A method for producing an electrostatic image developing toner includes a step 1 of producing toner particles by a wet process, the toner particles including an amorphous polyester resin, a crystalline polyester resin, and a vinyl resin, and a step 2 of bringing acidic water into contact with the toner particles.

The toner comprises a toner particle that contains a binder resin, a polymer C, and a pigment, wherein at least a portion of the polymer C is bonded with at least a portion of the pigment; in solid-state NMR measurement at 60° C. using as a sample, a solid fraction collected according to a prescribed procedure in which the toner is dissolved in chloroform, transverse relaxation time T2 of a peak observed at 1.5 ppm to 2.5 ppm is 1.0 ms to 50.0 ms; and using a SP.sub.A (J/cm.sup.3).sup.0.5 for a SP value of the binder resin and a SP.sub.B (J/cm.sup.3).sup.0.5 for a SP value of the polymer C, the SP.sub.A and the SP.sub.B satisfy a following formula (1).

1.0≤SP.sub.A−SP.sub.B≤2.4  (1)

A toner comprising a toner particle, wherein the toner particle comprises a binder resin, the binder resin comprises a resin A and a resin B, the toner particle comprises protrusions on a surface thereof, each of the protrusions comprises the resin B, a shape factor SF-2 of the toner as observed under SEM is 105 to 120, and when the toner is observed under the SEM, a surface unevenness index of the toner as calculated by formula (1) below is 0.010 to 0.050:
Surface unevenness index=(area of region surrounded by convex hull of toner−projected area of toner)/projected area of toner  (1).

The present invention provides an aqueous pigment dispersion liquid being such that a pigment is finely dispersed, and the viscosity, and the particle diameters of the pigment are unlikely to fluctuate, being excellent in storage stability, and enabling preparation of an emulsion-polymerized toner having properly controlled particle diameters while improving the pigment utilization rate. The aqueous pigment dispersion liquid is an aqueous pigment dispersion liquid for an emulsion-polymerized toner containing a pigment, a dispersant, and an aqueous medium. The dispersant is a polymer containing a constitutional unit (A) derived from a monomer (A) such that a group containing a (meth)acryloyloxy group or the like is bonded to one end of a particular polyethylene glycol chain or the like, and a constitutional unit (B) derived from a monomer (B) having a carboxy group or the like, the polymer has a number average molecular weight in terms of polystyrene of 4,000 to 15,000, as measured by gel permeation chromatography, the polymer is contained in a state of being not ionized substantially, and the aqueous pigment dispersion liquid has a pH of 3.0 to 8.4.

A toner for developing an electrostatic charge image contains toner particles containing at least one binder resin; the Mg element in an amount such that in an x-ray fluorescence analysis of the toner, the net intensity of the peak for the Mg element is 0.10 kcps or more and 1.20 kcps or less; and at least one external additive including particles of at least one compound represented by formula (1),
MTiO.sub.3  (1)
where M represents at least one selected from the group consisting of Ca, Sr, and Ba.

Disclosed herein is a toner composition, developer and additive for a toner composition. The toner composition includes toner particles having at least one resin, an optional colorant, an optional wax, and a crosslinked polymer particle on at least a portion of an external surface of the toner particles. The crosslinked polymeric particle on a surface of the toner particles includes at least a hydrophobic monomer comprising a non-fluorinated monomer having a carbon to oxygen (C/O) ratio of 3 or greater or a fluorinated monomer. The crosslinked polymer particle includes a second monomer comprising two or more vinyl groups present in an amount from about 8 wt % to about 40 wt % of the copolymer, a metal oxide and optionally a charge control agent monomer.

Provided is a toner has a toner particle containing a binder resin and is characterized in that the binder resin contains a polymer A, which is a polymer of a composition containing a first polymerizable monomer, a second polymerizable monomer and a crosslinking agent, the first polymerizable monomer is at least one monomer selected from the group consisting of (meth)acrylic acid esters having an alkyl group with 18 to 36 carbon atoms, the crosslinking agent has two or more polymerizable double bonds, a content of the first polymerizable monomer in the composition is 5.0 to 60.0 mol %, a content of the second polymerizable monomer is 20.0 to 95.0 mol %, and when the SP values of the first polymerizable monomer, the second polymerizable monomer and the crosslinking agent are denoted by SP.sub.12, SP.sub.22 and SP.sub.C2, respectively, the formulae 0.60≤(SP.sub.22−SP.sub.12)≤15.00 and SP.sub.12<SP.sub.C2<(SP.sub.22+3.00) are satisfied.

A toner for developing an electrostatic charge image contains toner particles containing at least one binder resin; the Mg element in an amount such that in an x-ray fluorescence analysis of the toner, the net intensity of the peak for the Mg element is 0.10 kcps or more and 1.20 kcps or less; and at least one external additive including particles of at least one compound represented by formula (1),

MTiO.sub.3  (1)

where M represents at least one selected from the group consisting of Ca, Sr, and Ba.

A toner comprises a toner particle containing a resin component and a wax; and an inorganic fine particle on a surface of the toner particle, wherein in the cross section of the toner particle, domains including the wax are present in a region ranging from a surface of the toner particle to a depth of 600 nm from the surface, wherein when a percentage ratio of sum of areas of all the domains in the region with respect to an area of the region is R2, and when a percentage ratio of sum of areas of the domains having a major diameter of 10 to 120 nm in the region with respect to the area of the region is R1, R1 and R2 satisfy the following formulae (1) and (2):

2.0≤R1(%)≤15.0  formula(1)

R1(%)/R2(%)≥0.60  formula (2).

Provided is an image forming method, including: transferring and fixing a toner onto a recording medium, and forming an image including a plurality of layers, in which an attachment amount of the toner on the recording medium is greater than or equal to 8 g/m.sup.2 and less than or equal to 40 g/m.sup.2, a toner forming a layer in contact with a fixing member contains at least a first mold release agent containing ester wax and a second mold release agent containing microcrystalline wax, and a special color toner is contained in any layer of the plurality of layers.