Patent classifications
G03G5/047
Electrophotographic photoconductor, method of manufacturing the same, and electrophotographic device
Provided are an electrophotographic photoconductor being resistant to abrasion even in long-term use, having highly sensitive electric characteristics, being capable of maintaining a high retention rate, and being capable of providing a stable image without filming, a method of manufacturing the same, and an electrophotographic device. The photoconductor includes an electroconductive substrate (1), a charge generation layer (3), and a charge transport layer (4); the charge transport layer contains a hole transport material, a resin binder, an electron transport material, and an inorganic oxide; the charge generation layer contains a charge generation material; the masses of the hole transport material, the resin binder, the electron transport material, and the inorganic oxide in the charge transport layer respectively denoted by a to d satisfy 1.5≤b/a≤5.7, 0.005≤c/a≤0.35, 0.05≤d/a≤0.70, a≥c+d, and c/d≥0.01; the hole transport material contains a compound expressed by formula (A-1); and the charge generation material contains titanyl phthalocyanine having an exothermic peak at 251±5° C., a half-value width of the exothermic peak equal to or less than 15° C., and a heating value equal to or greater than 1.0 mJ/mg when a temperature rise condition is 20° C./min in differential scanning calorimetry, and having an X-ray diffraction peak at 27.2±0.3°. ##STR00001##
Electrophotographic photoconductor, method of manufacturing the same, and electrophotographic device
Provided are an electrophotographic photoconductor being resistant to abrasion even in long-term use, having highly sensitive electric characteristics, being capable of maintaining a high retention rate, and being capable of providing a stable image without filming, a method of manufacturing the same, and an electrophotographic device. The photoconductor includes an electroconductive substrate (1), a charge generation layer (3), and a charge transport layer (4); the charge transport layer contains a hole transport material, a resin binder, an electron transport material, and an inorganic oxide; the charge generation layer contains a charge generation material; the masses of the hole transport material, the resin binder, the electron transport material, and the inorganic oxide in the charge transport layer respectively denoted by a to d satisfy 1.5≤b/a≤5.7, 0.005≤c/a≤0.35, 0.05≤d/a≤0.70, a≥c+d, and c/d≥0.01; the hole transport material contains a compound expressed by formula (A-1); and the charge generation material contains titanyl phthalocyanine having an exothermic peak at 251±5° C., a half-value width of the exothermic peak equal to or less than 15° C., and a heating value equal to or greater than 1.0 mJ/mg when a temperature rise condition is 20° C./min in differential scanning calorimetry, and having an X-ray diffraction peak at 27.2±0.3°. ##STR00001##
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, AND ELECTROPHOTOGRAPHIC APPARATUS
Provided is an electrophotographic photosensitive member including a support, an undercoat layer, a charge-generating layer, and a charge-transporting layer in the stated order, wherein with regard to an S.sub.0, an S.sub.1, an S.sub.2, an S.sub.3, and an S.sub.4 determined by a specific procedure (A), a ratio S.sub.1/S.sub.0 is 0.34 or less, and one of the S.sub.2, the S.sub.3, or the S.sub.4 is a positive value, and the other two thereof are negative values, or two thereof are positive values, and the other one thereof is a negative value.
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, AND ELECTROPHOTOGRAPHIC APPARATUS
Provided is an electrophotographic photosensitive member including a support, an undercoat layer, a charge-generating layer, and a charge-transporting layer in the stated order, wherein with regard to an S.sub.0, an S.sub.1, an S.sub.2, an S.sub.3, and an S.sub.4 determined by a specific procedure (A), a ratio S.sub.1/S.sub.0 is 0.34 or less, and one of the S.sub.2, the S.sub.3, or the S.sub.4 is a positive value, and the other two thereof are negative values, or two thereof are positive values, and the other one thereof is a negative value.
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, AND ELECTROPHOTOGRAPHIC APPARATUS
Provided is an electrophotographic photosensitive member including a support, a photosensitive layer, and a surface layer, wherein the surface layer includes a cured product of a composition containing at least one selected from the group consisting of: a charge-transportable compound; and electroconductive particles, and an organic salt having a polymerizable functional group, and wherein the organic salt is formed of an organic cation and at least one anion selected from the group consisting of: an organic anion; and an inorganic anion.
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, AND ELECTROPHOTOGRAPHIC APPARATUS
Provided is an electrophotographic photosensitive member including a support, a photosensitive layer, and a surface layer, wherein the surface layer includes a cured product of a composition containing at least one selected from the group consisting of: a charge-transportable compound; and electroconductive particles, and an organic salt having a polymerizable functional group, and wherein the organic salt is formed of an organic cation and at least one anion selected from the group consisting of: an organic anion; and an inorganic anion.
ELECTROPHOTOGRAPHIC PHOTORECEPTOR AND IMAGE FORMING DEVICE EQUIPPED THEREWITH, AND METHOD FOR PRODUCING ELECTROPHOTOGRAPHIC PHOTORECEPTOR AND CHARGE TRANSPORTING LAYER COATING LIQUID USED THEREFOR
This electrophotographic photoreceptor includes at least a laminated photoreceptive layer, in which a charge generating layer and a charge transporting layer are laminated in this order on a conductive base. The charge transporting layer contains at least a charge transporting substance, a binder resin, and silica particles, and contains 0.1 ppm or more and 20 ppm or less of Na element and/or 0.01 ppm or more and 10 ppm or less of K element.
ELECTROPHOTOGRAPHIC PHOTORECEPTOR AND IMAGE FORMING DEVICE EQUIPPED THEREWITH, AND METHOD FOR PRODUCING ELECTROPHOTOGRAPHIC PHOTORECEPTOR AND CHARGE TRANSPORTING LAYER COATING LIQUID USED THEREFOR
This electrophotographic photoreceptor includes at least a laminated photoreceptive layer, in which a charge generating layer and a charge transporting layer are laminated in this order on a conductive base. The charge transporting layer contains at least a charge transporting substance, a binder resin, and silica particles, and contains 0.1 ppm or more and 20 ppm or less of Na element and/or 0.01 ppm or more and 10 ppm or less of K element.
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, AND ELECTROPHOTOGRAPHIC APPARATUS
Provided is an electrophotographic photosensitive member having a feature in that, in a graph that is obtained by a method of measuring an EV curve, and that has a horizontal axis representing I and a vertical axis representing V, when V at I=0.500 [μJ/cm.sup.2] is represented by V.sub.r [V], a maximum value of S [V.Math.μJ/cm.sup.2] represented by S=I.Math.(V−V.sub.r) in a range of I=0.000 to 0.030 [μJ/cm.sup.2] is represented by S.sub.max [V.Math.μJ/cm.sup.2], and a product of a light amount I.sub.i [μJ/cm.sup.2] on the horizontal axis and a potential V.sub.i[V] on the vertical axis at a point of intersection between an approximate straight line in a range of I=0.000 to 0.010 [μJ/cm.sup.2] and an approximate straight line in a range of I=0.490 to 0.500 [μJ/cm.sup.2] is represented by S.sub.i=I.sub.i.Math.(V.sub.i−V.sub.r) [V.Math.μJ/cm.sup.2], a ratio of S.sub.i to S.sub.max, which is represented by AR=S.sub.i/S.sub.max, satisfies AR≤0.10.
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, AND ELECTROPHOTOGRAPHIC APPARATUS
Provided is an electrophotographic photosensitive member having a feature in that, in a graph that is obtained by a method of measuring an EV curve, and that has a horizontal axis representing I and a vertical axis representing V, when V at I=0.500 [μJ/cm.sup.2] is represented by V.sub.r [V], a maximum value of S [V.Math.μJ/cm.sup.2] represented by S=I.Math.(V−V.sub.r) in a range of I=0.000 to 0.030 [μJ/cm.sup.2] is represented by S.sub.max [V.Math.μJ/cm.sup.2], and a product of a light amount I.sub.i [μJ/cm.sup.2] on the horizontal axis and a potential V.sub.i[V] on the vertical axis at a point of intersection between an approximate straight line in a range of I=0.000 to 0.010 [μJ/cm.sup.2] and an approximate straight line in a range of I=0.490 to 0.500 [μJ/cm.sup.2] is represented by S.sub.i=I.sub.i.Math.(V.sub.i−V.sub.r) [V.Math.μJ/cm.sup.2], a ratio of S.sub.i to S.sub.max, which is represented by AR=S.sub.i/S.sub.max, satisfies AR≤0.10.