An electrostatic-based layer-wise manufacturing system (e.g., 200; 200-1; 250; 282; 300) decouples a layer imaging process from a layer transfusion process. The layer imaging process is performed in a first batch process that is independent from the layer transfusion process that is performed in a second batch process.

A water dispersible sulfo-polyamide is configured as a filament for use as an extrudable support material in the additive manufacture of a part comprising a non water dispersible polymer. The water dispersible sulfo-polyamide is a reaction product of a sulfo monomer, the water dispersible sulfo-polymer being dispersible in water resulting in separation of the water dispersible polymer from the part comprising the non water dispersible polymer.

A water dispersible sulfopolymer for use as a material in the layer-wise additive manufacture of a 3D part made of a non water dispersible polymer wherein the water dispersible polymer is a reaction product of a metal sulfo monomer, the water dispersible sulfo-polymer being dispersible in water resulting in separation of the water dispersible polymer from the 3D part made of the non water dispersible polymer.

A water dispersible sulfopolymer for use as a material in the layer-wise additive manufacture of a 3D part made of a non water dispersible polymer wherein the water dispersible polymer is a reaction product of a metal sulfo monomer, the water dispersible sulfo-polymer being dispersible in water resulting in separation of the water dispersible polymer from the 3D part made of the non water dispersible polymer.

A method for printing a three-dimensional part with an electrophotography-based additive manufacturing system having an electrophotography engine, a transfer medium, and a layer transfusion assembly includes providing a part material to the electrophotography-based additive manufacturing system, the part material compositionally comprising a charge control agent, and a thermoplastic material having a heat deflection temperature greater than about 150° C., and has a powder form. The method includes triboelectrically charging the part material to a Q/M ratio having a negative charge or a positive charge, and a magnitude ranging from about 5 micro-Coulombs/gram to about 50 micro-Coulombs/gram and developing layers of the three-dimensional part from the charged part material with the electrophotography engine. The method includes electrostatically attracting the developed layers from the electrophotography engine to the transfer medium and moving the attracted layers to the layer transfusion assembly with the transfer medium, wherein the layer transfusion assembly comprises a nip roller. The method includes transfusing the moved layers to previously-printed layers of the three-dimensional part with by moving the attracted layers about a nip of a nip roller using heat and pressure over time.

An intermediate transfer belt includes a base layer that has ionic conductivity and is a thickest layer out of multiple layers making up the intermediate transfer belt with respect to the thickness direction of the intermediate transfer belt, and an inner layer having electronic conductivity and a lower electrical resistance than the base layer.

A method of recycling a water dispersible sulfonated polymer material used as a support structure in an additive manufacturing process includes providing a tap water bath and placing a printed part having an adhered support structure into the tap water bath, the support structure comprising a water-soluble sulfonated polymer material. The method includes dissolving the sulfonated polymer material in the water bath to thereby create a dispersion, and modifying the ionic strength of the dispersion by adding a multivalent metal salt to the dispersion at a concentration of between 1 gram/L and 30 grams/L, to precipitate the dissolved sulfonated polymer material from the water. The method includes recovering the precipitated sulfonated polymer material from the water, drying the recovered sulfonated polymer material and reforming the dried sulfonated polymer material into a form suitable for subsequent use as a consumable feedstock in an additive manufacturing process.

A method of recycling and reusing a tap water-soluble sulfonated polymer material from a structural component made using an additive manufacturing process comprises dissolving the structural component in water to disperse the sulfonated polymer material into the water. The sulfonated polymer material is precipitated from the water and recovered; then dried and reformed into a form suitable for subsequent use as a consumable feedstock in a subsequent additive manufacturing process.

A method of printing a part in an electrophotographic additive manufacturing system includes printing a part and associated support structure in a layer by layer manner, and providing a chamber in which printing is performed. The chamber is supported by a movable platform and the chamber is positioned about a movable platen. The movable platen is supported by the movable build platform. The movable platen is movable within the chamber on the movable build platform. An electrophotography-based additive manufacturing system for printing a three-dimensional part includes a transfer medium configured to receive and transfer imaged layers of a three-dimensional part, and a support from one or more imaging engines. The system includes a heater configured to heat the imaged layers on the transfer medium to at least a fusion temperature, and a layer transfusion assembly configured to transfuse the imaged layers to the build platen or a previously printed layer.

In a method of producing a 3D part using an electrophotography-based additive manufacturing system, a plurality of layers of a powder-based material are developed using at least one electrophotography (EP) engine. The developed layers are transferred to a transfer medium. The layers on the transfer medium are dried by heating the layers without fully fusing the powder-based material to itself using a dryer. This reduces a water content of the layers. The dried layers are heated on the transfer medium to at least a fusion temperature, at which the power-based material fuses together, using a pre-transfusion heater. The dried layers are then transfused together on a build platform using a transfusion assembly to build the part in a layer-by-layer manner.