A window assembly includes an electro-optic element which has a first substantially transparent substrate defining first and second surfaces. The second surface includes a first electrically conductive layer. A second substantially transparent substrate defines third and fourth surfaces. The third surface includes a second electrically conductive layer. A primary seal is disposed between the first and second substrates. The seal and the first and second substrates define a cavity therebetween. An electro-optic medium is disposed in the cavity. The electro-optic medium is switchable such that the electro-optic element is operable between substantially clear and darkened states. An absorptive layer is positioned on the fourth surface of the electro-optic element and a reflective layer is positioned on the absorptive layer.

An electrochromic device includes a chamber defined by a first conductive surface of a first substrate, a second conductive surface of a second substrate, and a sealing member joining the first substrate to the second substrate; an electrochromic medium containing a blue cathodic electroactive compound and up to three anodic electroactive compounds; wherein the electrochromic medium is disposed within the chamber; the anodic electroactive compounds include a green anodic electroactive compound and one or two gray anodic electroactive compounds; and the anodic electroactive compounds include from about 8 mol % to about 15 mol % gray anodic electroactive compounds.

An electrochromic device includes a chamber defined by a first conductive surface of a first substrate, a second conductive surface of a second substrate, and a sealing member joining the first substrate to the second substrate; an electrochromic medium containing a blue cathodic electroactive compound and up to three anodic electroactive compounds; wherein the electrochromic medium is disposed within the chamber; the anodic electroactive compounds include a green anodic electroactive compound and one or two gray anodic electroactive compounds; and the anodic electroactive compounds include from about 8 mol % to about 15 mol % gray anodic electroactive compounds.

According to one embodiment, an illumination device includes an electrochromic element and light sources. The electrochromic element includes a first transparent substrate, a first transparent electrode provided on the first transparent substrate, a second transparent substrate opposing the first transparent substrate, projections provided on the second transparent substrate and projecting toward the first transparent substrate, a second transparent electrode provided on a part of the projection and an electrolyte layer provided between the first transparent substrate and the second transparent substrate and containing an electrochromic material including a reflective material capable of oxidation-reduction.

According to one embodiment, an illumination device includes an electrochromic element and light sources. The electrochromic element includes a first transparent substrate, a first transparent electrode provided on the first transparent substrate, a second transparent substrate opposing the first transparent substrate, projections provided on the second transparent substrate and projecting toward the first transparent substrate, a second transparent electrode provided on a part of the projection and an electrolyte layer provided between the first transparent substrate and the second transparent substrate and containing an electrochromic material including a reflective material capable of oxidation-reduction.

An electro-optic element having enhanced durability by the addition of an additive. The additive may enhance the durability of the electro-optic element by reducing or eliminating the effects of water on species with the electro-optic element, such as the electrolyte. Specifically, the additive may operate to reduce or eliminate the formation and/or accumulation of hydrogen fluoride within the electro-optic element by interaction of the electrolyte with water or alcohol molecules. In some embodiments, the additive may be an organosilicon species, such as (3-cyanopropyl) dimethylfluorosilane.

An electro-optic element having enhanced durability by the addition of an additive. The additive may enhance the durability of the electro-optic element by reducing or eliminating the effects of water on species with the electro-optic element, such as the electrolyte. Specifically, the additive may operate to reduce or eliminate the formation and/or accumulation of hydrogen fluoride within the electro-optic element by interaction of the electrolyte with water or alcohol molecules. In some embodiments, the additive may be an organosilicon species, such as (3-cyanopropyl) dimethylfluorosilane.

An image pickup apparatus including an electrochromic element, wherein the electrochromic element includes a complementary-type EC layer including a solvent and an anodic redox substance and a cathodic redox substance dissolved in the solvent, and image processing is performed based on a charge imbalance current flowing between a first electrode and a second electrode when a voltage lower than the voltage causing a substantial change in the transmittance of the EC layer is applied between the first electrode and the second electrode.

An image pickup apparatus including an electrochromic element, wherein the electrochromic element includes a complementary-type EC layer including a solvent and an anodic redox substance and a cathodic redox substance dissolved in the solvent, and image processing is performed based on a charge imbalance current flowing between a first electrode and a second electrode when a voltage lower than the voltage causing a substantial change in the transmittance of the EC layer is applied between the first electrode and the second electrode.

This disclosure provides compositions of electrochromic dyes, functionalized electrochromic dyes and dye macromers which may be incorporated into electrochromic devices with tailored optical properties. The disclosure provides an electrochromic dye with an attached functionalization group wherein the said dye colors by at least one of oxidation and reduction and contains at least two moieties wherein a first moiety is electrochromic and a second moiety is an electrochromic moiety, an electron donating moiety, or an electron receiving moiety and wherein the functionalization group. This disclosure also provides EC compositions and devices for controlling color.