A drop-in probe for determining phase changes by thermal analysis of a sample of a molten metal includes a measurement head having a first end which is an immersion end and an opposing second end having an end face. A sample chamber is arranged within the measurement head. An opening, which is free of any restrictions and which is in communication with the sample chamber, is formed in the end face of the second end of the measurement head. The sample chamber includes a first thermocouple having a first thermocouple junction enclosed within a wall which has a uniform internal geometry. A ratio D/H of an internal diameter D of the sample chamber to a length H extending between the opening and the first thermocouple junction is between 0.1 and 1.2.

A drop-in probe includes a measurement head having an immersion end and an opposing second end having an end face. The measurement head is formed of first and second body halves configured to mate together along a parting line. A sample chamber, arranged within the measurement head, is thermally isolated from a cooling mass thereof and includes a metal wall having a thickness of 2.5 mm or less. An inlet tube has an inlet opening to the sample chamber. The inlet opening has a diameter D.sub.inlet and is spaced apart from the end face of the measurement head at a distance of at least $\frac{D_{\mathrm{inlet}}}{2}.$
When the sample chamber is filled with a sample of the molten metal, a ratio of a mass of the metal sample to a mass of the metal wall of the sample chamber is greater than 2.6 and less than 6.

An immersion device for collecting a slag sample and measuring a molten metal parameter is provided. The immersion device includes an inflow conduit for directing the molten slag to a slag sample chamber and a measuring element for measuring the parameter of the molten metal. The inflow conduit and the measuring element are arranged in the top area of an immersion end of the immersion device and/or are facing towards an immersion direction. During immersion in the immersion direction into the molten slag and then the molten metal, the molten slag enters an external portion of the inflow conduit and is directed through an inner portion of the inflow conduit to the slag sample chamber. Reliable slag collection and molten metal measurement also in a converter can thereby be achieved. A method of collecting a slag sample and measuring a molten metal parameter is also provided.

An immersion device is provided for molten metal, as well as a method for making steel. The immersion device allows a trouble free operation. The immersion device includes a measuring head, a carrier for the measuring head, and a lance detachably connected to the carrier, preferably by a detachable tubular connecting element. A gas path runs from the lance to the detachable tubular connecting element. A gas tight connection is provided between a connecting surface of the lance and the detachable tubular connecting element. The tubular connecting element has wipers in the form of fins, which wipe the connecting surface of the lance during attaching and/or detaching the tubular connecting element and the lance.

An apparatus for producing metal bars and ingots with quality monitoring, includes at least one mold essentially constituted by a body that forms at least one cavity for forming an ingot or a bar and by at least one cover that is detachably associated with the body in order to upwardly close the cavity. The apparatus has at least one passage, provided on the body of the mold, on the cover or on both, for connecting the inside of the cavity to the outside even when the cover is associated with the body in order to upwardly close the cavity. The apparatus according to the invention also has the particularity that it includes a means for taking a sample of the melted material contained in a mold, constituted essentially by a body that forms at least one cavity for forming an ingot or a bar and by at least one cover that is detachably associated with the body in order to upwardly close the cavity. The present invention also relates to a plant and a method for producing metal bars and ingots with quality monitoring.

A sampler has a sample chamber for a sample forming from a molten material, at least one lower cooling body, at least one upper cooling body, at least one inner cooling body, and at least one filling part. The sample chamber is surrounded jointly at least by the lower cooling body and the inner cooling body, such that at least the sample chamber can be cooled by at least the lower and inner cooling bodies. The filling part merges into the sample chamber by a filling opening. Between a region of the outer surface of the inner cooling body and a region of the outer surface of the upper cooling body opposite the outer surface of the inner cooling body, the sampler has at least one gap for conducting at least one gas. The volume of the respective cooling bodies is larger than the volume of the gap.

A sampling device for molten metals includes a carrier tube having an immersion end and a sample chamber arranged in the carrier tube. The sample chamber has an inflow conduit. The inflow conduit has an inflow opening inside the sampling chamber and an outer open end which is surrounded by a protective cap. The protective cap has a metallic body with an inner side directed toward the inflow conduit and an outer side. A layer of a material is arranged at the outer side of the metallic body. The material comprises a compound which decomposes and forms water vapor if immersed in molten steel, molten iron or molten slag.

Briefly, the invention provides a method for analyzing molten salt electrolyte involving extracting a sample of a molten salt electrolyte from an electrorefiner or other process vessel or conduit; generating droplets from the sample, where the droplets are at a first temperature; transporting the droplets to detectors, where during transport, the droplets attain a second temperature that is lower than the first temperature; analyzing the droplets at or below the second temperature; and returning the droplets to the process. Also provided is a system for analyzing molten salt electrolyte using a droplet generator.

A sample chamber for taking samples from a molten metal bath. The chamber comprises a flat cover plate and a housing, wherein the flat cover plate and housing are assembled together to form a sample cavity. The housing comprises an immersion face and an opposing end face, a top face and a bottom face. The housing comprises a first opening in the immersion face, and a second opening in another face. The top face has at least one indentation, comprising a distribution segment, a ventilation segment and an analysis segment and wherein the analysis segment is bounded by an analysis plane AP. The distribution segment and the ventilation segment are in a direction from the top face to an opposite face of the housing and the maximum and the minimum cross-sectional area of the analysis segment do not deviate from each other by more than 20%.