By configuring a timepiece component to include an intermediate film provided on at least a portion of a surface of a base material formed by using a nonconductive first material as a main component and to include a buffer film stacked on the intermediate film and mainly composed of a second material having a tenacity higher than that of the first material, the timepiece component may be manufactured with high precision, the weight thereof may be reduced, and even when the base material is formed by using a brittle material such as silicon, the timepiece component becomes resistant to breakage and capable of exhibiting high strength when an impact is externally applied.

A balance-spring intended to equip a balance of an horological movement, comprising a core made of Nb—Ti made from an alloy consisting of: niobium: balance to 100% by weight, titanium: between 5 and 95% by weight, traces of elements chosen from the group consisting of O, H, C, Fe, Ta, N, Ni, Si, Cu, Al, each of said elements being present in a quantity between 0 and 1600 ppm by weight, the total quantity formed by all of said elements being between 0% and 0.3% by weight, wherein the core made of Nb—Ti is coated with a layer of niobium, said layer of niobium having a thickness between 20 nm and 10 μm.

A flexible timepiece component, in particular for an oscillator mechanism or for a barrel of a horological movement, the component extending along a main plane (P) and including at least a part made of a composite material (1), the composite material (1) including a matrix (2) and a multitude of nanowires (3) distributed in the matrix (2), the nanowires (3) being juxtaposed, the matrix (2) including a material (4) for filling the interstices between the nanowires (3) to join them to each other, each nanowire (3) forming a solid one-piece tube, the nanowires (3) being disposed substantially parallel to an axis (A) substantially perpendicular to the main plane (P) of the component (6, 7).

A flexible horological component for an oscillator mechanism of a horological movement, the component extending along a principal plane (P) and including at least a part made of a composite material (1), the composite material (1) including a matrix (2) and a multitude of nanotubes or nanowires (3) distributed in the matrix (2), the nanotubes or nanowires (3) being juxtaposed and disposed substantially parallel with an axis (A) substantially perpendicular to the plane (P) of the component, the matrix including a flexible filling material (4) to fill the interstices between the nanotubes or nanowires (3), the filling material (4) comprising at least in part a thermal compensation material wherein the thermoelastic coefficient (TEC) is of the opposite sign to that of the other materials of the composite material (1).

A method for producing a timepiece spring includes the following steps: producing a piece based on silicon, having the desired shape of the timepiece spring; thermally oxidising the piece; deoxidising the piece; annealing the piece in a reducing atmosphere; forming a silicon oxide layer on the piece.

A piezoelectric element for an automatic frequency control circuit, the element including: a balance spring formed of a strip of piezoelectric material; at least a first electrode, configured to be connected to the circuit and being disposed on all or part of one side of the strip; at least a second electrode configured to be connected to the circuit and being disposed on all or part of another one side of the strip distinct from the one side on which the first electrode is disposed, the piezoelectric material being a piezoelectric crystal or a piezoelectric ceramic; and at least two discontinuous layers of an insulating material, each discontinuous layer being disposed on at least one side of the strip and separating the first electrode from the second electrode, the layers of insulating material being distributed on predetermined portions of the balance spring substantially forming arcs in a predetermined angular periodicity.

A piezoelectric element for an automatic frequency control circuit. The element includes a balance spring formed of a piezoelectric crystal strip, a first electrode connected to the automatic control circuit, and disposed on at least a first side of the strip, and a second electrode connected to the automatic control circuit and disposed on at least a second side of the strip. The first and second electrodes are placed on one portion or over the entire length of the balance spring in a predetermined angular distribution.

A process for fabricating a hairspring having a final stiffness includes the steps of fabricating a hairspring to thickened dimensions, and determining the initial stiffness of the hairspring formed in order to remove the volume of material to obtain the hairspring having the dimensions required for said final stiffness.

A horology component based on a fragile material, wherein said component comprises at least one surface part of fragile material covered with a coating (10) comprising at least two layers CE of elastic material (11) separated by a layer CR of a material (12) stronger than the elastic material (11).

A balance spring (1) intended to equip a balance of a horological movement, wherein the balance spring (1) is made of a niobium and titanium alloy containing: niobium: the remainder to 100 wt %; titanium with a weight percentage that is greater than or equal to 1 wt % and less than 40 wt %; traces of other elements chosen from among O, H, C, Fe, Ta, N, Ni, Si, Cu and Al, each of said elements being in the range 0 to 1,600 ppm of the total weight, and the sum of said trace elements being less than or equal to 0.3 wt %.