Provided are a magnetic tape including a non-magnetic support and a magnetic layer including a ferromagnetic powder, a magnetic tape cartridge and a magnetic tape apparatus including this magnetic tape. An amount of a fluid lubricant collected by wiping a surface of the magnetic layer by a nonwoven fabric is in a range of 5 to 400 ng/m.sup.2 as a value per unit area of the surface of the magnetic layer.

The present technology provides a tape-shaped magnetic recording medium including: a magnetic layer; an underlayer; a base layer; and a back layer, in which the number of recesses having a depth of 20% or more of the thickness of the magnetic layer is 10 or more and 200 or less per surface area of 1600 μm.sup.2, the base layer includes a polyester as a main component, a surface on a side of the back layer has a kurtosis of 2.0 or more and 4.4 or less, the magnetic recording medium has an average thickness t.sub.T of 5.6 μm or less, the magnetic recording medium includes a lubricant, the magnetic recording medium has pores, and the pores have an average diameter of 6 nm or more and 11 nm or less when the diameters of the pores are measured in a state where the lubricant has been removed from the magnetic recording medium and the magnetic recording medium has been dried.

The present technology provides a tape-shaped magnetic recording medium including: a magnetic layer; an underlayer; a base layer; and a back layer, in which the number of recesses having a depth of 20% or more of the thickness of the magnetic layer is 10 or more and 200 or less per surface area of 1600 μm.sup.2, the base layer includes a polyester as a main component, a surface on a side of the back layer has a kurtosis of 2.0 or more and 4.4 or less, the magnetic recording medium has an average thickness t.sub.T of 5.6 μm or less, the magnetic recording medium includes a lubricant, the magnetic recording medium has pores, and the pores have an average diameter of 6 nm or more and 11 nm or less when the diameters of the pores are measured in a state where the lubricant has been removed from the magnetic recording medium and the magnetic recording medium has been dried.

The magnetic recording medium contains, in a magnetic layer, a fatty acid ester and a polyester resin having a number average molecular weight of greater than or equal to 1,000 but less than 20,000, and containing a structural unit derived from a polyvalent carboxylic acid and a structural unit derived from a polyol, as well as 10 mol % to 50 mol % of a structural unit, derived from a cyclic polyvalent carboxylic acid selected from the group consisting of an alicyclic polyvalent carboxylic acid and an aromatic polyvalent carboxylic acid, per 100 mol % of a combined total of the above structural units, and one or more partial structures selected from the group consisting of the following partial structures:

##STR00001##

wherein each of L.sup.1 and L.sup.2 independently denotes a divalent connecting group, and each of Z.sup.1 and Z.sup.2 independently denotes a monovalent group denoted by —OM or a monovalent group denoted by —O.sup.−A.sup.+.

The magnetic recording medium contains, in a magnetic layer, a fatty acid ester and a polyester resin having a number average molecular weight of greater than or equal to 1,000 but less than 20,000, and containing a structural unit derived from a polyvalent carboxylic acid and a structural unit derived from a polyol, as well as 10 mol % to 50 mol % of a structural unit, derived from a cyclic polyvalent carboxylic acid selected from the group consisting of an alicyclic polyvalent carboxylic acid and an aromatic polyvalent carboxylic acid, per 100 mol % of a combined total of the above structural units, and one or more partial structures selected from the group consisting of the following partial structures:

##STR00001##

wherein each of L.sup.1 and L.sup.2 independently denotes a divalent connecting group, and each of Z.sup.1 and Z.sup.2 independently denotes a monovalent group denoted by —OM or a monovalent group denoted by —O.sup.−A.sup.+.

The magnetic tape has a magnetic layer containing ferromagnetic powder, abrasive, and binder on a nonmagnetic support, wherein the centerline average surface roughness Ra measured on the surface of the magnetic layer is less than or equal to 1.8 nm, the contact angle for 1-bromonaphthalene that is measured on the surface of the magnetic layer falls within a range of 45.0° to 60.0°, and the coefficient of friction that is measured on the base portion of the surface of the magnetic layer is less than or equal to 0.35.

The magnetic tape has a magnetic layer containing ferromagnetic powder, abrasive, and binder on a nonmagnetic support, wherein the centerline average surface roughness Ra measured on the surface of the magnetic layer is less than or equal to 1.8 nm, the contact angle for 1-bromonaphthalene that is measured on the surface of the magnetic layer falls within a range of 45.0° to 60.0°, and the coefficient of friction that is measured on the base portion of the surface of the magnetic layer is less than or equal to 0.35.

The magnetic tape has a magnetic layer containing ferromagnetic powder and binder on one surface of a nonmagnetic support and has a backcoat layer containing nonmagnetic powder and binder on the other surface thereof, wherein the thickness of the backcoat layer is less than or equal to 0.20 μm, the contact angle for 1-bromonaphthalene that is measured on the surface of the backcoat layer falls within a range of 10.0° to 30.0°, and the contact angle for 1-bromonaphthalene that is measured on the surface of the magnetic layer falls within a range of 45.0° to 55.0°.

The magnetic tape has a magnetic layer containing ferromagnetic powder and binder on one surface of a nonmagnetic support and has a backcoat layer containing nonmagnetic powder and binder on the other surface thereof, wherein the thickness of the backcoat layer is less than or equal to 0.20 μm, the contact angle for 1-bromonaphthalene that is measured on the surface of the backcoat layer falls within a range of 10.0° to 30.0°, and the contact angle for 1-bromonaphthalene that is measured on the surface of the magnetic layer falls within a range of 45.0° to 55.0°.

The present invention relates to a novel process for the synthesis of (per)fluoropolyether polymers, to certain novel (per)fluoropolyether polymers. The present invention also relates to the use of the (per)fluoropolyether polymers thus obtained as intermediate compounds for the manufacture of further polymers suitable for use as lubricants, notably for magnetic recording media (MRM).