Patent classifications
G03G5/0668
Photosensitive body for electrophotography, method for producing same and electrophotographic apparatus
An electrophotographic photoreceptor includes a conductive substrate; and a photosensitive layer arranged on the conductive substrate and containing, as a charge generating material, any one material selected from the group consisting of titanyl phthalocyanines, metal-free phthalocyanines, chlorogallium phthalocyanines and hydroxygallium phthalocyanines; and, as an electron transporting material, a naphthalene tetracarboxylic acid diimide compound represented by Formula (1) below, where R.sup.1 and R.sup.2 each represent a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, an alkylene group, an alkoxy group, an alkyl ester group, a phenyl group optionally having a substituent, a naphthyl group optionally having a substituent, or a halogen element; and R.sup.1 and R.sup.2 are optionally the same or different: ##STR00001##
The photoreceptor realizes a stable print density even in a low-temperature environment by suppressing a reduction in print density that is caused by potential fluctuation of the photoreceptor in the low-temperature environment.
Electrophotographic photosensitive member, process cartridge, and image forming apparatus
An electrophotographic photosensitive member (1) includes a conductive substrate (2) and a photosensitive layer (3). The photosensitive layer (3) is a single-layer photosensitive layer. The photosensitive layer (3) contains at least a charge generating material, a hole transport material, an electron transport material, and a binder resin. The charge generating material includes a metal-free phthalocyanine. The hole transport material includes a triphenylamine derivative represented by general formula (1) shown below. The electron transport material includes a quinone derivative represented by general formula (2) shown below. In general formula (1), R.sup.1, R.sup.2, R.sup.3, m1, m2, k, p, and q are the same as those described in the description. In general formula (2), R.sup.4, R.sup.5, and R.sup.6 are the same as those described in the description. ##STR00001##
Electrophotographic photosensitive member, process cartridge, and image forming apparatus
A photosensitive member (1) includes a conductive substrate (2) and a photosensitive layer (3). The photosensitive layer is a single-layer photosensitive layer (3c). The photosensitive layer contains a charge generating material, a hole transport material, an electron transport material, and a binder resin. The hole transport material includes a triphenylamine derivative represented by general formula (HT). The electron transport material includes a compound represented by general formula (ET1), (ET2), (ET3), (ET4), or (ET5). The binder resin includes a polyarylate resin represented by general formula (1) ##STR00001## ##STR00002##
Polyarylate resin and electrophotographic photosensitive member
An electrophotographic photosensitive member includes a photosensitive layer. The photosensitive layer contains a charge generating material, a hole transport material, and a binder resin. The binder resin contains a polyarylate resin represented by general formula (1). In general formula (1), r and s each represent an integer of at least 0 and no greater than 49 and t and u represents an integer of at least 1 and no greater than 50. Furthermore, r+s+t+u=100 and r+t=s+u. X and Y each represent, independently of one another, a divalent group represented by chemical formula (1-1), (1-2), (1-3), or (1-4). ##STR00001##
Production method for electrophotographic photosensitive member
A method for producing an electrophotographic photosensitive member includes an electrically conductive substrate and a photosensitive layer. The method includes applying an application liquid for photosensitive layer formation containing a solvent, a binder resin, and a hole transport material directly or indirectly onto the electrically conductive substrate, and removing a portion of the solvent, to form the photosensitive layer. The solvent contains a first solvent that is an alcohol having a carbon number of at least 1 and no greater than 3, and a second solvent other than the first solvent. The binder resin includes a polyarylate resin that is a polymerization product of monomers including a first monomer represented by general formula (1) and a second monomer represented by general formula (2), ##STR00001##
ELECTROPHOTOGRAPHIC PHOTOCONDUCTOR, IMAGE FORMING APPARATUS, AND PROCESS CARTRIDGE
An electrophotographic photoconductor is provided that includes a conductive substrate, an undercoat layer overlying the conductive substrate, and a photosensitive layer overlying the undercoat layer. The undercoat layer contains zinc oxide particles and a binder resin and has a volume resistivity of 0.0310.sup.6 .Math.cm or less in an electrical field of 5 V/m at a temperature of 23 degrees C. and a relative humidity of 55%. The photosensitive layer contains a compound represented by the following general formula (1):
##STR00001##
where each of R.sub.1 to R.sub.3 independently represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms which may have a substituent, or a substituted or unsubstituted aryl group having 6 to 12 carbon atoms.
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS
A photosensitive layer included in an electrophotographic photosensitive member contains at least a charge generating material, a hole transport material, and a binder resin. The hole transport material includes a compound (1). The binder resin includes a polyarylate resin having at least one repeating unit (10) and at least one repeating unit (11). Alternatively, the binder resin includes a polycarbonate resin having a repeating unit (20) and a repeating unit (21). The general formulas (1), (10), (11), (20), and (21) are as follows
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ELECTROPHOTOGRAPHIC PHOTORECEPTOR, METHOD FOR MANUFACTURING SAME, AND ELECTROPHOTOGRAPHIC DEVICE
An electrophotographic photoreceptor, including a photosensitive layer formed on an electroconductive substrate. The photosensitive layer includes a charge-generating material and an electron-transporting material, and the electron-transporting material includes first and second electron-transporting materials. A difference in lowest unoccupied molecular orbital (LUMO) energy between the first electron-transporting material and the charge-generating material is in a range from 1.0 to 1.5 eV, and a difference in LUMO energy between the second electron-transporting material and the charge-generating material is in a range from 0.6 to 0.9 eV. A ratio of mass of the second electron-transporting material to a total of mass of the first electron-transporting material and the mass of the second electron-transporting material is in a range from 3 to 40%.
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS
An electrophotographic photosensitive member (1) includes a conductive substrate (2) and a photosensitive layer (3). The photosensitive layer (3) is a single-layer photosensitive layer. The photosensitive layer (3) contains at least a charge generating material, a hole transport material, an electron transport material, and a binder resin. The charge generating material includes a metal-free phthalocyanine. The hole transport material includes a triphenylamine derivative represented by general formula (1) shown below. The electron transport material includes a quinone derivative represented by general formula (2) shown below. In general formula (1), R.sup.1 R.sup.2, R.sup.3, m1, m2, k, p, and q are the same as those described in the description. In general formula (2), R.sup.4, R.sup.5, and R.sup.6 are the same as those described in the description.
##STR00001##
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS
A single-layer photosensitive layer of an electrophotographic photosensitive member contains a charge generating material, a hole transport material, an electron transport material, and a binder resin. The charge generating material is a phthalocyanine pigment. A content percentage of the phthalocyanine pigment relative to the mass of the photosensitive layer is at least 0.70% by mass and no greater than 1.40% by mass. A film thickness of the photosensitive layer is at least 25 m and no greater than 32 m. A charge amount difference Q is no greater than 6.50 C.