Patent classifications
G03G5/0696
Electrophotographic photosensitive member, electrophotographic apparatus, and process cartridge
Provided is an electrophotographic photosensitive member that is improved in potential stability in long-term use under a high-temperature and high-humidity environment, and does not cause degradation in image quality, such as a low density. The electrophotographic photosensitive member includes: a support; an undercoat layer formed on the support; a charge-generating layer formed directly on the undercoat layer; and a charge-transporting layer formed on the charge-generating layer. The undercoat layer contains a polyamide resin, titanium oxide particles surface-treated with an organic silicon compound, and a compound represented by the following Formula (1), and has a content of the compound represented by the Formula (1) of 4 ppm or more and 80 ppm or less: ##STR00001##
in the Formula (1), R and R each independently represent a methyl group or an ethyl group.
Electrophotographic photosensitive member
An electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer. The photosensitive layer is a single-layer photosensitive layer and contains a charge generating material, a hole transport material, an electron transport material, and a binder resin. A hole mobility .sub.h is at least 1.0010.sup.7 cm.sup.2/V/second and an electron mobility .sub.e is at least 4.0010.sup.8 cm.sup.2/V/second in the photosensitive layer as measured under conditions of a temperature of 23 C. and an electric field intensity of 1.5010.sup.5 V/cm. A ratio (.sub.h/.sub.e) of the hole mobility .sub.h to the electron mobility .sub.e is at least 1.0 and no greater than 50.0.
Polyarylate resin and electrophotographic photosensitive member
An electrophotographic photosensitive member includes a photosensitive layer. The photosensitive layer contains a charge generating material, a hole transport material, and a binder resin. The binder resin contains a polyarylate resin represented by general formula (1). In general formula (1), r and s each represent an integer of at least 0 and no greater than 49 and t and u represents an integer of at least 1 and no greater than 50. Furthermore, r+s+t+u=100 and r+t=s+u. X and Y each represent, independently of one another, a divalent group represented by chemical formula (1-1), (1-2), (1-3), or (1-4). ##STR00001##
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE AND ELECTROPHOTOGRAPHIC APPARATUS
The present disclosure provides an electrophotographic photosensitive member that suppresses electric potential fluctuations in repeated use. The electrophotographic photosensitive member includes a support, a photosensitive layer and a protective layer, in this order, wherein the photosensitive layer includes a compound having a structure represented by formula (1), and the protective layer includes a resin having a structure represented by formula (2) and a structure represented by formula (3).
ELECTROPHOTOGRAPHIC PHOTORECEPTOR, PROCESS CARTRIDGE, AND ELECTROPHOTOGRAPHIC APPARATUS
An electrophotographic photoreceptor includes a support, an undercoat layer placed on the support, a charge generation layer placed on the undercoat layer, and a charge transport layer placed on the charge generation layer. The undercoat layer contains titanium oxide particles surface-treated with an organosilicon compound that is at least one member selected from the group consisting of compounds represented by formulas (1) to (8) and a polyamide resin. The charge generation layer contains hydroxygallium phthalocyanine.
Electrophotographic photoreceptor, method for manufacturing same, and electrophotographic apparatus using same
An electrophotographic photoreceptor of a negatively-chargeable laminate-type includes a conductive substrate; a charge generation layer provided on the conductive substrate and including a charge generating material; and a charge transport layer provided on the charge generation layer and containing, as a binder resin, a copolymerized polycarbonate resin having a repeating unit represented by Formula (1); as a hole transporting substance, a compound having a structure represented by Formula (2); as an electron transporting substance, a compound having a structure represented by Formula (3), and, as an antioxidant, a compound represented by Structural Formula (4), where a mass ratio H/(B+H) represents a ratio of mass (H) of the hole transporting substance with respect to a sum of mass (B) of the binder resin and the mass (H) of the hole transporting substance, and satisfies Formula (5), 0.20 by massH/(B+H)0.35 by mass, ##STR00001##
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS
An electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer. The photosensitive layer is a single layer. The photosensitive layer contains a charge generating material, a hole transport material, an electron transport material, and a binder resin. The hole transport material includes a compound represented by chemical formula (1-1) or (1-2). The photosensitive layer further contains an n-type pigment. The n-type pigment is preferably an azo pigment or a perylene pigment.
##STR00001##
ELECTROPHOTOGRAPHIC PHOTORECEPTOR, METHOD FOR MANUFACTURING SAME, AND ELECTROPHOTOGRAPHIC DEVICE
An electrophotographic photoreceptor, including a photosensitive layer formed on an electroconductive substrate. The photosensitive layer includes a charge-generating material and an electron-transporting material, and the electron-transporting material includes first and second electron-transporting materials. A difference in lowest unoccupied molecular orbital (LUMO) energy between the first electron-transporting material and the charge-generating material is in a range from 1.0 to 1.5 eV, and a difference in LUMO energy between the second electron-transporting material and the charge-generating material is in a range from 0.6 to 0.9 eV. A ratio of mass of the second electron-transporting material to a total of mass of the first electron-transporting material and the mass of the second electron-transporting material is in a range from 3 to 40%.
Image forming apparatus and image forming method
An image forming apparatus includes an image bearing member and a static elimination device. The static elimination device irradiates static elimination light onto a circumferential surface of the image bearing member. The image bearing member includes a conductive substrate and a single-layer photosensitive layer. The photosensitive layer contains a charge generating material, a hole transport material, an electron transport material, and a binder resin. The static elimination light has a wavelength of at least 600 nm and no greater than 800 nm. The photosensitive layer has an optical absorption coefficient of at least 600 cm.sup.1 and no greater than 1,500 cm.sup.1 with respect to light having a wavelength of 660 nm.
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS
An electrophotographic photosensitive member (1) includes a conductive substrate (2) and a photosensitive layer (3). The photosensitive layer (3) is a single-layer photosensitive layer. The photosensitive layer (3) contains at least a charge generating material, a hole transport material, an electron transport material, and a binder resin. The charge generating material includes a metal-free phthalocyanine. The hole transport material includes a triphenylamine derivative represented by general formula (1) shown below. The electron transport material includes a quinone derivative represented by general formula (2) shown below. In general formula (1), R.sup.1 R.sup.2, R.sup.3, m1, m2, k, p, and q are the same as those described in the description. In general formula (2), R.sup.4, R.sup.5, and R.sup.6 are the same as those described in the description.
##STR00001##