Downhole tools for isolating and analyzing one or more gases include a gas separation assembly in fluid communication with a gas specific analyzer. The gas separation assembly includes a piston disposed within a housing and a separation volume defined between the piston and the housing. The piston is movable to separate a gas component and a liquid component from a downhole formation fluid within the separation volume. The gas specific analyzer is operable to measure one or more properties of the gas component. In some configurations, the gas specific analyzer is an optical assembly containing a light source, an optical detector, and a gas cell that contains an observation volume. The optical assembly is operable to measure one or more properties of the gas component within the observation volume via the light source and the optical detector.

A soil imaging probe has a housing with an interior cavity and an outer surface exposed for sliding contact with soil. A window is mounted in the outer surface for providing optical communication between the soil and the interior cavity. An optical module is positioned within the interior cavity. The optical module includes at least one light source and a camera mounted in a block. An indexing surface is defined in the interior cavity to maintain the optical module at a predetermined fixed distance from the window to keep the camera focused on the soil outside the window. An elastomeric fill material fills the interior cavity and substantially surrounds the optical module to reduce energy transference from the housing of the probe to the optical module. An image processing method is also provided to identify pixels in an image captured by the camera that show potential hydrocarbon contamination.

Improved devices, systems and methods for measuring in situ saturations of non-aqueous phase liquids and/or petroleum in media such as soil. A clear or otherwise UV-transparent well for detecting fluorescence in a soil column having a transparent casing and an oil sensing device positioned in the well configured to monitor the soil column. A method for real-time estimation of LNAPL saturations in media, including emplacing a UV-transparent well in the media and recording fluorescence in the media via an oil sensing device.

A spectrometer probe is disclosed herein including a shaft having a first end and a second end, a fiberoptic bundle located within the shaft, the fiberoptic bundle having a first end and a second end, a mirror, a transparent window, a prism, a prism support, an elastically deformable material, an index-matching elastomer, wherein the prism is completely encompassed by the index-matching elastomer, and a penetration cone operatively attached to the second end of the fiberoptic bundle, the mirror located within the second end of the shaft, wherein the transparent window is substantially parallel with the fiberoptic bundle and the shaft, wherein the prism is angled at approximately a 45 degree angle in relation to the window and the fiberoptic bundle, wherein the prism is flush with the prism support, wherein the elastically deformable material is biasly connected to the prism support.

A method for mapping distribution of chemical compounds in soil is described herein including inserting a probe into the soil at multiple locations, obtaining spectroscopic data regarding the soil, sampling a core of soil adjacent to the probe locations, dividing the core into multiple depth increments, analyzing the core samples, matching each core sample with a corresponding depth increment of the probe insertions, obtaining data from the probe insertions, dividing the probe insertion data into training, validation, and test categories, resampling spectral variables from the probe insertion data to a wavelength interval longer than a native wavelength interval of an associated spectrometer, normalizing the probe insertion data on a spectrum by spectrum basis, utilizing a machine learning normalization algorithm, standardizing the spectral variables to a common scale by removing a mean and scaling to unit variance, and choosing a model utilizing the test set.

A spectrometer probe is disclosed herein including a shaft having a first end and a second end, a fiberoptic bundle located within the shaft, the fiberoptic bundle having a first end and a second end, a mirror, a transparent window, a prism, a prism support, an elastically deformable material, an index-matching elastomer, wherein the prism is completely encompassed by the index-matching elastomer, and a penetration cone operatively attached to the second end of the fiberoptic bundle, the mirror located within the second end of the shaft, wherein the transparent window is substantially parallel with the fiberoptic bundle and the shaft, wherein the prism is angled at approximately a 45 degree angle in relation to the window and the fiberoptic bundle, wherein the prism is flush with the prism support, wherein the elastically deformable material is biasly connected to the prism support.

A method for mapping distribution of chemical compounds in soil is described herein including inserting a probe into the soil, obtaining spectroscopic data regarding the soil, sampling a core of soil adjacent to the probe locations, dividing the core into multiple depth increments, analyzing the core samples, matching each core sample with a corresponding depth increment of the probe insertions, obtaining data from the probe insertions, dividing the probe insertion data into training, validation, and test categories, resampling spectral variables from the probe insertion data to a wavelength interval longer than a native wavelength interval of an associated spectrometer, normalizing the probe insertion data on a spectrum by spectrum basis, utilizing a machine learning normalization algorithm, standardizing the spectral variables to a common scale by removing a mean and scaling to unit variance, and choosing a model utilizing the test set.

A method and apparatus are provided for performing in-situ fluid analysis. The method involves obtaining a first and second mixture of uncontaminated oil and a contaminant, wherein a percentage of the uncontaminated oil in the first mixture is different from the second mixture. The method may further include establishing a rate of change of a physical property of the first mixture and the second mixture to estimate a mass density of the uncontaminated oil and a mass density of the contaminant. In addition, the method may include obtaining a volume fraction of the uncontaminated oil for the first mixture and second mixture using the mass density of the uncontaminated oil and the mass density of the contaminant. An optical device may be used to determine a composition of the first and second mixtures in order to calculate a composition of the contaminant and a composition of the uncontaminated oil.

An apparatus comprising: a direct push probe configured to be pushed into a subsurface soil environment; a transparent window mounted to a side of the probe; a white light source mounted within the probe and positioned such that when the white light source is activated only white light exits the window; an ultraviolet (UV) light source mounted within the probe and positioned such that when the UV light source is activated only UV light having a given wavelength exits the window; and an imaging system disposed within the probe and configured to capture a white-light-only-illuminated image and a UV-light-induced-fluorescence image of the subsurface soil environment at a given depth, wherein the imaging system comprises a longpass filter to filter out the UV light having the given wavelength.

An automated image acquisition device includes a housing including an image acquisition chamber. A tray is deployed in the image acquisition chamber and is configured to receive a drill cuttings sample. At least one light is also deployed in the image acquisition chamber and is disposed to illuminate the tray. A digital camera is deployed in the image acquisition chamber and is configured to acquire a digital image (e.g., a digital color image) of the cuttings sample. The device further includes an electronic controller configured to instruct the digital camera to record a digital image of the drill cuttings and save the image to digital memory or transfer the image to an external computing device.