Antimicrobial compositions and methods for depositing or coating the antimicrobial or antibacterial compositions on a substrate to prevent microbial adhesion are provided. The antimicrobial composition may include a cationic polymer having a poly-allylamine backbone. A portion of the poly-allylamine backbone may be functionalized with at least one of a guanidine functional group and a biguanide functional group.

The invention provides a cosmetic base having an unprecedented appearance and feeling on use, in particular a cosmetic base with a novel feeling on use that gives a fresh feeling and a unique feel as the cosmetic softly bursts and collapses, allowing water to flow out, when applied to the skin, and a skin cosmetic using the same. A cosmetic base includes (A) 0.15-0.6 mass % of sodium acrylate-grafted starch and (B) 0.25-1.35 mass % of an associative thickener having a polyoxyalkylene chain wherein the total amount of the (A) sodium acrylate-grafted starch and (B) associative thickener having a polyoxyalkylene chain compounded is 0.5-1.5 mass % and to a skin cosmetic that uses the cosmetic base.

The invention provides a cosmetic base having an unprecedented appearance and feeling on use, in particular a cosmetic base with a novel feeling on use that gives a fresh feeling and a unique feel as the cosmetic softly bursts and collapses, allowing water to flow out, when applied to the skin, and a skin cosmetic using the same. A cosmetic base includes (A) 0.15-0.6 mass % of sodium acrylate-grafted starch and (B) 0.25-1.35 mass % of an associative thickener having a polyoxyalkylene chain wherein the total amount of the (A) sodium acrylate-grafted starch and (B) associative thickener having a polyoxyalkylene chain compounded is 0.5-1.5 mass % and to a skin cosmetic that uses the cosmetic base.

Disclosed is a modified biopolymer having the formula A-XY wherein: (a) A is a starting material selected from the group consisting of a polysaccharide, a protein and a cellulose; (b) X is a first moiety bearing a functionality co-reactive with A; (c) Y is a second moiety covalently bound to X, capable of undergoing free radical polymerization and bearing at least two ethylenically unsaturated functional groups; (d) the starting material A and the first moiety X are linked covalently through linkages selected from the group consisting of an ester, an amide, a urethane, a urea, a sulfonate ester, a phosphate ester and an ether; and (e) a degree of substitution of the starting material A with the first moiety X is less than 0.5 but more than 0.1. Compositions including the modified biopolymer and methods for making them are also disclosed.

Disclosed is a modified biopolymer having the formula A-XY wherein: (a) A is a starting material selected from the group consisting of a polysaccharide, a protein and a cellulose; (b) X is a first moiety bearing a functionality co-reactive with A; (c) Y is a second moiety covalently bound to X, capable of undergoing free radical polymerization and bearing at least two ethylenically unsaturated functional groups; (d) the starting material A and the first moiety X are linked covalently through linkages selected from the group consisting of an ester, an amide, a urethane, a urea, a sulfonate ester, a phosphate ester and an ether; and (e) a degree of substitution of the starting material A with the first moiety X is less than 0.5 but more than 0.1. Compositions including the modified biopolymer and methods for making them are also disclosed.

An elastomer has the general structure of: ##STR00001##
where: subscript a is 50-500, b is 1-10, c is 2-30, R.sup.1 has the structure:
—CH.sub.2(CH.sub.2).sub.nO(CH.sub.2).sub.pCH(OH)(CH.sub.2).sub.qNR.sup.2R.sup.2′ where n, p and q are each independently 1-5 and R.sup.2 and R.sup.2′ are independently selected from alkyl and hydroxyalkyl groups having 1-5 carbon atoms; where X is a crosslinker remnant bound to a siloxane unit corresponding to subscript c of a siloxane backbone polymer in addition to the one shown so that the crosslinker remnant in each occurrence is a reaction product with two siloxane backbone polymers, wherein the crosslinker is selected from a group consisting of primary organic dienes, divinyl siloxane and polyoxyalkylenes wherein at least two X components correspond to crosslinker remnants connecting the same two siloxane backbone polymers.

An elastomer has the general structure of: ##STR00001##
where: subscript a is 50-500, b is 1-10, c is 2-30, R.sup.1 has the structure:
—CH.sub.2(CH.sub.2).sub.nO(CH.sub.2).sub.pCH(OH)(CH.sub.2).sub.qNR.sup.2R.sup.2′ where n, p and q are each independently 1-5 and R.sup.2 and R.sup.2′ are independently selected from alkyl and hydroxyalkyl groups having 1-5 carbon atoms; where X is a crosslinker remnant bound to a siloxane unit corresponding to subscript c of a siloxane backbone polymer in addition to the one shown so that the crosslinker remnant in each occurrence is a reaction product with two siloxane backbone polymers, wherein the crosslinker is selected from a group consisting of primary organic dienes, divinyl siloxane and polyoxyalkylenes wherein at least two X components correspond to crosslinker remnants connecting the same two siloxane backbone polymers.

A water-in-oil emulsion composition comprising (a) water, (b) at least one oil, (c) at least one surfactant, (d) at least one water-soluble vinyl polymer, and (e) at least one organosiloxane film-former that is selected from a silicone resin and a random acrylic/silicone graft copolymer is provided. The composition may be a composition for eyelashes, for example a mascara composition further including at least one colorant.

A water-in-oil emulsion composition comprising (a) water, (b) at least one oil, (c) at least one surfactant, (d) at least one water-soluble vinyl polymer, and (e) at least one organosiloxane film-former that is selected from a silicone resin and a random acrylic/silicone graft copolymer is provided. The composition may be a composition for eyelashes, for example a mascara composition further including at least one colorant.

The invention relates to a cosmetic process for caring for the skin, more particularly facial skin, in particular wrinkled skin, comprising the topical application to the skin of a cosmetic composition comprising a grafted polysaccharide polymer (I) and exposure of the treated skin to light radiation, polymer (I) being of formula:

PS—(CO—NH-L-X).sub.a(COOH)b

in which PS denotes the basic backbone of the polysaccharide bearing the carboxylic acid groups;
L is a divalent hydrocarbon-based group containing from 1 to 20 carbon atoms;
X denotes a photoactive group of azide or diazirine type;
a denotes the content of COOH groups substituted with the group —NH-L-X;
b denotes the content of unsubstituted free COOH groups;
a being between 0.01 and 0.8; b being between 0.2 and 0.99;
a+b=1

The invention also relates to the polymers (I) bearing a photoactive group X of diazirine type and to a composition comprising such a polymer in a physiologically acceptable medium.