A wax composition for toner which may give low-temperature fixability and heat storage stability to the toner and has excellent coloring agent dispersibility is provided. A wax composition for toner comprises a wax (a) containing a monoester of a straight-chain monocarboxylic acid and a straight-chain monoalcohol and an ester (b) of glycerin with mixed carboxylic acid composed of straight-chain C12 to C24 monocarboxylic acid having one hydroxyl group and straight-chain C12 to C24 monocarboxylic acid, and the wax (a) containing the monoester of straight-chain monocarboxylic acid and straight-chain monoalcohol has hydroxyl value of 30 or lower.

Provided is a magnetic toner having a toner particle containing a binder resin and a magnetic body, wherein the binder resin contains a polymer A having a first monomer unit and a second monomer unit, the first polymerizable monomer is at least one selected from the group consisting of the (meth)acrylic acid esters having C.sub.18-36 alkyl groups, a content of the first monomer unit and a content of the second monomer unit based on the total moles of all monomer units in the polymer A are respectively 5.0 to 60.0 mol % and 20.0 to 95.0 mol %, and assuming that an SP value of the first monomer unit and the second monomer unit are taken as SP.sub.11 (J/cm.sup.3).sup.0.5 and SP.sub.21(J/cm.sup.3).sup.0.5, respectively, 3.00≤(SP.sub.21−SP.sub.11)≤25.00 is satisfied, and an oil absorption of the magnetic body is 5 to 40 ml/100 g.

To provide a magnetic core material for electrophotographic developer and carrier for electrophotographic developer which have small environmental dependence of the electric resistance, can suppress the carrier scattering, and can stably provide good images; a developer contains the carrier; a method for producing the magnetic core material for electrophotographic developer; a method for producing the carrier for electrophotographic developer, and a method for producing the developer.

The magnetic core material for electrophotographic developer, satisfying a value of Formula (1): a+b10+c+d+e+f, being from 20 to 150, when a fluoride ion amount is denoted by a (ppm), a chloride ion amount is denoted by b (ppm), a bromide ion amount is denoted by c (ppm), a nitrite ion amount is denoted by d (ppm), a nitrate ion amount is denoted by e (ppm), and a sulfate ion amount is denoted by f (ppm), which are measured by a combustion ion chromatography method.

A toner for developing an electrostatic charge image, comprising a toner particle and an external additive, the toner particle comprising a binder resin containing a crystalline polyester resin, a colorant, and a release agent, the crystalline polyester resin comprising an alicyclic dibasic acid, a terephthalic acid, and an isophthalic acid as acid components and being contained in the toner particle in an amount of 4 to 8% by mass.

A toner containing a toner particle that contains a binder resin including a polyester resin, and a polyolefin resin having COOM that is a neutralized carboxy group with a monovalent metal ion M, wherein the polyolefin resin having COOM is a polymer in which a vinyl polymer is bonded to a polyolefin, a content of a monomer unit containing COOM in the polyolefin resin having COOM is 1 to 20 mass %, and in a FT-IR spectrum obtained through measurement of a large particle size-side particle group and a small particle size-side particle group obtained by dividing the toner into two substantially equal parts, on a number basis, a ratio of the intensity of a maximum absorption peak in a range from 1545 cm.sup.1 to 1555 cm.sup.1 with respect to the intensity of a maximum absorption peak in a range from 1713 cm.sup.1 to 1723 cm.sup.1 exhibits a specific relationship.

A carrier for electrostatic image development includes: a core material; and a coating resin layer that contains inorganic particles and covers the core material. The content of the inorganic particles is 10% by mass or more and 60% by mass or less based on the total mass of the coating resin layer. The volume average diameter D (m) of the inorganic particles and the thickness T (m) of the coating resin layer satisfy the following relational expression (1): 0.007D/T0.24.

A toner that is suppressed from deteriorating owing to its long-term use and can maintain high transferability. The toner includes: a toner particle containing an amorphous polyester serving as a binder resin and a polymer A; and inorganic fine particles, wherein the polymer A includes a graft copolymer of a polyolefin and a vinyl-based polymer unit having a carboxylate anion group, and a metal ion having a valence of 2 or more.

A white toner comprising a toner particle including a binder resin, an inorganic white pigment, and a polyvalent metal salt compound, wherein the inorganic white pigment has an acidic group at a surface thereof; an amount of the inorganic white pigment in the toner particle is 10% to 50% by volume; the polyvalent metal salt compound is a specific compound; an absolute value of the difference between an SP value (J/cm.sup.3).sup.1/2 of the binder resin and that of the polyvalent metal salt compound is 0.0 to 6.0; and an amount of the polyvalent metal salt compound, an amount of a polyvalent metal, the amount of the inorganic white pigment, and an amount of the acidic group at a surface of the inorganic white pigment satisfy a specific relationship.

The present invention relates to a binder resin composition for toners for development of electrostatic images capable of giving a toner excellent in fusing properties on PP films, a toner for development of electrostatic images containing the binder resin composition, a printing method using the toner, and a printed material. [1] A binder resin composition for toners for development of electrostatic images, including a polyester-based resin and polyolefin particles, wherein the polyolefin particles contain a polymer having a polymer skeleton of olefin having 2 or more and 3 or less carbon atoms, the volume median diameter (D.sub.50) of a small particle size component, as measured according to a dynamic light scattering method using a dispersion S of a small particle size component obtainable according to Methods 1 and 2, is 20 nm or more and 400 nm or less, the content of a large particle size component obtainable according to Method 2 is 0% by mass or more and 30% by mass or less relative to the total amount of the large particle size component and the small particle size component, and the content of the small particle size component is 70% by mass or more and 100% by mass or less relative to the total amount of the large particle size component and the small particle size component, and the melting endothermic energy amount of the small particle size component is 3 J/g or more and 10 J/g or less; [2] a toner for development of electrostatic images including the binder resin composition for toners for development of electrostatic images according to the above [1] in an amount of 20% by mass or more and 100% by mass or less in the binder resin therein, and including a releasing agent having a melting point of 60 C. or higher and 100 C. or lower in an amount of 1 part by mass or more and 10 parts by mass or less relative to 100 parts by mass of the binder resin; [3] a printing method including printing on a plastic film according to an electrophotographic method with the toner for development of electrostatic images according to the above [2]; and [4] a printed material obtainable according to the method of the above [3].

Provided is a toner including a binder resin, and a charge-controlling agent, wherein a volume average particle diameter X of the toner after a stress treatment satisfies Formula (1), and an amount Y of fine toner particles having particle diameters of 3 micrometers or smaller and circularity of 0.70 or less satisfies Formula (2).