According to one aspect of the present invention, an organic fluorine compound is represented by a general formula
(R-π-E-CH.sub.2).sub.2-A  (1A)
(where A is a divalent perfluoropolyether group, π is an arylene group or a single bond, R is an alkenyl group or an alkynyl group, and E is an ether bond or an ester bond or a group that is represented by a chemical formula
—O—CH.sub.2CH(OH)CH.sub.2O—
two groups each of which is represented by a general formula
R-π-E-CH.sub.2—
may be the same or different, and at least one n among two π is an arylene group).

Provided are a lubricant that is highly resistant to contamination and highly thermally stable, a lubricant that is highly durable and highly heat resistant, and a magnetic disk. A fluoropolyether compound contains perfluoropolyether groups, end groups each containing at least one hydroxyl group, and a linking group that is comprised of a C.sub.4-C.sub.14 hydrocarbon group and that contains at least one hydroxyl group.

Provided is a lubricant solution capable of being applied to a magnetic disk without use of a fluorine solvent. A lubricant solution in accordance with an aspect of the present invention includes: water; and a perfluoropolyether compound that satisfies Expression (I) below:

N.sub.OH/(Mn/1500)≥2  (1), where N.sub.OH represents the number of hydroxyl groups per molecule of the perfluoropolyether compound and Mn represents a number average molecular weight of the perfluoropolyether compound.

A lubricant including a plurality of segments including a divalent center segment and two sidechain segments, each including a perfluoroalkyl ether moieties is provided in which a dewetting thickness of the lubricant may be determined based in-part on a segment weight average molecular weight of the segments. A magnetic recording medium and a magnetic data storage system including the lubricant are also provided.

A lubricant including a plurality of segments including a divalent center segment and two sidechain segments, each including a perfluoroalkyl ether moieties is provided in which a dewetting thickness of the lubricant may be determined based in-part on a segment weight average molecular weight of the segments. A magnetic recording medium and a magnetic data storage system including the lubricant are also provided.

High temperature lubricants for magnetic media are provided. One such lubricant includes fluoroalkyl, fluoroalkenyl, perfluoroalkyl, or perfluoroalkyl ether segments, anchoring functional groups engageable with a protective overcoat of a magnetic recording media, and cyclic functional groups. The lubricants can be used in conjunction with a magnetic recording medium and/or a magnetic data storage system.

Low-profile thermally stable lubricants for data storage devices are provided based on multi-dentate molecular designs. One such lubricant comprises perfluoroalkyl ether segments, a divalent linking segment, and anchoring functional groups attachable to, or engageable with, a protective overcoat of a magnetic recording medium. The lubricants can be used in conjunction with a magnetic recording medium and/or a magnetic data storage system.

A fluorine-containing ether compound represented by a formula (1) shown below.
R.sup.4—CH.sub.2—R.sup.3—CH.sub.2—R.sup.2—CH.sub.2—R.sup.1—CH.sub.2—R.sup.2—CH.sub.2—R.sup.3—CH.sub.2—R.sup.5  (1) In formula (1), R.sup.1 and R.sup.3 represent the same or different perfluoropolyether chains, R.sup.2 represents a linking group containing at least one polar group, one or both of R.sup.4 and R.sup.5 represent a terminal group containing two or more polar groups, and R.sup.4 and R.sup.5 are different.

The present invention relates to a fluorine-containing ether compound represented by Formula (1),
R.sup.1—R.sup.2—CH.sub.2—R.sup.3—CH.sub.2—R.sup.4  (1).
(In Formula (1), R.sup.1 is an end group including an organic group having at least one double bond or triple bond, R.sup.2 is a divalent linking group bonded to R.sup.1 by etheric oxygen, R.sup.3 is a perfluoropolyether chain, R.sup.4 is an end group having two or three polar groups with each polar group being bonded to different carbon atoms, and the carbon atoms, to which the polar groups are bonded, being bonded to each other via a linking group including carbon atoms to which the polar groups are not bonded.)

Fluoropolyether compounds that can be used as a lubricant, such as for magnetic recording media. The compounds have a terminal group that includes a phenol or benzene. The fluoropolyether compounds reduce the head to media distance while keeping comparable reliability in a hard disk drive compared to current industrial widely used fluoropolyether based lubricants.