Provided are electrolyte films or cells for use in variety of applications, such as electrochromic windows. An electrolytic film comprises a polymer layer, such as thermoplastic polyurethane or polymethyl methacrylate, and an electrolyte within the polymer layer. The electrolyte comprises a salt and a plasticizer. The plasticizer comprises one or more materials that are selected to provide sufficient conductivity and optical transparency for operation of the electrolyte film in an application requiring substantial optical clarity and switching speed, such as a smart window.

The present application discloses a method for preparing an electrochromic device. The method includes placing an edge protection material on a first and second substrates, placing a first and second interlayers respectively within the edge protection material on the first and second substrates, wherein the edge protection material surrounds edges of the first and second interlayers, and interposing an electrochromic film between the first and second interlayers. The edge protection material prevents chemicals in the first and second interlayers from entering into the electrochromic film.

In the electrochromic device according to an embodiment of the present application, when the first voltage is applied to the electrochromic device in a state that the electrochromic element has the first state, the electrochromic device becomes the second state, and when the first voltage is applied to the electrochromic element in a state that the electrochromic element has the fourth state, the electrochromic element becomes the third state.

Electrochromic device including: first electrode; a first auxiliary electrode; a second electrode; a second auxiliary electrode having average distance of 100 mm or less with the first auxiliary electrode; an electrochromic layer; a solid electrolyte layer; and controlling unit configured to control to apply voltage according to a driving pattern that is at least one selected from the group consisting of a first driving pattern, a second driving pattern, and an initialization driving pattern, wherein the first driving pattern is a driving pattern configured to turn the electrochromic layer into first coloring state, the second driving pattern is a driving pattern configured to turn the first coloring state into a second coloring state that has coloring density lower than coloring density of the first coloring state, and the initialization driving pattern is driving pattern for forming an initial decolored state.

According to one embodiment, a viewing angle control element includes a first substrate, a second substrate, and an electrolyte layer. The first substrate includes a first transparent substrate, a first light-shielding portion and a second light-shielding portion provided between the first transparent substrate and the electrolyte layer, a first transparent insulating layer provided between the first light-shielding portion and the second light-shielding portion, and a first transparent electrode. The first transparent electrode includes a first electrode portion overlapping the first light-shielding portion, a second electrode portion overlapping the second light-shielding portion, and an opening portion overlapping the first transparent insulating layer.

A flexible variable emissivity electrochromic device and a preparation method thereof are disclosed. The device includes a working electrode, a gel electrolyte layer, and a counter electrode sequentially from top to bottom. The working electrode includes a flexible polymer film and a metal film, the flexible polymer film is a surface-modified film and/or a film with a transition layer plated on a lower side thereof, and the metal film is deposited on the surface-modified film or the transition layer. The electrolyte layer includes a porous membrane and an electrolyte. The electrolyte is infiltrated in the porous membrane. The electrolyte includes an electrochromic material containing metal ions and a solvent, the metal ions enable reversible electrodeposition and dissolution, and metal of the metal ions is different from that used in the metal film. The preparation method includes preparing and assembling a working electrode, a gel electrolyte layer and a counter electrode.

An object of the present invention is to provide a novel electrochromic device (ECD). Disclosed is an electrochromic device (ECD) comprising two metal-complex-based electrochromic thin films individually acting as a working electrode and a counter electrode; (i) one of the two metal-complex-based electrochromic thin films being a film of a cathodically coloring metallo-supramolecular polymer comprising at least one organic ligand having a plurality of metal coordination positions and a metal ion of at least one transition metal and/or lanthanoid metal with the at least one organic ligand and the metal ion being arranged alternately, and the other of the two metal-complex-based electrochromic thin films being a film of an anodically coloring metal hexacyanoferrate (MHCF) represented by the formula: M(II).sub.3[Fe(III)CN.sub.6].sub.2 (where M=Fe, Ni or Zn), and (ii) the electrochromic device having a first conducting substrate; the film of the cathodically coloring metallo-supramolecular polymer; an electrolyte; the film of the anodically coloring metal hexacyanoferrate (MHCF); and a second conducting substrate being arranged in this order.

The present disclosure relates generally to multi-layer display devices including electrochromic material and methods of making the same. The display device may include one or more of a first layer comprising a first substrate depicting a display pattern; a second layer comprising an electrochromic polymer; a third layer comprising a solid state electrolyte; a fourth layer comprising a charge storage layer; a fifth layer comprising a second substrate, and/or other components. The one or more of the second layer, the third layer, and/or the fourth layer may be interposed between the first layer and the fifth layer. An application of a voltage between the first substrate and the second substrate may case a change in transmission and/or reflectance of light through the display device such that the display pattern on the first substrate may be displayed.

This invention discloses how EC devices can be fabricated as tags or labels; and further the materials used, device structures and how these can be processed by printing technologies. In addition, systems using displays of such EC devices and their integration with other components are described for forming labels and tags, etc, that may be actuated wirelessly or powered with low voltage and low capacity batteries.

Achieving precise, localized reversible control of optical material properties is challenging. Fortunately, electrochemical reactions and proton pumping in a solid-state system provide reversible electrical control of the solid-state system's optical properties. Applying a voltage to a thin solid electrolyte layer, such as GdO.sub.x, splits water into O.sub.2 and H.sup.+ (with charge conservation ensured by electron transfer at the electrodes) at the interface between the solid electrolyte and an electrode. The voltage drives the protons into the solid electrolyte, changing the solid electrolyte's refractive index. Reversing the polarity of the applied voltage drives the protons out of the solid electrolyte, reversing the refractive index change. This reversible electrical control can be used to implement interference color modulation, transmission modulation, and switchable plasmonics. Because the solid electrolyte can be less than 10 nanometers thick, this electrochemical control enables highly localized control of optical properties active plasmonic devices and reconfigurable metamaterials.