G01J3/4338

Fourier domain dynamic correction method for complex optical fringes in laser spectrometers

A method is provided for Fourier domain dynamic correction of optical fringes in a laser spectrometer. The method includes Fourier transforming a background spectrum contaminated with the optical fringes to obtain baseline fringes in a frequency domain. The method includes partitioning the baseline fringes in the frequency domain to obtain partitioned baseline fringes. The method includes reconstructing the partitioned baseline fringes as separate spectra. The method includes constructing a fitting model to approximate the background spectrum by assigning a first and a second free parameter to each of partitioned baseline fringe components to respectively allow for drift and amplitude adjustments during a fitting of the fitting model. The method includes applying the fitting model to a newly acquired spectrum to provide an interpretation of the newly acquired spectrum having a reduced influence of spectral contamination on concentration retrieval.

Cavity enhanced absorption spectroscopy using a piecewise tunable laser and hierarchical wavelength determination

Improved cavity enhanced absorption spectroscopy is provided using a piecewise tunable laser by using a lookup table for laser tuning that is configured specifically for this application. In preferred embodiments this is done in combination with a laser control strategy that provides precise wavelength determination using cavity modes of the instrument as a reference.

Cross-comb spectroscopy

A system for performing spectroscopy, including a first frequency comb source outputting first electromagnetic radiation comprising a first frequency comb centered at a first wavelength and having a first repetition rate; a second frequency comb source outputting a second electromagnetic radiation comprising a second frequency comb centered at a second wavelength and having a second repetition rate; a nonlinear device positioned to receive the first frequency comb and the second frequency comb, wherein the nonlinear device interacts the first frequency comb and the second frequency comb through sum frequency generation or difference frequency generation so as to generate an output electromagnetic radiation; and a detection system outputting a signal in response to detecting an interference of the output electromagnetic radiation with a third electromagnetic radiation, the signal comprising information used for determining a spectrum of at least the first frequency comb or the second frequency comb.

AMPLIFIER AMPLITUDE DIGITAL CONTROL FOR A MASS SPECTROMETER

Control of an amplitude of a signal applied to rods of a quadrupole is described. In one aspect, a mass spectrometer includes an amplifier circuit that causes a radio frequency (RF) signal to be applied to the rods of the quadrupole based on an amplifier RF input signal. An analog-to-digital converter (ADC) can generate a digital representation of the RF signal. A controller circuit can receive the digital representation and adjust an amplitude of the amplifier RF input signal based on differences between an amplitude of a fundamental frequency of the RF signal being different than an expected amplitude.

Apparatuses and methods for anomalous gas concentration detection

Embodiments of the disclosure are drawn to apparatuses and methods for anomalous gas concentration detection. A spectroscopic system, such as a wavelength modulated spectroscopy (WMS) system may measure gas concentrations in a target area. However, noise, such as speckle noise, may interfere with measuring relatively low concentrations of gas, and may lead to false positives. A noise model, which includes a contribution from a speckle noise model, may be used to process data from the spectroscopic system. An adaptive threshold may be applied based on an expected amount of noise. A speckle filter may remove measurements which are outliers based on a measurement of their noise. Plume detection may be used to determine a presence of gas plumes. Each of these processing steps may be associated with a confidence, which may be used to determine an overall confidence in the processed measurements/gas plumes.

Cavity Enhanced Absorption Spectroscopy using a piecewise tunable laser and hierarchical wavelength determination

Improved cavity enhanced absorption spectroscopy is provided using a piecewise tunable laser by using a lookup table for laser tuning that is configured specifically for this application. In preferred embodiments this is done in combination with a laser control strategy that provides precise wavelength determination using cavity modes of the instrument as a reference.

CAVITY BUILDUP DISPERSION SPECTROMETER AND PERFORMING CAVITY BUILDUP DISPERSION SPECTROSCOPY

A cavity buildup dispersion spectrometer includes a shutter that modulates coherent electromagnetic radiation at a shutter frequency; and produces modulated electromagnetic radiation; a frequency shifter that frequency shifts the modulated electromagnetic radiation to a shifter frequency and produces frequency shifted radiation; a resonator that produces cavity radiation from the frequency shifted radiation and the coherent electromagnetic radiation, receives an analyte; subjects the analyte to cavity radiation, and transmits the cavity radiation as transmitted electromagnetic radiation; and a receiver that: produces a detector signal from the transmitted electromagnetic radiation, such that the detector signal includes a beat frequency that corresponds to a change in a motion of resonator that includes a change in the distance between the mirrors or a change of refractive index of the analyte in the intracavity space.

(MULTI-) HETERODYNE DETECTION SPECTROMETER SETUP
20210131868 · 2021-05-06 · ·

A heterodyne detection spectrometer setup comprises an optical path with at least a first cavity able to emit a first laser beam; a second cavity able to emit a second laser beam; and at least one combining and/or reflecting element. The cavities are connected to current drivers for stimulating laser emission, which shows increased signal-to-noise ratios of the heterodyne signal and an increased dynamic range. This can be reached if at least the second cavity comprises an active medium connected to a heterodyne signal extraction element and a (multi-) heterodyne signal processing unit, which is simultaneously usable for laser light generation and as detector element, comprising an active medium introduced in the optical path in order that the first and/or second laser beam can enter the respective other cavity. At least one reference path is established between the two cavities in the optical path with at least two combining and/or reflecting elements.

Method and Gas Analyzer for Measuring the Concentration of a Gas Component in a Measurement Gas
20210096068 · 2021-04-01 ·

Method and gas analyzer for measuring the concentration of a gas component in a measurement gas, a wavelength-tunable laser diode is actuated with a current, one part of the light generated by the laser diode is guided through the measurement gas to a measuring detector to generate a measuring signal, the other part of the light is guided to a monitor detector to generate a monitor signal, the current is varied in periodically consecutive scanning intervals to scan an absorption line of interest of the gas component as a function of the wavelength, the current is further modulated with a radio-frequency noise signal having a lower cut-off frequency selected as a function of the properties of the laser diode and high enough to ensure no wavelength modulation occurs and the measuring signal is correlated with the monitor signal and then evaluated to generate a measurement result.

Analysis apparatus and analysis method

The present invention relates to an analysis apparatus adapted to analyze a measurement target component contained in a sample by irradiating a measurement cell into which the sample is introduced with pulse-oscillated light, whereby suppressing reduction in wavelength resolution without shortening the pulse width. The analysis apparatus includes multiple light sources adapted to produce pulse oscillations, a light detector adapted to detect light emitted from the light source and transmitted through the measurement cell, and a signal separation part adapted to separate, from a light intensity signal obtained by the light detector, signals corresponding to a part of pulses from the light sources.