Herein are described two-dimensional metal organic frameworks (2D MOFs). The 2D MOFs includes a plurality of multivalent metals or metal ions and a plurality of multidentate ligands arranged to form a crystalline structure having a lateral size of at least about 2.5 μm and a thickness of less than about 5 nm. Herein are also described methods for preparing the 2D MOFs. The 2D MOFs can be used, for example, in electrochromic devices such as smart windows and flexible displays.

The present invention concerns an electrochromic device, a method for depositing an organic electrochromic material and a method for producing an electrochromic device. The device is preferably an electrochromic display, preferably a full-color electrochromic display. The device preferably comprises an electrodeposited organic electrochromic material and/or a polymeric organic electrochromic material.

Disclosed is an electrochromic device including an electrolyte layer having first and second surfaces directed in opposite directions, an electrochromic layer provided on the first surface of the electrolyte layer, a counter electrode layer provided on the second surface of the electrolyte layer, a first transparent electrode layer provided on a surface opposite to the electrolyte layer based on the electrochromic layer, and a second transparent electrode layer provided on a surface opposite to the electrolyte layer based on the counter electrode layer, in which the first and second transparent electrode layers are each provided as a composite layer in which an oxide-based electrode layer made of a material selected from a group consisting of AZO, FTO, and ITO and a metal-based electrode layer made of a material selected from a group consisting of nanowires (AgNWs), PEDOT:PSS, graphene, and a metal mesh are laminated.

The present disclosure relates to a method for manufacturing a flexible electrochromic device, and more particularly, to a method for manufacturing a flexible electrochromic device that bonds an electrochromic part and a counter electrode part while solidifying a wet-coated electrolyte with ultraviolet rays, thereby being capable of eliminating the possibility of bubble generation in the electrolyte and improving transmittance characteristics and durability.

A method of making an electrochromic device, includes: providing an electrochromic layer comprising a p-type electrochromic material; providing an ion-storage layer comprising an n-type metal oxide; and tuning the ion-storage layer, the electrochromic layer, or both the ion-storage layer and the electrochromic layer, so that when the electrochromic device is operating, the ion-storage layer operates in a minimally color changing mode.

The color of an electrochromic stack in a tinted state may be modified to achieve a desired color target by utilizing various techniques alone or in combination. A first approach generally involves changing a coloration efficiency of a WO.sub.x electrochromic (EC) layer by lowering a sputter temperature to achieve a WO.sub.x microstructural change in the EC layer. A second approach generally involves utilizing a dopant (e.g., Mo, Nb, or V) to improve the neutrality of the tinted state of WO.sub.x (coloration efficiency changes). A third approach generally involves tailoring a thickness of the WO.sub.x layer to tune the color of the tinted stack.

An electrochromic device according to an embodiment includes a first transparent conductive layer, an ion storage layer, an electrolyte layer, an electrochromic layer, and a second transparent conductive layer. The electrolyte layer includes a tantalum atom. The electrochromic layer includes a tungsten atom. The ion storage layer includes an iridium atom and a tantalum atom. The ion storage layer is hydrogenated in bleached state and the electrochromic device has a transmittance of 64.1% or more in bleached state. A difference between the transmittance of the electrochromic device in bleached state and the transmittance of the electrochromic device in colored state is 8.4% or more.

A insulated glazing unit is disclosed. The insulated glazing unit can include a first panel, a second panel, an electrochromic device coupled to the first panel, an electronics module coupled to the second panel, and a photovoltaic module coupled to the electronics module, the electrochromic device, and the first panel. In one embodiment, the first panel has a first length and the second panel has a second length, where the second length is less than the first length.

An imaging system for a portable electronic device includes a variable aperture between a lens group and an image sensor. The variable aperture is defined by an electrochromic stack that defines a switching region and a central non-switching region. The electrochromic stack is defined by a layer of electrochromic material in which an electrochromic crystallite dispersion (e.g., nickel oxide) is suspended in a field of a lithiated ion conductor layer (e.g., lithiated tungsten nickel oxide).

Various embodiments herein relate to electrochromic devices, methods of fabricating electrochromic devices, and apparatus for fabricating electrochromic devices. In a number of cases, the electrochromic device may be fabricated to include a particular counter electrode material. The counter electrode material may include a base anodically coloring material. The counter electrode material may further include one or more halogens. The counter electrode material may also include one or more additives.