A real-time online analysis device for substance pyrolysis, including: a pyrolyzing system (1), a capturing system (2), a testing system (3) and a controlling system (4) is disclosed. The pyrolyzing system (1), the capturing system (2) and the testing system (3) are connected with the controlling system (4). The capturing system (2) has a cooling cavity (22) and a heating cavity (23) inside. The temperature of the cooling cavity (22) ranges from room temperature to −200° C., and the temperature of the heating cavity (23) ranges from room temperature to 1000° C. A method for real-time online analysis of substance pyrolysis using the device is also disclosed. The present device can provide real-time online pyrolysis, capturing, separation and analysis of substances at a plurality of temperature points or ranges.

A gas analysis device and a gas analysis method for performing measurement in a direct mode and a trap mode without carrying out a complicated control. The gas analysis device includes a branching section that branches a target gas, a mass spectrometer performing mass spectrometry of one branched target gas, a trap section holding the other branched target gas, a gas chromatograph analyzing the other branched target gas, and a controller controlling the flow path of the one branched target gas and the other branched target gas. The branching section is controlled so that, while a thermal analysis is performed by a thermal analysis device, the branching section continuously branches the supplied target gas and discharges the one branched target gas and the other branched target gas, and when the thermal analysis is completed, the other branched target gas held by the trap section is supplied to the gas chromatograph.

A method for simultaneous determination of nitrogen and oxygen isotope compositions of natural nitrate and nitrite, which quantitatively converts natural nitrate and nitrite into an organic ester and a nitro-compounds respectively, and then nitrate and nitrite δ.sup.18O and δ.sup.15N are simultaneously determined by adopting a gas chromatography/pyrolysis/gas chromatography/isotope ratio mass spectrometry coupling technology (GC/Py/GC/IRMS). According to the method for simultaneously determining the nitrogen and oxygen isotope compositions of the natural nitrate salt and nitrite salt, the small amount of sample does not result in the loss, acquisition, exchange and fractionation of nitrogen and oxygen.

The disclosure describes a method for simultaneous determination of nitrogen and oxygen isotope compositions of natural nitrate and nitrite, which quantitatively converts natural nitrate and nitrite into an organic ester and a nitro-compounds respectively, and then nitrate and nitrite δ.sup.18O and δ.sup.15N are simultaneously determined by adopting a gas chromatography/pyrolysis/gas chromatography/isotope ratio mass spectrometry coupling technology (GC/Py/GC/IRMS). According to the method for simultaneously determining the nitrogen and oxygen isotope compositions of the natural nitrate salt and nitrite salt, the small amount of sample does not result in the loss, acquisition, exchange and fractionation of nitrogen and oxygen.

A method for securing qualitative and quantitative information of a high molecular weight additive in a polymer resin sample is disclosed herein. In some embodiments, the method includes separating a fraction of a polymer resin sample using size exclusion chromatography (SEC), wherein the fraction corresponding to a high molecular weight additive, pyrolyzing the fraction in a pyrolysis-gas chromatography/mass spectrometer (Py-GC/MS) to obtain a mass spectrum of the pyrolyzed fraction; identifying a structure of the high molecular weight additive by comparing m/z values for fragment peaks in the mass spectrum to m/z values for fragment peaks in a mass spectrum of a standard, and determining the amount of the high molecular weight additive in the polymer resin sample, relative to the total weight of the polymer resin sample by comparing a sum of areas of the fragment peaks to a calibration line of the standard.

An analysis method is a method of analyzing a second substance in a sample including the second substance produced by decomposition of a first substance, and includes analyzing a sample and a compound having a known concentration and detecting the first substance, the second substance and the above-mentioned compound, calculating an intensity or a concentration of the first substance obtained from the above-mentioned data based on data obtained by the detection and a relative response factor in regard to the first substance and the above-mentioned compound, and producing information about an amount or a concentration of the second substance excluding the second substance produced from the first substance in the analysis, based on an intensity or a concentration of the first substance.

A method for evaluating a degree of transformation ratio of kerogen to oil and/or gas and/or gas to oil generation index using a pyrolysis gas chromatography is disclosed. The method comprises providing a rock sample in powdered form; determining, by a source rock analysis instrument, total organic carbon in said rock sample, remaining hydrocarbon generation potential in rock sample, and a maturity of rock sample; feeding said sample in a pyrolyzer if said sample satisfies a pre-defined condition; analyzing, said sample in said pyrolyzer, by heating said sample at a pre-specified pyrolysis temperature in pre-specified pyrolysis steps and for pre-specified pyrolysis time; determining, by a gas chromatograph, a peak area of hydrocarbons present in said sample analyzed; evaluating, in a said degree of transformation ratio of said sample to oil and/or gas and/or said gas to oil generation index.

An open system pyrolysis of a first hydrocarbon source rock sample obtained from a natural system is performed within a pyrolysis chamber by maintaining the pyrolysis chamber at a substantially constant temperature. Hydrocarbons are recovered from the pyrolysis chamber released by the first hydrocarbon source rock sample. A thermo-vaporization is performed within the pyrolysis chamber on the pyrolyzed sample at a substantially constant temperature. A first hydrocarbon expulsion efficiency of hydrocarbon source rock is determined. A second hydrocarbon rock sample is ground to a grain size less than or equal to or less than 250 micrometers. A second pyrolysis is performed on the ground hydrocarbon source rock sample by maintaining the chamber at a substantially constant temperature. A second hydrocarbon expulsion efficiency of the hydrocarbon source rock in the natural system is determined. The first hydrocarbon expulsion efficiency is verified using the second hydrocarbon expulsion efficiency.

A method for securing qualitative and quantitative information of a high molecular weight additive in a polymer resin sample is disclosed herein. In some embodiments, the method includes separating a fraction of a polymer resin sample using size exclusion chromatography (SEC), wherein the fraction corresponding to a high molecular weight additive, pyrolyzing the fraction in a pyrolysis-gas chromatography/mass spectrometer (Py-GC/MS) to obtain a mass spectrum of the pyrolyzed fraction; identifying a structure of the high molecular weight additive by comparing m/z values for fragment peaks in the mass spectrum to m/z values for fragment peaks in a mass spectrum of a standard, and determining the amount of the high molecular weight additive in the polymer resin sample, relative to the total weight of the polymer resin sample by comparing a sum of areas of the fragment peaks to a calibration line of the standard.

A gas analysis device and a gas analysis method capable of performing measurement in a direct mode and a trap mode without carrying out a complicated control. The gas analysis device includes a branching section that branches a target gas, a mass spectrometer that carries out mass spectrometry of one branched target gases, a trap section that holds the other branched target gases, a gas chromatograph that analyzes the other branched target gas held by the trap section, and a controller that controls the flow path of the one branched target gas and the other branched target gas. The branching section is controlled so that, while the thermal analysis is being carried out by the thermal analysis device, the branching section continuously branches the supplied target gas and discharges one branched target gas and the other branched target gas, and when the thermal analysis has been completed, the other branched target gas held by the trap section is supplied to the gas chromatograph.