ZrO.sub.2-toughened glass ceramics having high molar fractions of tetragonal ZrO.sub.2 and fracture toughness value of greater than 1.8 MPa.Math.m.sup.1/2. The glass ceramic may also include also contain other secondary phases, including lithium silicates, that may be beneficial for toughening or for strengthening through an ion exchange process. Additional second phases may also decrease the coefficient of thermal expansion of the glass ceramic. A method of making such glass ceramics is also provided.

Provided herein are high performance dental restoration compositions, particularly two-part compositions having good self-cure times. Also provided herein are methods for restoring or filling a cavity in a tooth in an individual with the two-part dental restoration compositions. In particular, compositions provided herein are useful in restoring large cavities, including Class I and Class II cavities.

Provided herein are high performance dental restoration compositions, particularly two-part compositions having good self-cure times. Also provided herein are methods for restoring or filling a cavity in a tooth in an individual with the two-part dental restoration compositions. In particular, compositions provided herein are useful in restoring large cavities, including Class I and Class II cavities.

A dental self-adhesive resin cement is provided comprising a two-component system. A first catalyst component includes one or more acidic monomers. A second base component includes one or more basic fillers. The mixture of the first and second components is polymerizable and has an initial pH that is acidic immediately after mixing and a pH of at least about pH 8 after polymerization.

A dental self-adhesive resin cement is provided comprising a two-component system. A first catalyst component includes one or more acidic monomers. A second base component includes one or more basic fillers. The mixture of the first and second components is polymerizable and has an initial pH that is acidic immediately after mixing and a pH of at least about pH 8 after polymerization.

The invention refers to a method for producing a dental restoration comprising a lithium silicate glass or glass ceramic as well as a dental restoration inself. The invention further refers to a ingot with the same composition having a defined strength.

A dental curable composition which comprises a radically polymerizable monomer component (A), a polymerizing catalyst (B) and an inorganic granular material (C), characterized in that: the radically polymerizable monomer component (A) contains a bifunctional monomer (A-1) represented by the following formula (α),
R.sub.P—SP.sup.1—R.sub.P  (α) where, R.sub.P is a radically polymerizable group represented by CH.sub.2═C(R)—COO— or CH.sub.2═C(R)—CONH—, wherein R is a hydrogen atom or a hydrocarbon group having 1 to 3 carbon atoms, and SP.sup.1 is a hydrocarbon group having 5 to 15 carbon atoms, and the content of the bifunctional monomer (A-1) in the radically polymerizable monomer component (A) is 5 to 40% by mass under a condition that the content of a diluting monomer (A-2) represented by the following formula (β),
R.sub.P—SP.sup.2—R.sub.P  (β) where, R.sub.P is as defined in the above formula (α), and SP.sup.2 is an aliphatic hydrocarbon group different from SP.sup.1, an oxygen-containing aliphatic hydrocarbon group having not less than 2 oxygen atoms, or an oxygen-containing aromatic hydrocarbon group having not less than 3 oxygen atoms,
is zero or not more than 10% by mass.

A dental curable composition which comprises a radically polymerizable monomer component (A), a polymerizing catalyst (B) and an inorganic granular material (C), characterized in that: the radically polymerizable monomer component (A) contains a bifunctional monomer (A-1) represented by the following formula (α),
R.sub.P—SP.sup.1—R.sub.P  (α) where, R.sub.P is a radically polymerizable group represented by CH.sub.2═C(R)—COO— or CH.sub.2═C(R)—CONH—, wherein R is a hydrogen atom or a hydrocarbon group having 1 to 3 carbon atoms, and SP.sup.1 is a hydrocarbon group having 5 to 15 carbon atoms, and the content of the bifunctional monomer (A-1) in the radically polymerizable monomer component (A) is 5 to 40% by mass under a condition that the content of a diluting monomer (A-2) represented by the following formula (β),
R.sub.P—SP.sup.2—R.sub.P  (β) where, R.sub.P is as defined in the above formula (α), and SP.sup.2 is an aliphatic hydrocarbon group different from SP.sup.1, an oxygen-containing aliphatic hydrocarbon group having not less than 2 oxygen atoms, or an oxygen-containing aromatic hydrocarbon group having not less than 3 oxygen atoms,
is zero or not more than 10% by mass.

An object of the present disclosure is to provide a dental composition that can exhibit sufficient curability even in a state where moisture is excessive as in the oral environment. The dental composition of the present disclosure contains component (a): monomer containing (meth)acrylamide group represented by formula (1): ##STR00001##
(In formula, R represents a hydrogen atom or a methyl group and Rs may be the same or different from each other. R2 is an alkyl group having 2 to 6 carbon atoms and R2s may be the same or different from each other.)

An object of the present disclosure is to provide a dental composition that can exhibit sufficient curability even in a state where moisture is excessive as in the oral environment. The dental composition of the present disclosure contains component (a): monomer containing (meth)acrylamide group represented by formula (1): ##STR00001##
(In formula, R represents a hydrogen atom or a methyl group and Rs may be the same or different from each other. R2 is an alkyl group having 2 to 6 carbon atoms and R2s may be the same or different from each other.)