An electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer having a single-layer structure. The photosensitive layer contains a charge generating material, an electron transport material, a polycarbonate resin, and a hole transport material. The electron transport material includes a compound having a halogen atom and represented by general formula (1), (2), (3), (4), or (5). The hole transport material includes a compound represented by general formula (20), (21), (22), (23), (24), (25), (26), or (27). A charge of calcium carbonate as measured by charging the calcium carbonate through friction with the photosensitive layer is at least +6.5 C/g. A Vickers hardness of the photosensitive layer at 45 C. is at least 17.0 HV.

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The present invention relates to an electrophotographic photosensitive member in which a surface layer contains a polymer of a hole transport material having a polymerizable functional group, and the hole transport material has a specific fluorene structure.

An improved organic photoconductor drum used in an electrophotographic image forming device and method to make the same is provided. The organic photoconductor drum contains a protective overcoat. The protective overcoat is prepared from a curable composition including a charge transport molecule containing four radical polymerizable hydrophilic functional groups containing an oxygen atom of the general structure shown below:

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where R.sub.1 and R.sub.2 contain a spacer group and a radical polymerizable hydrophilic functional group containing an oxygen atom, R.sub.3 and R.sub.4 are a non-radical polymerizable functional group, and R.sub.5 and R.sub.6 contain a spacer group and a radical polymerizable hydrophilic functional group containing an oxygen atom. The curable composition may also contain at least one curing agent. This organic photoconductor drum has excellent wear resistance without negatively altering the electrophotographic properties, thus protecting the organic photoconductor drum from damage and extending its service life.

An electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer having a single-layer structure. The photosensitive layer contains a charge generating material, an electron transport material, and a binder resin. The electron transport material includes a compound having a halogen atom and represented by a general formula (1), (2), (3), (4), or (5). The binder resin includes a polyarylate resin. The polyarylate resin includes at least one type of repeating unit each represented by general formula (11), at least one type of repeating unit each represented by general formula (12), and a terminal group represented by general formula (13). In general formula (13), R.sup.f represents a chain aliphatic group substituted by at least one fluoro group. A charge of calcium carbonate charged by friction between the photosensitive layer and the calcium carbonate is at least +8.0 C/g.

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An electrophotographic photoreceptor includes a conductive substrate and a photosensitive layer disposed on the conductive substrate which serves as an outermost surface of the electrophotographic photoreceptor. The electrophotographic photoreceptor satisfies YCYA0.1 MPa, YCYB0.1 MPa, and YC4.5 MPa, where YA, YB, and YC (MPa) represent the Young's moduli of a surface of the photosensitive layer determined by nanoindentation at an indentation depth of 500 nm at end portions A and B extending from a position 10 mm to a position 70 mm from the respective edges of the photosensitive layer toward the center of the photosensitive layer in an axial direction of the electrophotographic photoreceptor and a central portion C extending from a position 20 mm in front of and to a position 20 mm behind the center of the photosensitive layer in the axial direction of the electrophotographic photoreceptor, respectively.

A positively chargeable single-layer electrophotographic photosensitive member is used as an image bearing member in an image forming apparatus including a charging section configured to be in contact with the image bearing member to apply a voltage thereto. The positively chargeable single-layer electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer. The photosensitive layer contains at least a charge generating material, a hole transport material, an electron transport material, and a binder resin. The hole transport material contains a triarylamine derivative represented by the following general formula (I). In general formula (I), R.sub.1, R.sub.2, m and n have the same meaning as R.sub.1, R.sub.2, m, and n defined in the description. ##STR00001##

A single-layer electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer. The conductive substrate contains aluminum or an aluminum alloy. A surface of the conductive substrate has an aluminum oxide film or an aluminum alloy oxide film. The photosensitive layer is disposed directly on the conductive substrate. The photosensitive layer contains an electron transport material. The electron transport material has a reduction potential of at least 0.88 V and no greater than 0.66 V versus a reference electrode (Ag/Ag.sup.+). The single-layer electrophotographic photosensitive member has a leakage onset voltage of at least 5.0 kV in a high temperature and humidity environment at a temperature of 30 C. and a relative humidity of 80%. The leakage onset voltage is a voltage applied to the single-layer electrophotographic photosensitive member at which current leakage starts.

An electrophotographic photoreceptor includes a conductive substrate and a single-layer-type photosensitive layer on the conductive substrate. The single-layer-type photosensitive layer contains a binder resin, a charge generating material, an electron transporting material, and a hole transporting material. The product of a volume resistivity (G.Math.m) of the single-layer-type photosensitive layer and an elastic modulus (GPa) of the single-layer-type photosensitive layer is about 90 or more.

An electrophotographic photoreceptor includes a conductive substrate and a photosensitive layer disposed on the conductive substrate which serves as an outermost surface of the electrophotographic photoreceptor. The electrophotographic photoreceptor satisfies YCYA0.1 MPa, YCYB0.1 MPa, and YC4.5 MPa, where YA, YB, and YC (MPa) represent the Young's moduli of a surface of the photosensitive layer determined by nanoindentation at an indentation depth of 500 nm at end portions A and B extending from a position 10 mm to a position 70 mm from the respective edges of the photosensitive layer toward the center of the photosensitive layer in an axial direction of the electrophotographic photoreceptor and a central portion C extending from a position 20 mm in front of and to a position 20 mm behind the center of the photosensitive layer in the axial direction of the electrophotographic photoreceptor, respectively.

An electrophotographic photoreceptor includes a conductive substrate and a single-layer-type photosensitive layer on the conductive substrate. The single-layer-type photosensitive layer contains a binder resin, a charge generating material, an electron transporting material, and two hole transporting materials having different redox potentials. The two hole transporting materials are a hole transporting material A and a hole transporting material B that has a redox potential lower than that of the hole transporting material A. The ratio A/B of a weight of the hole transporting material A to a weight of the hole transporting material B is about 12/1 or more and about 36/1 or less.