Methods and materials to fabricate electrochromic including electrochemical devices are disclosed. In particular, emphasis is placed on the composition, fabrication and incorporation of electrolytic sheets in these devices. Composition, fabrication and incorporation of redox layers and sealants suitable for these devices are also disclosed. Incorporation of EC devices in insulated glass system (IGU) windows is also disclosed.

The present invention relates to an electrochromic device, and according to one aspect of the present invention, there is provided an electrochromic device comprising: a first electrode layer, a first electrochromic layer provided on the first electrode layer, an electrolyte layer provided on the first electrochromic layer, a second electrochromic layer provided on the electrolyte layer, and a second electrode layer provided on the second electrochromic layer, wherein it comprises a first auxiliary electrode layer and a second auxiliary electrode layer each provided on each opposite surface of the first electrochromic layer and the second electrochromic layer opposed to each other with the electrolyte layer interposed therebetween, and the first and second auxiliary electrode layers each comprise an electrode portion formed of a metal material and an insulation portion for insulating the electrode portion.

Methods and materials to fabricate electrochromic including electrochemical devices are disclosed. In particular, emphasis is placed on the composition, fabrication and incorporation of electrolytic sheets in these devices. Composition, fabrication and incorporation of redox layers and sealants suitable for these devices are also disclosed. Incorporation of EC devices in insulated glass system (IGU) windows is also disclosed.

An electro-optic cell for an electrochromic device includes an electrochromic medium including an electrochromic compound M having at least one reduced state and at least one oxidized state. The electrochromic compound M can act as both the anodic material and the cathodic material in the electro-optic cell. The electrochromic medium can be capable of reversibly attenuating transmittance of light having a wavelength within a predetermined range.

A method of making an electrochromic device, includes: providing an electrochromic layer comprising a p-type electrochromic material; providing an ion-storage layer comprising an n-type metal oxide; and tuning the ion-storage layer, the electrochromic layer, or both the ion-storage layer and the electrochromic layer, so that when the electrochromic device is operating, the ion-storage layer operates in a minimally color changing mode.

Various embodiments herein relate to electrochromic devices, methods of fabricating electrochromic devices, and apparatus for fabricating electrochromic devices. In a number of cases, the electrochromic device may be fabricated to include a particular counter electrode material. The counter electrode material may include a base anodically coloring material. The counter electrode material may further include one or more halogens. The counter electrode material may also include one or more additives.

Methods and materials to fabricate electrochromic including electrochemical devices are disclosed. In particular, emphasis is placed on the composition, fabrication and incorporation of electrolytic sheets in these devices. Composition, fabrication and incorporation of redox layers and sealants suitable for these devices are also disclosed. Incorporation of EC devices in insulated glass system (IGU) windows is also disclosed.

Ion-storage layers for electrochromic devices (ECDs) that are tuned to be minimally color changing (MCC) during operation of the ECDs. In some embodiments, an ion-storage layer is composed of an n-type metal oxide that complements a p-type electrochromic (EC) layer, such as an EC layer made of a p-type EC polymer. In some embodiments, an ion-storage layer may be tuned to be MCC by configuring an ion-storage layer to have a total charge density that is higher than the total charge density of a corresponding EC layer or to have a coloration efficiency lower than the coloration efficiency of the corresponding EC layer, or both. Methods for preparing ion-storage layers are disclosed, including methods for creating highly structured metal oxide having reduced coloration efficiencies. ECD devices incorporating MCC ion-storage layers are also disclosed.

An electrochromic device includes an optically transparent first substrate, a first transparent conductor disposed on the first substrate, a counter electrode disposed on the first transparent conductor, an optically transparent, ionically conductive first capping layer disposed on the counter electrode, and configured to permit diffusion of alkali metal ions, and to block the diffusion of organic compounds and carbon, an optically transparent second substrate, a second transparent conductor disposed on the second substrate, a working electrode comprising electrochromic nanoparticles disposed on the second transparent conductor, and an electrolyte disposed between the first capping layer and the working electrode.

A laminated substrate for an electrochromic dimmer element includes a glass substrate; and a transparent conductive film. The glass substrate includes a silicon oxide, an aluminum oxide, a boron oxide, an alkaline earth metal oxide, and an alkali metal oxide in a total amount of 90 mol % or more, and includes the alkali metal oxide in a total amount of 12 mol % or less. The transparent conductive film includes an indium oxide film containing tin, and a tin oxide film containing at least one of tantalum, antimony and fluorine, in this order from a glass substrate side. The indium oxide film is formed directly on the glass substrate, a refractive index and an extinction coefficient of the indium oxide film at a wavelength of 1.3 m is less than 0.4, and greater than 0.4, respectively. A film thickness of the tin oxide film is greater than 35 nm.