Disclosed is a support member for supporting a wafer during a heat treatment of the wafer. The support member includes a support plate and spacers and retaining elements carried by the support plate. The spacers serve to maintain a gap between the support plate and the wafer. The retaining elements serve to prevent the wafer from moving horizontally. The support plate may be made of silicon, quartz or silicon carbide. The spacers and the retaining elements may be fixed to the support plate by bayonet-type connections.

A balance spring (1) of a sprung balance assembly of a mechanical horological movement, formed by a succession of coils (S1, . . . , Sn) which extend between a first free end, referred to as inner first coil (2), and a second free end, referred to as outer last coil (6). The are arranged off-centre when the balance spring is in the free state, the outer last coil (6) terminating in a stop means for the attachment thereof to a stud (14). The balance spring (1) is centred and its spires concentric when the spring (1) is in the mounted state inside the sprung balance assembly, the coils being rearranged concentrically when the spring is in the mounted state. The attachment of the spring to the stud inducing, in the coils, a resilient stress as a result whereof the stop is attached in a captive manner to the stud (14).

A method for treating a surface (2) of a base (1) of a timepiece component (10), in particular a balance spring, e.g. a balance spring made of a paramagnetic NbZr alloy, includes: a first step of depositing a first layer (41) of a first oxide or first nitride or first carbide; and a second step of depositing a second layer (51) of a second oxide or second nitride or second carbide.

A metastable titanium alloy is provided, which includes, by weight percent, between 24 and 45% niobium, between 0 and 20% zirconium, between 0 and 10% tantalum and/or between 0 and 1.5% silicon and/or less than 2% oxygen, said alloy having a crystallographic structure containing: a mix of austenitic phase and alpha phase; and a presence of omega phase precipitates the volume fraction of which is less than 10%. Also provided is a timepiece spring made from such an alloy and a method for producing such a spring.

A spiral spring is configured to equip a balance of a horological movement. The spiral spring is made of an alloy consisting of: Nb, Ti and at least one element selected from V and Ta, optionally at least one element selected from Zr and Hf, optionally at least one element selected from W and Mo, possible traces of other elements selected from O, H, C, Fe, N, Ni, Si, Cu, Al, with the following weight percentages: a total content of Nb, V and Ta comprised between 40 and 85%, a total content of Ti, Zr and Hf comprised between 15 and 55%, a content for W and Mo respectively comprised between 0 and 2.5%, a content for each of the elements selected from O, H, C, Fe, N, Ni, Si, Cu, Al between 0 and 1600 ppm with the sum of the traces less than or equal to 0.3% by weight.

A spiral spring intended to equip a balance of a horological movement, wherein the spiral spring is made of an alloy consisting of Nb, Ti and at least one element selected from Zr and Hf, optionally at least one element selected from W and Mo, possible traces of other elements selected from O, H, Ta, C, Fe, N, Ni, Si, Cu, Al, with the following weight percentages: a content of Nb comprised between 40 and 84%, a total content of Ti, Zr and Hf comprised between 16 and 55%, a content for W and Mo respectively comprised between 0 and 2.5%, a content for each of said elements selected from O, H, Ta, C, Fe, N, Ni, Si, Cu, Al comprised between 0 and 1600 ppm with the sum of said traces less than or equal to 0.3% by weight. The method for manufacturing the spiral spring is also disclosed.

A method for improving an iron-nickel-chromium-manganese alloy for timepiece applications, particularly for producing a balance spring, is described. The base alloy contains, by mass, from 9.0% to 13.0% of nickel, from 4.0% to 12.0% of chromium, from 21.0% to 25.0% of manganese, from 0 to 5.0% of molybdenum, and/or from 0 to 5.0% of copper in addition to iron. The alloy is hardened while its anti-ferromagnetic properties are maintained by introducing 0.10% to 1.20% of carbon and 0.10% to 1.20% of nitrogen interstitially, based on the mass of the base alloy.

An assembly (300) includes (i) a hairspring (2) made of a paramagnetic alloy including at least one of the following elements: Nb, V, Ta, Ti, Zr and Hf, notably an alloy including the elements Nb and Zr with between 5% and 25% by mass of Zr and an interstitial doping agent including oxygen, and oxygen, and least one fastening part (1; 1), notably two parts (1; 1), in particular a stud (1) or a collet (1), for an end (2a; 2b) of the hairspring (2), the at least one part (1; 1) having a first portion (10; 10) that is designed to come into contact with the hairspring (2) and that is made of titanium or titanium alloy or of tantalum or tantalum alloy, notably grade 2 titanium or grade 5 titanium.

A resonator of the inertia/elasticity type includes a balance-spring coupled to an inertia flywheel and a system for adjusting the frequency of the resonator including an index-assembly arranged to cooperate with one coil of the balance-spring in order to selectively choose the active length of the balance-spring. The portion of the coil of the balance-spring cooperating with the index-assembly includes at least one area of larger cross-section than the other balance-spring coils for finer adjustment of the frequency of the resonator.

The present invention relates to a spiral spring for a balance wheel made of an alloy of niobium and titanium with an essentially single-phase structure, and the method of manufacture thereof which comprises: a step of producing a blank in a niobium-based alloy consisting of: niobium: balance to 100 wt %, titanium: between 40 and 49 wt %, traces of elements selected from the group consisting of O, H, C, Fe, Ta, N, Ni, Si, Cu, Al, between 0 and 1600 ppm by weight individually, and cumulatively less than 0.3 wt %, a step of type ? hardening of said blank at a given diameter, in such a way that the titanium of the niobium-based alloy is essentially in the form of a solid solution with niobium in ? phase, the content of titanium in ? phase being less than or equal to 10 vol %, at least one deformation step of said alloy alternating with at least one step of heat treatment, the number of steps of heat treatment and of deformation being limited so that the niobium-based alloy obtained retains a structure in which the titanium of the niobium-based alloy is essentially in the form of a solid solution with niobium in ? phase, the content of titanium in ? phase being less than or equal to 10 vol % and it has an elastic limit greater than or equal to 600 MPa and an elastic modulus less than or equal to 100 GPa, a step of winding to form the spiral spring being carried out before the last heat treatment step.