Methods and apparatus for estimating parameters of interest of a volume in an earth formation from a response spectrum representing radiation information obtained by a radiation detector in a borehole intersecting the volume responsive to nuclear phenomena in the volume, the response spectrum including spectral distortion resulting i) environmental conditions in the formation, or ii) deterioration of at least one component of the radiation detector. Methods include recovering an enhanced response spectrum estimating the true spectrum, comprising mitigating the spectral distortion by applying at least one contrast sharpening mask to the response spectrum. The at least one contrast sharpening mask may comprise at least a low pass smoothing mask subtracted from a unity mask which when applied to the response spectrum obtains high-frequency data and adds the high-frequency data to the response spectrum. The response spectrum may be a gamma ray spectrum.

Methods, tools, and systems for determining CO.sub.2 saturation in a porous formation using pulsed neutron logging are described. Embodiments of a pulsed neutron logging tool feature a pulsed neutron generator configured to emit pulsed neutrons into the formation and at least two detectors configured to receive emitted photons. The first detector is located closer to the neutron generator than the second detector. Embodiments of the method involve determining first detector formation capture counts indicative of neutron capture photons originating from the formation and detected at the first detector, determining second detector borehole capture counts indicative of neutron capture photons originating from the borehole and detected at the second detector, using the first detector formation capture counts and the second detector borehole capture counts to estimate the saturation of CO.sub.2 in the formation.

The present disclosure is directed to methods for evaluating a gravel pack, a frac-pack, or cement in a wellbore. In at least one embodiment, a method for evaluating a gravel pack, frac-pack or cement in a wellbore, includes pumping a first material into the wellbore, wherein the first material comprises a first tracer that is not radioactive. The method includes pumping a second material into the wellbore, wherein the second material comprises a second tracer that is not radioactive. The method includes obtaining a set of data using the downhole tool in the wellbore after the first and second materials are pumped into the wellbore. The method includes obtaining a baseline using the downhole tool in the wellbore in a depth interval without the first or second material. The method includes comparing the set of data with the baseline.

Systems and methods are provided for distinguishing between elements located at different distances from a radiation detector used in neutron-induced gamma-ray spectroscopy using a Doppler effect. A pulsed neutron generator may emit neutrons out of a downhole tool in a geological formation at an energy level high enough to cause inelastic scattering with nuclei of an element to generate gamma-rays. A gamma-ray detector may detect the energy levels of the gamma-rays, in the reference frame of the detector, and data processing circuitry takes the detected spectrum of gamma-rays and distinguishes spectra of gamma-ray energy levels for nuclei of the element located nearer to or farther from the detector based at least in part on the Doppler shift of the energy levels of respective gamma-rays.

The present disclosure provides methods for identifying chemical diverter material placed in a borehole region and provides chemical diverter material. In one embodiment, a method for detecting diverter material placed in a borehole region includes (a) obtaining a first data set by: emitting pulses of neutrons from the pulsed neutron source into the borehole region and detecting capture gamma rays resulting from nuclear reactions in the borehole region; (b) placing a diverter material comprising aqueous-swellable particles and a thermal neutron absorbing material into the borehole region; (c) obtaining a second data set by: emitting pulses of neutrons from the first pulsed neutron source or a second pulsed neutron source into the borehole region, and detecting capture gamma rays in the borehole; and (d) comparing the first data set and the second data set to determine the location of diverter material placed in the borehole region.

Methods and systems for quantitatively determining pack density within a section of a wellbore are disclosed. The method compares acquired pulsed neutron measurements to models of the section having zero pack density and one hundred percent pack density and extrapolates the measured pulsed neutron data between those two extremes to quantitatively determine pack density. The methods and systems allow hydrocarbon saturation and pack density to be determined in a single trip of a pulsed neutron tool.

The present disclosure describes various embodiments related to methods for determining salinity of water in a borehole of a formation and the water in the formation. Various methods may use inelastic and capture gamma-ray spectra obtained from a pulsed neutron logging tool. Various embodiments may use a ratio of chlorine from a capture spectrum to oxygen from an inelastic spectrum for a near and a far detector to calculate apparent salinity ratios for water in a borehole and a formation. From the apparent salinity ratios, a borehole salinity and a formation salinity may be calculated using a tool characterization database and without using formation water saturation for the calculation. Other embodiments may be disclosed or claimed.

In some embodiments, a method and apparatus, as well as an article, may operate to estimate a property of an earth formation by generating at least one shale model to represent an earth formation comprised of a non-zero percentage of shale. The shale model includes two curves to represent a relationship between a porosity parameter and a pulsed neutron measurement at two different corresponding percentages of gas saturation, respectively. A matrix model representing an earth formation with 0% shale is combined with one or more shale models to create a formation model. Measured pulsed neutron data is compared with the formation model to estimate a property of the earth formation. Additional apparatus, systems, and methods are disclosed.

Systems and methods are provided for distinguishing between elements located at different distances from a radiation detector used in neutron-induced gamma-ray spectroscopy using a Doppler effect. A pulsed neutron generator may emit neutrons out of a downhole tool in a geological formation at an energy level high enough to cause inelastic scattering with nuclei of an element to generate gamma-rays. A gamma-ray detector may detect the energy levels of the gamma-rays, in the reference frame of the detector, and data processing circuitry takes the detected spectrum of gamma-rays and distinguishes spectra of gamma-ray energy levels for nuclei of the element located nearer to or farther from the detector based at least in part on the Doppler shift of the energy levels of respective gamma-rays.

Systems and method presented herein enable the estimation of porosity using neutron-induced gamma ray spectroscopy. For example, the systems and methods presented herein include receiving, via a control and data acquisition system, data relating to energy spectra of gamma rays captured by one or more gamma ray detectors of a neutron-induced gamma ray spectroscopy logging tool. The method also includes deriving, via the control and data acquisition system, one or more spectral yields relating to one or more elemental components from the data relating to the energy spectra of the gamma rays. The method further includes estimating, via the control and data acquisition system, a measurement of porosity based on the one or more spectral yields relating to the one or more elemental components.