Technologies for rapid equilibration for water isotope analysis are disclosed. In at least one illustrative embodiment, a vaporizer may include an injection block that defines a chamber and a septum positioned over an inlet of the chamber to seal the chamber. The chamber may be configured to be fluidly coupled to a pump to develop a vacuum within the chamber, and the septum may be configured to receive a needle that is inserted into the chamber. A thermally conductive wool may be positioned within the chamber and may be configured to receive a tip of the needle.

Technologies for rapid equilibration for water isotope analysis are disclosed. In at least one illustrative embodiment, a vaporizer may include an injection block that defines a chamber and a septum positioned over an inlet of the chamber to seal the chamber. The chamber may be configured to be fluidly coupled to a pump to develop a vacuum within the chamber, and the septum may be configured to receive a needle that is inserted into the chamber. A thermally conductive wool may be positioned within the chamber and may be configured to receive a tip of the needle.

Disclosed is a sample pretreatment method of microextraction tube injection, comprising providing a capillary micro-extraction tube with extracting medium in it as an injector, passing a sample through the capillary micro-extraction tube, during which an analyte is extracted into an extracting medium inside the capillary micro-extraction tube; then, filling the capillary micro-extraction tube with an organic solvent and keeping the filling for a certain period of time, so that the extracted analyte is dissolved in the organic solvent inside the capillary micro-extraction tube to form an injection solution; finally, keeping one end of the capillary micro-extraction tube sealed and inserting the other end directly into an injection port of a gas chromatography, such that the injection solution is automatically ejected out from the capillary micro-extraction tube into the injection port.

Disclosed is a sample pretreatment method of microextraction tube injection, comprising providing a capillary micro-extraction tube with extracting medium in it as an injector, passing a sample through the capillary micro-extraction tube, during which an analyte is extracted into an extracting medium inside the capillary micro-extraction tube; then, filling the capillary micro-extraction tube with an organic solvent and keeping the filling for a certain period of time, so that the extracted analyte is dissolved in the organic solvent inside the capillary micro-extraction tube to form an injection solution; finally, keeping one end of the capillary micro-extraction tube sealed and inserting the other end directly into an injection port of a gas chromatography, such that the injection solution is automatically ejected out from the capillary micro-extraction tube into the injection port.

A septum containing a duckbill valve assembly includes a plurality of elastomeric ribs extending from the body of the septum to the duckbill valve assembly. When inserted into an injection port cavity, force generated by an interference fit between the body of the septum and the cavity is transmitted by the ribs to the duckbill valve assembly. The ribs are configured to reversibly collapse at a hinge point when a needle is inserted through the duckbill valve assembly and are spaced to assist in centering the needle in the duckbill valve assembly. The ribs reduce wear on the duckbill valve assembly by reducing the concentration of compressive forces at higher inlet pressures while maintaining sufficient compressive force to close the duckbill valve assembly at lower inlet pressures.

A septum containing a duckbill valve assembly includes a plurality of elastomeric ribs extending from the body of the septum to the duckbill valve assembly. When inserted into an injection port cavity, force generated by an interference fit between the body of the septum and the cavity is transmitted by the ribs to the duckbill valve assembly. The ribs are configured to reversibly collapse at a hinge point when a needle is inserted through the duckbill valve assembly and are spaced to assist in centering the needle in the duckbill valve assembly. The ribs reduce wear on the duckbill valve assembly by reducing the concentration of compressive forces at higher inlet pressures while maintaining sufficient compressive force to close the duckbill valve assembly at lower inlet pressures.

A housing is provided with an internal space for accommodating an insert and a cylindrical cap attachment part provided, at the distal end surface thereof, with an opening part communicating with the internal space. An inclined groove that is inclined from the distal end side to the proximal end side of the cap attachment part along the circumferential direction of the cap attachment part is provided on the outer circumferential surface of the cap attachment part. A cap fixing part for attaching a seal cap to the cap attachment part has a cap holding part for holding the outer peripheral surface of the seal cap and an elastic part connected to the cap holding part. The elastic part is provided with a protrusion that is fit into the inclined groove of the outer peripheral surface of the cap attachment part.

A housing is provided with an internal space for accommodating an insert and a cylindrical cap attachment part provided, at the distal end surface thereof, with an opening part communicating with the internal space. An inclined groove that is inclined from the distal end side to the proximal end side of the cap attachment part along the circumferential direction of the cap attachment part is provided on the outer circumferential surface of the cap attachment part. A cap fixing part for attaching a seal cap to the cap attachment part has a cap holding part for holding the outer peripheral surface of the seal cap and an elastic part connected to the cap holding part. The elastic part is provided with a protrusion that is fit into the inclined groove of the outer peripheral surface of the cap attachment part.

Disclosed is a separation column for micro gas chromatography, having superior separation performance and including a microchannel formed on a substrate and having a serpentine shape, and bumps formed on the surface of the microchannel, wherein the bumps are alternately disposed to face each other on the surface of the microchannel. In the separation column for micro gas chromatography, a sufficient pressure drop occurs, and thus an interaction between a gas mixture to be analyzed and a stationary phase in the column sufficiently takes place, whereby individual gas components are efficiently separated from the gas mixture, discharged from the column, and detected.

Disclosed is a separation column for micro gas chromatography, having superior separation performance and including a microchannel formed on a substrate and having a serpentine shape, and bumps formed on the surface of the microchannel, wherein the bumps are alternately disposed to face each other on the surface of the microchannel. In the separation column for micro gas chromatography, a sufficient pressure drop occurs, and thus an interaction between a gas mixture to be analyzed and a stationary phase in the column sufficiently takes place, whereby individual gas components are efficiently separated from the gas mixture, discharged from the column, and detected.