGD) apparatus, the plasma chamber comprising a hollow body and a lens. The hollow body is configured to enclose a plasma generated between a solid electrode and a solution electrode, and includes at least one viewing port for letting light generated from the plasma leave the hollow body. The lens is disposed at or near the viewing port, the lens being configured to collect light from the plasma and direct the light onto a light receiving unit.

A portable device (1) for detecting and quantifying a concentration of a marker, for example TROPONIN I, present in a sample of biological fluid. The device (1) comprises a cartridge (100) adapted to receive the biological fluid sample and comprising at least one reactive agent configured to bind to the marker defining an electrochemiluminescent solution. The cartridge (100) is coupled to an electrode cell (101) configured to supply electrical energy to the electrochemiluminescent solution so as to trigger an electrochemiluminescence reaction of the electrochemiluminescent solution, generating a light signal representative of a concentration value of the marker in the biological fluid sample. The device (1) further comprises an analyzer (200), connectable to the cartridge (100) and configured to receive and analyze at least one property of the light signal so as to quantify a concentration of the marker in the biological fluid.

The present disclosure is for a tool and a method using or making the tool for detection of production or formation water in drilling fluid. The tool includes a sampling chamber to receive a bypass line from a flow line at a well site. The tool further includes spectroscopy components to perform spectroscopy of the drilling fluid bypassed from a flow line into the bypass line. Processing components are provided in the tool to process spectra from the spectroscopy of the drilling fluid and to generate data associated with at least identification formation or production water in the drilling fluid. The tool includes a communication module to transmit the data externally from the tool.

The present disclosure is for a tool and a method using or making the tool for detection of production or formation water in drilling fluid. The tool includes a sampling chamber to receive a bypass line from a flow line at a well site. The tool further includes spectroscopy components to perform spectroscopy of the drilling fluid bypassed from a flow line into the bypass line. Processing components are provided in the tool to process spectra from the spectroscopy of the drilling fluid and to generate data associated with at least identification formation or production water in the drilling fluid. The tool includes a communication module to transmit the data externally from the tool.

To provide an automatic analyzer with improved workability when a flow cell is loaded and unloaded. The automatic analyzer includes: a photomultiplier tube; a board disposed vertically below the photomultiplier tube; and a flow cell disposed vertically below the board. A lower surface of the board has a protrusion portion and/or a recess portion, and an upper surface of the flow cell has a recess portion and/or a protrusion portion. The automatic analyzer includes a pressing member configured to press the flow cell vertically upward from below in a state in which the recess portion and/or the protrusion portion of the flow cell is fitted to the protrusion portion and/or the recess portion of the board.

Methods and systems for the use of a thin-layer spectroelectrochemical cell to detect porphyrins in a wellbore environment are provided. In one embodiment, methods for the use of a thin-layer spectroelectrochemical cell to detect porphyrins in a wellbore environment comprises: positioning a spectroelectrochemical cell in a wellbore penetrating at least a portion of a subterranean formation comprising a downhole fluid; allowing at least a portion of the downhole fluid to flow into the spectroelectrochemical cell; and detecting at least one compound in at least a portion of the downhole fluid, wherein the at least one compound is selected from the group consisting of: a porphyrin, a metalloporphyrin, a porphyrin derivative, a porphyrin-like macrocycle, and any combination thereof.

The specification provides an assay electrode including a composite containing a matrix and a multiplicity of graphene particles dispersed therein.

Provided herein are systems and methods for the detection, quantification, and/or monitoring of analytes in samples. The systems and methods can be used, for example, to track the deposition and electrochemical behavior of individual nanoparticles and nanoparticles clusters clusters in situ with high spatial and temporal resolution. The systems and methods can be used to track the deposition and oxidation of several hundreds to thousands of nanoparticles simultaneously and reconstruct their voltammetric curves at the single nanoparticle level.