The invention relates to a solution for coloring and imparting fluorescence to a zirconia dental article, the solution comprising: •a solvent, •a coloring agent comprising ions selected from Tb, Er, Pr, Mn and combinations thereof, •a fluorescing agent comprising ions of Bi, the solution not comprising Fe ions in an amount above about 0.05 wt.-% with respect to the weight of the whole solution.

[Problem]

To support the metal without segregation on the zirconia mill blank for dental cutting and machining which has been adjusted to a hardness that enables to cut and machine by calcining at a low temperature.

[Solution]

A zirconia mill blank for dental cutting and machining is prepared by A preparing method of a zirconia mill blank for dental cutting and machining, comprising an impregnation step of impregnating a porous zirconia molded body with an impregnating solution containing at least one metal ion and at least one precipitant, and a deposition step of decomposing the precipitant in the porous zirconia molded body to deposit a metal compound.

The invention relates to glass ceramics and glasses with a europium content, containing the following components:

TABLE-US-00001 Component wt.-% SiO.sub.2 30.0 to 75.0 Al.sub.2O.sub.3 10.0 to 45.0 Europium, calculated as Eu.sub.2O.sub.3 0.05 to 5.0

and which are suitable in particular for the production of dental restorations, the fluorescence properties of which largely correspond to those of natural teeth.

[Problem]

A technique for imparting high translucency which is similar to an enamel of a natural tooth to a zirconia sintered body, has been required.

[Solution]

To provide a zirconia mill blank for dental cutting and machining, containing, an yttrium compound and an indium compound as stabilizers, wherein, an amount of the yttrium compound is within a range of 3.0 mol % to 6.0 mol % in terms of oxide, an amount of the indium compound is within a range of 0.2 mol % to 3.0 mol % in terms of oxide, and a total amount of the yttrium compound and the indium compound is within a range of 5.5 mol % to 7.0 mol % in terms of oxide.

The invention relates to a method to derive a medical form body of lithium silicate glass ceramic. To increase its strength it is proposed that in the form body comprising lithium silicate glass or containing lithium silicate glass the lithium ions are replaced by alkali ions of greater diameter to generate a surface compressive stress. To this end the form body is covered with a melt containing an alkali metal for which an aliquoted quantity of salt containing the alkali metal is used.

The invention relates to a method to derive a medical form body of lithium silicate glass ceramic. To increase its strength it is proposed that in the form body comprising lithium silicate glass or containing lithium silicate glass the lithium ions are replaced by alkali ions of greater diameter to generate a surface compressive stress. To this end the form body is covered with a melt containing an alkali metal for which an aliquoted quantity of salt containing the alkali metal is used.

A block for dental prostheses is in the form of a column or a board, a main crystalline phase of the block being of lithium disilicate, and when the block is observed in a field of view of a partially enlarged cross section of the block, the proportion of the total area of crystals having a length of at least 0.5 μm, the crystals appearing in the field of view, to an area of the field of view is at most 21%.

The present invention is related to a pink colored pre-sintered or fully-sintered blank for use for the production of a dental restoration, such as a denture base of a full or a partial denture, a partial denture, or an implant supported denture, consisting of a ceramic material which comprises zirconium dioxide doped with yttrium oxide (Y.sub.2O.sub.3), calcium oxide (CaO), magnesium oxide (MgO) and/or cerium oxide (CeO.sub.2), wherein the pink colored blank comprises 2 to 25 wt %, preferably 4 to 17 wt %, and more preferably 5 to 12 wt %, erbium oxide.

The present invention is related to a method for producing a ceramic multilayer blank comprising at least a first layer of a first ceramic material and at least a second layer of a second ceramic material, wherein the first layer and the second layer are made of ceramic materials of different compositions, which are filled in pourable condition layer-by-layer into a mold and thereafter they are pressed and then sintered, wherein the first layer is a pink colored layer, wherein the first ceramic material comprises 2 to 25 wt % erbium oxide.

The invention relates to the use of a printing sol as construction material in an additive manufacturing process for producing a 3-dim article, the printing sol comprising solvent(s), nano-sized crystalline zirconia particles in an amount from 2 to 25 vol.-% with respect to the volume of the sol, the average primary particle size of the nano-sized crystalline zirconia particles being in a range up to 50 nm, a first monomer being a polymerizable surface modification agent represented by formula A-B, with A being capable of attaching to the surface of the nano-sized crystalline zirconia particles and B being a radiation curable group, optionally a second monomer, the second monomer comprising at least one radiation curable moiety but no acidic or silane group(s), photo initiator(s). The invention also relates to a ceramic article obtainable according to such a process.