An energy storage device includes a cathodic material in an activated state; and an anodic material in an activated state; wherein: the cathodic material is a viologen covalently attached to, or confined within, a first polymer matrix, the first polymer matrix is configured to prevent or minimize substantial diffusion of the cathodic material in the activated state; and the anodic material is a phenazine, a phenothiazine, a triphenodithiazine, a carbazole, a indolocarbazole, a biscarbazole, or a ferrocene covalently attached to, or confined within, a second polymer matrix, the second polymer matrix is configured to prevent or minimize substantial diffusion of the anodic material in the activated state.

An electrochromic medium includes a solvent, a first pair of a first anodic material and a first cathodic material, and at least one of a second anodic material and a second cathodic material. At least one of the first anodic material and the first cathodic material is an electrochromic absorbing in the visible range, and at least one of the second anodic material and the second cathodic material is electrochromic absorbing in the visible range.

Protic-soluble electrochromic materials, ion-paired electrochromic materials including protic-soluble electrochromic materials, as well as electrochromic media and electrochromic devices incorporating such materials, are provided. The use of protic solvent mixtures, especially mixtures incorporating water, allows for the use of a wider variety of substrate materials. For example, plastics that may be soluble in organic aprotic solvent systems may be used in water-based devices.

An electrochromic device is structured to selectively switch separate regions to separate transmission levels, based at least in part upon different transport rates of different charged electrolyte species in the separate regions. Charged electrolyte species can be introduced in various regions of one or more electrochromic stack layers, including a counter-electrode layer, ion-conducting layer, and electrochromic layer. The charged electrolyte species can have different transport rates, so that a distribution of one species introduced in some regions move between layers and different rates relative another distribution of another species introduced in some regions. A species can be introduced, in one or more regions, in one or more particular distributions associated with a particular transmission pattern to structure the electrochromic device to selectively switch to the particular transmission pattern. Species can be introduced via various processes, including ion implantation, chemical diffusion, etc.

An electrochromic device is structured to restrict moisture permeation between an electrochromic stack in the device and an external environment. The electrochromic device includes conductive layers and one or more encapsulation layers, where the encapsulation layers and conductive layers collectively isolate the electrochromic stack from the ambient environment. The encapsulation layers resist moisture permeation, and at least the outer portions of the conductive layers resist moisture permeation. The moisture-resistant electrochromic device can be fabricated based at least in part upon selective removal of one or more outer portions of at least the EC stack, so that at least the encapsulation layer extends over one or more edge portions of the EC stack to isolate the edge portions of the EC stack from the ambient environment. The encapsulation layer can include one or more of an anti-reflective layer, infrared cut-off filter, etc.

An electrochromic device is structured to selectively switch separate regions to separate transmission levels, based at least in part upon different respective sheet resistances of separate conductive layer regions. Sheet resistance of a conductive layer region can be associated with a transmission level to which a corresponding EC stack region can be switched, and a conductive layer with separate regions having separate sheet resistances causes corresponding EC stack regions to switch to different transmission levels. Sheet resistance in a conductive layer region can be adjusted via various processes, including introducing various chemical species into the conductive layer region to adjust a chemical species distribution in the region, where the chemical species distribution is associated with the sheet resistance of the region, heating conductive layer regions to induce oxidation of the region, adjusting the thickness of a conductive layer region, etc.

An electrochromic device includes a chamber defined by a first conductive surface of a first substrate, a second conductive surface of a second substrate, and a sealing member joining the first substrate to the second substrate; an electrochromic medium containing a blue cathodic electroactive compound and up to three anodic electroactive compounds; wherein the electrochromic medium is disposed within the chamber; the anodic electroactive compounds include a green anodic electroactive compound and one or two gray anodic electroactive compounds; and the anodic electroactive compounds include from about 8 mol % to about 15 mol % gray anodic electroactive compounds.

An electrochromic device is structured to include multiple independently controllable electrochromic regions which can be independently controlled to switch to different transmission levels. One of the electrochromic regions is isolated from any direct electrical connection with any electrodes, and one or more other electrochromic regions interpose an indirect electrical connection between one or more electrodes and the isolated electrochromic region. The electrochromic device can be structured to include multiple independently controllable electrochromic regions, based at least in part upon segmentation of the conductive layers into separate segments to establish the various electrochromic regions.

The present disclosure relates to relates to heat-resistant gel electrolyte materials and their uses, for example, in electrochromic devices such as electrochromic windows. In certain embodiments, the disclosure provides an electrolyte material including a polymer of ethyleneimine, optionally at least partially crosslinked (e.g., with an epoxide crosslinker such as the diglycidyl ether of bisphenol A); a lithium salt (e.g., lithium perchlorate); and a high-boiling solvent (e.g., DMSO). The electrolyte materials can be used in electrochromic devices, such as electrochromic windows, e.g., for use as automobile sunroofs.

A multi-layer device comprising a first substrate and a first electrically conductive layer on a surface thereof, the first electrically conductive layer having a sheet resistance to the flow of electrical current through the first electrically conductive layer that varies as a function of position.