A method of determining a thermal state or a thermal state transition of a substance based on how much liquid phase is available is disclosed. The method includes: (a) determining a current thermal state of the substance when the internal combustion engine is switched on based on a tank temperature and on a time interval during which the engine is switched off; and (b) calculating a percentage of the liquid phase in case the thermal state is a mixture of solid phase and liquid phase based on a total mass of the substance in the tank, a heat amount supplied to the tank, a heat exchange of the tank with an external environment; and (c) detecting the thermal state transitions based on said tank temperature and its time derivative and on said percentage of the liquid phase.

Systems and methods for monitoring emissions of a combusted gas are provided. The method includes determining a first net heating value of a flare gas. The method also includes determining a second net heating value of a combustion gas including the flare gas. The second net heating value can be determined based upon the first net heating value and a volumetric flow rate of the flare gas. Based upon the value of the second net heating value, an empirical model or a non-parametric machine learning model can be selected. A combustion efficiency of the combustion gas can be determined using the selected model, the second net heating value, and selected ones of the process conditions and the environmental conditions. Total emissions of the combustion mixture can be further determined from the combustion efficiency and a volumetric flow rate of the combustion gas.

A combustion analyzer configured to simultaneously detect the concentrations of oxygen, carbon monoxide and methane in a combustion process is provided. The combustion analyzer includes an oxygen sensor configured to detect the oxygen in the combustion process and generate a sensor signal indicative of the concentration of oxygen in the combustion process. The combustion analyzer further includes a dual carbon monoxide-methane sensor configured to operate at approximately 400° C. and provide a second sensor signal indicative of methane concentration and at approximately 300° C. to selectively provide a third sensor signal indicative of carbon monoxide concentration. The combustion analyzer finally includes a controller configured to receive the sensor signals, determine the concentration of oxygen, and generate a carbon monoxide concentration output and methane concentration output based on the dual carbon monoxide-methane sensor signals and the concentration of oxygen.

A combustion analyzer configured to simultaneously detect the concentrations of oxygen, carbon monoxide and methane in a combustion process is provided. The combustion analyzer includes an oxygen sensor configured to detect the oxygen in the combustion process and generate a sensor signal indicative of the concentration of oxygen in the combustion process. The combustion analyzer further includes a dual carbon monoxide-methane sensor configured to operate at approximately 400° C. and provide a second sensor signal indicative of methane concentration and at approximately 300° C. to selectively provide a third sensor signal indicative of carbon monoxide concentration. The combustion analyzer finally includes a controller configured to receive the sensor signals, determine the concentration of oxygen, and generate a carbon monoxide concentration output and methane concentration output based on the dual carbon monoxide-methane sensor signals and the concentration of oxygen.

A combustion analyzer configured to simultaneously detect the concentrations of oxygen, carbon monoxide and methane in a combustion process is provided. The combustion analyzer includes an oxygen sensor configured to detect the oxygen in the combustion process and generate a sensor signal indicative of the concentration of oxygen in the combustion process. The combustion analyzer further includes a dual carbon monoxide-methane sensor configured to operate at approximately 400° C. and provide a second sensor signal indicative of methane concentration and at approximately 300° C. to selectively provide a third sensor signal indicative of carbon monoxide concentration. The combustion analyzer finally includes a controller configured to receive the sensor signals, determine the concentration of oxygen, and generate a carbon monoxide concentration output and methane concentration output based on the dual carbon monoxide-methane sensor signals and the concentration of oxygen.

A combustion analyzer configured to simultaneously detect the concentrations of oxygen, carbon monoxide and methane in a combustion process is provided. The combustion analyzer includes an oxygen sensor configured to detect the oxygen in the combustion process and generate a sensor signal indicative of the concentration of oxygen in the combustion process. The combustion analyzer further includes a dual carbon monoxide-methane sensor configured to operate at approximately 400° C. and provide a second sensor signal indicative of methane concentration and at approximately 300° C. to selectively provide a third sensor signal indicative of carbon monoxide concentration. The combustion analyzer finally includes a controller configured to receive the sensor signals, determine the concentration of oxygen, and generate a carbon monoxide concentration output and methane concentration output based on the dual carbon monoxide-methane sensor signals and the concentration of oxygen.

A portable, compact, real-time and accurate sensor and method for deriving a physicochemical property of a liquid fuel, such as cetane number, carbon content, carbon/hydrogen (C/H) atomic ratio, or heating value (net heat of combustion). The sensor comprises a constant-volume ignition chamber equipped for measuring ignition delay and magnitude of a peak rise in pressure or temperature following dispensation of a liquid fuel into the chamber. The sensor utilizes air at atmospheric pressure and microliter quantities of fuel. The sensor can be implemented in real-time refinery operations for blending diesel fuels that meet government mandated cetane number standards as well as in applications for standardizing jet, biodiesel, and synthetic fuels, which presently are not classified by any physicochemical property.

A portable, compact, real-time and accurate sensor and method for deriving a physicochemical property of a liquid fuel, such as cetane number, carbon content, carbon/hydrogen (C/H) atomic ratio, or heating value (net heat of combustion). The sensor comprises a constant-volume ignition chamber equipped for measuring ignition delay and magnitude of a peak rise in pressure or temperature following dispensation of a liquid fuel into the chamber. The sensor utilizes air at atmospheric pressure and microliter quantities of fuel. The sensor can be implemented in real-time refinery operations for blending diesel fuels that meet government mandated cetane number standards as well as in applications for standardizing jet, biodiesel, and synthetic fuels, which presently are not classified by any physicochemical property.

A multi-component fluid composition and concentration sensor system and method. The system can be configured with multiple sensing elements whereby each specifically responds to different combinations and concentrations of multiple fluid component mixtures. Because these responses can be captured and committed to a lookup table during an initial calibration sequence, subsequent measurements of unknown mixtures of the same gases will match known states found in the lookup table and the fluid concentrations can be deduced. The number of sensing elements with unique responses to the fluid mixtures should equal the number of unknown fluids that are active on the sensing surfaces, similar to how solving for multiple variables requires no fewer equations than there are unknowns, i.e. 3 equations and 3 variables. A reference surface can also be present in the fluid composition and concentration sensor so that the effects measured by the sensing surfaces can be determined against a relevant control that is not sensitive to the active fluids being measured.

A multi-component fluid composition and concentration sensor system and method. The system can be configured with multiple sensing elements whereby each specifically responds to different combinations and concentrations of multiple fluid component mixtures. Because these responses can be captured and committed to a lookup table during an initial calibration sequence, subsequent measurements of unknown mixtures of the same gases will match known states found in the lookup table and the fluid concentrations can be deduced. The number of sensing elements with unique responses to the fluid mixtures should equal the number of unknown fluids that are active on the sensing surfaces, similar to how solving for multiple variables requires no fewer equations than there are unknowns, i.e. 3 equations and 3 variables. A reference surface can also be present in the fluid composition and concentration sensor so that the effects measured by the sensing surfaces can be determined against a relevant control that is not sensitive to the active fluids being measured.