The electrophotographic photosensitive member includes a support and a photosensitive layer on the support, in which a surface layer of the electrophotographic photosensitive member contains a particle, the surface layer has a particle partially exposed from the surface layer among the particle contained in the surface layer, the particle has a volume average particle diameter of 50.0 nm or more and 350.0 nm or less; in a cross-section of the surface layer, the number of the particle partially exposed from the surface layer is 80% by number or more based on a total number of the particle contained in the surface layer; and a total volume of an exposed portion of the particle partially exposed from the surface layer is 30% by volume or more and 80% by volume or less based on an entire volume of the particle contained in the surface layer.

A method of forming an overcoat layer. The method comprises providing a substrate having an imaging structure formed thereon, the imaging structure comprising (i) a charge transport layer and a charge generating layer, or (ii) an imaging layer comprising both charge generating material and charge transport material. An overcoat composition is deposited on the imaging structure, the overcoat composition comprising a charge transport molecule, a fluorinated building block, a leveling agent, a liquid carrier and optionally a first catalyst. The fluorinated building block is a fluorinated alkyl monomer substituted at the and positions with a hydroxyl, carboxyl, carbonyl or aldehyde functional group or the anhydrides of any of those functional groups. The overcoat composition is cured to form an overcoat layer that is a fluorinated structured organic film, the curing comprising treating an outer surface of the overcoat composition with at least one cross-linking process. The crosslinking process forms a cross-linking gradient in the overcoat layer. If the overcoat composition comprises the first catalyst, there is an insufficient amount of the first catalyst to fully cross-link the overcoat layer.

An electrophotographic photoreceptor includes a conductive support, a photosensitive layer on the conductive support, and a protective layer on the photosensitive layer. The protective layer includes a binder resin, metal oxide particles, and fluororesin particles. The metal oxide particles include, on a surface thereof, a first surface-treating agent including fluorine atoms, and a second surface-treating agent including a polymerizable reactive group and a hydrophobic group. At least some of the metal oxide particles are supported on a surface of the fluororesin particles. The fluororesin particles are fixed to the binder resin via the at least some of the metal oxide particles supported on the surface of the fluororesin particles.

A method of forming an overcoat layer. The method comprises providing a substrate having an imaging structure formed thereon, the imaging structure comprising (i) a charge transport layer and a charge generating layer, or (ii) an imaging layer comprising both charge generating material and charge transport material. An overcoat composition is deposited on the imaging structure, the overcoat composition comprising a charge transport molecule, a fluorinated building block, a leveling agent, a liquid carrier and optionally a first catalyst. The fluorinated building block is a fluorinated alkyl monomer substituted at the and positions with a hydroxyl, carboxyl, carbonyl or aldehyde functional group or the anhydrides of any of those functional groups. The overcoat composition is cured to form an overcoat layer that is a fluorinated structured organic film, the curing comprising treating an outer surface of the overcoat composition with at least one cross-linking process. The crosslinking process forms a cross-linking gradient in the overcoat layer. If the overcoat composition comprises the first catalyst, there is an insufficient amount of the first catalyst to fully cross-link the overcoat layer.