Described herein is a dental filler material having a core made of a core material and a shell made of a shell material, where the shell material coats or covers at least a portion of the core.

The invention relates to the use of a printing sol as construction material in an additive manufacturing process for producing a 3-dim article, the printing sol comprising solvent(s), nano-sized crystalline zirconia particles in an amount from 2 to 25 vol.-% with respect to the volume of the sol, the average primary particle size of the nano-sized crystalline zirconia particles being in a range up to 50 nm, a first monomer being a polymerizable surface modification agent represented by formula A-B, with A being capable of attaching to the surface of the nano-sized crystalline zirconia particles and B being a radiation curable group, optionally a second monomer, the second monomer comprising at least one radiation curable moiety but no acidic or silane group(s), photo initiator(s). The invention also relates to a ceramic article obtainable according to such a process.

The invention relates to the use of a printing sol as construction material in an additive manufacturing process for producing a 3-dim article, the printing sol comprising solvent(s), nano-sized crystalline zirconia particles in an amount from 2 to 25 vol.-% with respect to the volume of the sol, the average primary particle size of the nano-sized crystalline zirconia particles being in a range up to 50 nm, a first monomer being a polymerizable surface modification agent represented by formula A-B, with A being capable of attaching to the surface of the nano-sized crystalline zirconia particles and B being a radiation curable group, optionally a second monomer, the second monomer comprising at least one radiation curable moiety but no acidic or silane group(s), photo initiator(s). The invention also relates to a ceramic article obtainable according to such a process.

Systems and methods for additive manufacturing of ZrO.sub.2 ceramic objects, and in particular ZrO.sub.2-based ceramic dental crowns. A method includes mixing a doped ZrO.sub.2 powder with a photo-curable resin to produce a printing mixture, 3D printing of a dental crown green body structure using the printing mixture, wherein the 3D printing includes an advanced digital light processing (ADLP) process using a gradient printing technique to form a color gradient in the dental crown green body structure, debinding the dental crown green body structure to remove organic polymers using one of a thermal debinding process, an infrared debinding process, and a laser debinding process, sintering the debound dental crown structure to produce a densified dental crown structure using one of a pressureless sintering process, a laser sintering process, and an electric field sintering process, and surface engineering the densified dental crown structure to produce a finished dental crown structure using one of a mechanical polishing process, a laser polishing process, a laser shock peening process, a shot peening process, and a water jet process.

The invention relates to a porous zirconia article in particular for use in the dental or orthodontic field, the porous zirconia article comprising ZrO.sub.2: 80 to 87 wt. %, Y.sub.2O.sub.3: 3 to 5 wt. %, Al.sub.2O.sub.3: 10 to 14 wt. %, wt. % with respect to the weight of the porous zirconia article, the porous zirconia article being characterized by a BET surface from 15 to 100 m.sup.2/g. The invention also relates to a sintered zirconia article in particular for use in the dental or orthodontic field, the sintered zirconia article comprising ZrO.sub.2: 80 to 87 wt. %, Y.sub.2O.sub.3: 3 to 5 wt. %, Al.sub.2O.sub.3: 10 to 14 wt. %, wt. % with respect to the weight of the porous zirconia article, the sintered zirconia article being characterized by a corundum crystal phase content of 7 to 12 wt. % and a flexural strength of at least 2,000 MPa.

The invention relates to a porous zirconia article in particular for use in the dental or orthodontic field, the porous zirconia article comprising ZrO.sub.2: 80 to 87 wt. %, Y.sub.2O.sub.3: 3 to 5 wt. %, Al.sub.2O.sub.3: 10 to 14 wt. %, wt. % with respect to the weight of the porous zirconia article, the porous zirconia article being characterized by a BET surface from 15 to 100 m.sup.2/g. The invention also relates to a sintered zirconia article in particular for use in the dental or orthodontic field, the sintered zirconia article comprising ZrO.sub.2: 80 to 87 wt. %, Y.sub.2O.sub.3: 3 to 5 wt. %, Al.sub.2O.sub.3: 10 to 14 wt. %, wt. % with respect to the weight of the porous zirconia article, the sintered zirconia article being characterized by a corundum crystal phase content of 7 to 12 wt. % and a flexural strength of at least 2,000 MPa.

Systems, methods, components, and materials are disclosed for stereolithographic fabrication of three-dimensional, dense objects. A resin including at least one component of a binder system and dispersed particles can be exposed to an activation light source. The activation light source can cure the at least one component of the binder system to form a green object, which can include the at least one component of the binder system and the particles. A dense object can be formed from the green object by removing the at least one component of the binder system in an extraction process and thermally processing particles to coalesce into the dense object.

Systems, methods, components, and materials are disclosed for stereolithographic fabrication of three-dimensional, dense objects. A resin including at least one component of a binder system and dispersed particles can be exposed to an activation light source. The activation light source can cure the at least one component of the binder system to form a green object, which can include the at least one component of the binder system and the particles. A dense object can be formed from the green object by removing the at least one component of the binder system in an extraction process and thermally processing particles to coalesce into the dense object.

A root canal filling material composition comprising a lithium salt has higher healing promoting activity than conventional root canal filling material compositions. Preferable compositions are (1) a composition further comprising a calcium hydroxide, (2) a combination composition of a paste A containing a higher fatty acid and rosin and a paste B containing magnesium oxide and a vegetable oil, and one or both of the paste A and the paste B comprise the lithium salt, and (3) a combination composition of a paste A and a paste B and hardens by mixing the paste A and the paste B, one or both of the paste A and the paste B comprise the lithium salt, one or both of the paste A and the paste B comprise a glass powder, the glass powder contains calcium oxide and silicon dioxide in a total amount of 50 to 100% by weight relative to a total amount of the glass powder, and in the glass powder, a weight ratio of the calcium oxide to the silicon dioxide (calcium oxide:silicon dioxide) is 6:4 to 3:7.

A root canal filling material composition comprising a lithium salt has higher healing promoting activity than conventional root canal filling material compositions. Preferable compositions are (1) a composition further comprising a calcium hydroxide, (2) a combination composition of a paste A containing a higher fatty acid and rosin and a paste B containing magnesium oxide and a vegetable oil, and one or both of the paste A and the paste B comprise the lithium salt, and (3) a combination composition of a paste A and a paste B and hardens by mixing the paste A and the paste B, one or both of the paste A and the paste B comprise the lithium salt, one or both of the paste A and the paste B comprise a glass powder, the glass powder contains calcium oxide and silicon dioxide in a total amount of 50 to 100% by weight relative to a total amount of the glass powder, and in the glass powder, a weight ratio of the calcium oxide to the silicon dioxide (calcium oxide:silicon dioxide) is 6:4 to 3:7.