A nanovoided polymer-based material may include a bulk polymer material defining a plurality of nanovoids and an interfacial film disposed at an interface between each of the plurality of nanovoids and the bulk polymer material. The interfacial film may include one or more layers of material. A method of forming a nanovoided polymer-based material may include (1) forming a bulk polymer material defining a plurality of nanovoids and (2) forming an interfacial film at an interface between each of the plurality of nanovoids and the bulk polymer material. Various other methods, systems, and materials are also disclosed.

In some examples, a method includes forming a material layer on a substrate, partially polymerizing a component of the material layer, to form fluid-filled droplets within a partially polymerized matrix, deforming the material layer to form anisotropic fluid-filled droplets, and further polymerizing the partially polymerized matrix to form an anisotropic voided polymer, including anisotropic voids in a polymer matrix. The anisotropic voids may include anisotropic nanovoids. Example methods may further include depositing electrodes on the anisotropic voided polymer so that at least a portion of the anisotropic voided polymer is located between the electrodes. Examples may include forming electroactive elements including an anisotropic nanovoided polymer, and devices (such as sensors and/or actuators) including electroactive elements.

In some examples, a device includes a multilayer structure, a first electrode, and a second electrode, where the multilayer structure is located at least in part between the first electrode and the second electrode, and the multilayer structure includes a nanovoided polymer layer, and a solid layer. The solid layer may include a non-nanovoided layer. The nanovoided polymer layer may be an electroactive layer. The device may further include a control circuit configured to apply an electrical potential between the first electrode and the second electrode, which may induce a mechanical deformation of the multilayer.

An example device includes a nanovoided polymer element, a first electrode, and a second electrode. The nanovoided polymer element may be located at least in part between the first electrode and the second electrode. In some examples, the nanovoided polymer element may include anisotropic voids. In some examples, anisotropic voids may be elongated along one or more directions. In some examples, the anisotropic voids are configured so that a polymer wall thickness between neighboring voids is generally uniform. Example devices may include a spatially addressable electroactive device, such as an actuator or a sensor, and/or may include an optical element. A nanovoided polymer layer may include one or more polymer components, such as an electroactive polymer.

Apparatus is provided including an acoustic sensor (50) having an optical waveguide (20). The optical waveguide (20) includes a waveguide core (202) having a waveguide core refractive index and a waveguide core photo-elastic coefficient, and an over-cladding layer (204) coupled to the waveguide core (202) and including an optically transparent polymer having an over-cladding refractive index and an over-cladding photo-elastic coefficient. The waveguide core refractive index is greater than the over-cladding refractive index, and the over-cladding photo-elastic coefficient is greater than the waveguide core photo-elastic coefficient. Other applications are also described.

Embodiments of the disclosure are generally directed to systems and methods for switchable electroactive devices for head-mounted displays (HMDs). In particular, a method may include (1) applying an electric field to an electroactive element of an electroactive device via electrodes of the electroactive device that are electrically coupled to the electroactive element to compress the electroactive element, which comprises a polymer material defining nanovoids, such that an average size of the nanovoids is decreased and a density of the nanovoids is increased in the electroactive element, wherein the electroactive device is positioned at a distance from a user's eye, and (2) emitting image light from an emissive device positioned such that at least a portion of the image light is incident on a surface of the electroactive device facing the user's eye.

An example device includes a nanovoided polymer element, which may be located at least in part between the electrodes. In some examples, the nanovoided polymer element may include anisotropic voids, including a gas, and separated from each other by polymer walls. The device may be an electroactive device, such as an actuator having a response time for a transition between actuation states. The gas may have a characteristic diffusion time (e.g., to diffuse half the mean wall thickness through the polymer walls) that is less than the response time. The nanovoids may be sufficiently small (e.g., below 1 micron in diameter or an analogous dimension), and/or the polymer walls may be sufficiently thin, such that the gas interchange between gas in the voids and gas absorbed by the polymer walls may occur faster than the response time, and in some examples, effectively instantaneously.

A mobile system includes a self-supporting platform, a tunable reflective skin or film disposed on and secured to the mobile platform, one or more actuators and a controller. The tunable reflective skin or film includes one or more layers that are at least partially reflective to optical energy at one or more optical wavelengths. The skin or film is substantially flexible and/or stretchable and has an optical reflectivity to incident electromagnetic radiation of a given wavelength which is selectively variable when flexed and/or stretched. The actuators are able to flex and/or stretch the skin or film in response to receipt of a control signal. The controller generates the control signal based on a measured value of the optical reflectivity of the skin or film to the incident electromagnetic radiation of the given wavelength.

Example methods include depositing a precursor layer onto a substrate where the precursor layer includes droplets comprising a polymerizable material, inducing a phase inversion in the precursor layer to obtain a modified precursor layer including droplets of a non-polymerizable liquid within a polymerizable liquid mixture, and polymerizing the polymerizable liquid mixture to obtain a nanovoided polymer element. Examples include devices fabricated using nanovoided polymer elements fabricated using such methods, including electroactive devices such as actuators and sensors.

An optical element includes a nanovoided polymer layer having a first refractive index in an unactuated state and a second refractive index different than the first refractive index in an actuated state. Compression or expansion of the nanovoided polymer layer, for instance, can be used to reversibly control the size and shape of the nanovoids within the polymer layer and hence tune its refractive index over a range of values, e.g., during operation of the optical element. Various other apparatuses, systems, materials, and methods are also disclosed.