Radioactive material adsorbing clay material effectively and efficiently removes radioactive material, namely radium, from aqueous fluids, thereby purifying the same. Methods of synthesizing and using the same are further provided.

A canister for interim storage and subsequent consolidation of waste materials via hot pressing and comprising at least one ion exchange material. The canister is configured to house the ion exchange material after it is exchanged with a contaminating ion without releasing the contaminating ion and to consolidate waste materials via hot-isostatic pressing. A method comprising contacting a fluid waste with an ion exchange material.

A canister for interim storage and subsequent consolidation of waste materials via hot pressing and comprising at least one ion exchange material. The canister is configured to house the ion exchange material after it is exchanged with a contaminating ion without releasing the contaminating ion and to consolidate waste materials via hot-isostatic pressing. A method comprising contacting a fluid waste with an ion exchange material.

Methods and materials are described for the removal of iodate from aqueous solutions. The methods comprise reduction of the iodate to iodide and subsequent or concurrent removal of the iodide by sorption, ion exchange, or precipitation. These methods are effective for the removal of radioactive iodine from radioactive and nuclear wastes.

Methods and materials are described for the removal of iodate from aqueous solutions. The methods comprise reduction of the iodate to iodide and subsequent or concurrent removal of the iodide by sorption, ion exchange, or precipitation. These methods are effective for the removal of radioactive iodine from radioactive and nuclear wastes.

Provided are a cobalt ion adsorption material which has a large adsorption capacity and which tends not to generate fine powder, and a method for producing the same. This cobalt ion adsorption material is a powder with a particle diameter of 100-1,000 μm, and contains 0.3-8.0 parts by mass of a binder constituted of a water-insoluble metal oxide or metal hydroxide fine particles with respect to 100 parts by mass of a cobalt adsorption main agent constituted of potassium hydrogen dititanate hydrate.

Provided are a cobalt ion adsorption material which has a large adsorption capacity and which tends not to generate fine powder, and a method for producing the same. This cobalt ion adsorption material is a powder with a particle diameter of 100-1,000 μm, and contains 0.3-8.0 parts by mass of a binder constituted of a water-insoluble metal oxide or metal hydroxide fine particles with respect to 100 parts by mass of a cobalt adsorption main agent constituted of potassium hydrogen dititanate hydrate.

Provided herein is a cesium adsorbent including: a support modified to have a carboxyl group on a surface thereof; and Prussian blue synthesized on the surface of the modified support, wherein the Prussian blue is at least partially chemically bound with the surface of the support. The cesium adsorbent may effectively adsorb cesium, which is a radioactive element released into the water and may be easily prepared using a simple solution process.

Provided herein is a cesium adsorbent including: a support modified to have a carboxyl group on a surface thereof; and Prussian blue synthesized on the surface of the modified support, wherein the Prussian blue is at least partially chemically bound with the surface of the support. The cesium adsorbent may effectively adsorb cesium, which is a radioactive element released into the water and may be easily prepared using a simple solution process.

A receptor for the simultaneous removal of oxoanions and their counterions from aqueous phase, particularly containing radioactive wastes, containing amide groups specifically coordinating the oxoanions, as well as moieties specifically coordinating cations, according to the present invention is characterised in that it contains within one molecule domains binding oxoanions and domains binding cations, preferably adapting a molecular structure of a general formula: (I) wherein Z this is a group containing crown ether, preferably a benzocrown group, X is any substituent, including the Y-Z grouping, and Y is any substituent or 0 (i.e. a direct bond between N and Z), where the oxoanion binding domain is a squaramide unit coordinating the oxoanions through amide groups, and squaramide contains additional substituents that increase or decrease the acidity of its amide protons, compared to unsubstituted squaramide, whereas the counter ion binding domain is a crown ether of a size adjusted to the type of binding cation, which forms part of at least one of the aforementioned substituents of squaramide, where the receptor has the ability to remove oxoanions and their counterions from aqueous phase to another water-immiscible phase, preferably to organic phase, and has the ability to form soluble complexes in at least one of the aforementioned phases. The invention considers also a method of removing oxoanions in the form of inorganic salts from aqueous phase, using receptors of the invention in the form of organic molecules containing amide groups, according to the invention is characterised in that it uses the aforementioned receptors for simultaneous binding of oxoanions and their counterions in aqueous phase, preferably acidic when using the receptor with substituents increasing acidity of squaramide protons, or alkaline when using the receptor with substituents decreasing acidity of squaramide protons. A sensor for detecting oxoanions according to the invention is characterised in that it uses the aforementioned receptors, dissolved or suspended in an organic solvent or in a mixture of organic solvents, forming coloured complexes in contact with the phase containing given oxoanions. The preparation for removing oxoanions from aqueous solutions, particularly containing radioactive waste at the stage preceding their disposal by vitrification, is characterised in that it contains the receptor according to the invention, dissolved or suspended in the water-immiscible phase, and the appropriate amount of counterion facilitating extraction. A process of utilisation of aqueous solutions by vitrification, particularly solutions containing radioactive waste, is characte