The electrophotographic photosensitive member includes an undercoat layer and a surface layer on or above a support in this order, in which the undercoat layer contains metal oxide particles and a specific binder resin, the surface layer contains a charge transporting substance, fluororesin particles, and a specific binder resin, an arithmetic average roughness Ra of a surface of the undercoat layer is 0.15 m or less, a refractive index (a) of the metal oxide particles and a refractive index (b) of the binder resin contained in the undercoat layer satisfy a specific relationship, and a refractive index (c) of the binder resin contained in the surface layer and a refractive index (d) of the fluororesin particles satisfy a specific relationship.

An image forming apparatus includes a photoreceptor photoreceptor having an outermost surface layer that contains polytetrafluoroethylene particles and a dispersant containing fluorine atoms and has a perfluorooctanoic acid content of 25 ppb or less relative to the polytetrafluoroethylene particles; and a transfer device that includes an intermediate transfer body having a surface onto which a toner image is transferred, a first transfer device that performs first transfer that involves transferring the toner image on the surface of the photoreceptor onto the surface of the intermediate transfer body, and a second transfer device that performs second transfer that involves transferring the toner image on the surface of the intermediate transfer body onto a surface of a recording medium, the second transfer device having a second transfer member having a surface with a hexadecane contact angle of 30 degrees or more.

An electrophotographic photoreceptor includes a support, a photosensitive layer, and a protection layer. The protection layer contains a copolymer of a compound having a specific frame and a hole-transporting compound containing a specific polarizable functional group.

A fluorine-containing resin particle contains 0 or more and 30 or less carboxyl groups per 10.sup.6 carbon atoms and 0 ppm or more and 3 ppm or less of a basic compound.

An electrophotographic photoreceptor includes a conductive substrate and a photosensitive layer disposed on the conductive substrate. An outermost surface layer of the electrophotographic photoreceptor contains fluorine-containing resin particles and a fluorine-containing graft polymer having a fluorinated alkyl group. In an infrared absorption spectrum of the fluorine-containing graft polymer, a ratio of a peak area in a wavenumber range of from 1,020 cm.sup.1 to 1,308 cm.sup.1 to a peak area in a wavenumber range of from 1,673 cm.sup.1 to 1,779 cm.sup.1 is 2.7 or more and 4.8 or less.

The electrophotographic photosensitive member includes: a support; a charge-generating layer; and a charge-transporting layer, the charge-generating layer and the charge-transporting layer being arranged on the support, wherein a surface layer of the electrophotographic photosensitive member contains: inorganic particles having an average particle diameter (L) of primary particles of 5 nm or more and 50 nm or less; and resin particles having an average particle diameter (L) of primary particles of 0.1 m or more and 5.0 m or less, and wherein in any cross-section of the surface layer, (Sm)/(S)0.3 is satisfied, where a region within (L/2) from a surface of each of the resin particles is defined as a region (M), a sum of cross-sectional areas of the inorganic particles in the any cross-section is represented by (S), and a sum of cross-sectional areas of the inorganic particles that are included in the region (M) is represented by (Sm).

An electrophotographic photoreceptor includes a conductive substrate and a photosensitive layer disposed on the conductive substrate. An outermost surface layer of the electrophotographic photoreceptor contains fluorine-containing resin particles and a fluorine-containing graft polymer having a structural unit represented by general formula (FA), a structural unit represented by general formula (FB), and a structural unit represented by general formula (FC): ##STR00001##
where R.sup.F1, R.sup.F2, R.sup.F3, and R.sup.F4 each independently represent a hydrogen atom or an alkyl group; X.sup.F1 represents an alkylene chain, a halogen-substituted alkylene chain, S, O, NH, or a single bond; Y.sup.F1 represents an alkylene chain, a halogen-substituted alkylene chain, (C.sub.fxH.sub.2fx-1(OH)), or a single bond; Q.sup.F1 represents O or NH; fl, fm, and fn each independently represent an integer of 1 or more; fp, fq, fr, and fs each independently represent an integer of 0 or 1 or more; ft represents an integer of 1 or more and 7 or less; fx represents an integer of 1 or more; R.sup.F5 and R.sup.F6 each independently represent a hydrogen atom or an alkyl group; and fz represents an integer of 1 or more.

The electrophotographic photosensitive member includes an undercoat layer and a surface layer on or above a support in this order, in which the undercoat layer contains metal oxide particles and a specific binder resin, the surface layer contains a charge transporting substance, fluororesin particles, and a specific binder resin, an arithmetic average roughness Ra of a surface of the undercoat layer is 0.15 m or less, a refractive index (a) of the metal oxide particles and a refractive index (b) of the binder resin contained in the undercoat layer satisfy a specific relationship, and a refractive index (c) of the binder resin contained in the surface layer and a refractive index (d) of the fluororesin particles satisfy a specific relationship.

Provided is an electrophotographic photoreceptor, which is excellent in abrasion resistance and scratch resistance, has excellent electrical characteristics, and is capable of inhibiting an image defect, a manufacturing method of an electrophotographic photoreceptor, a process cartridge, and an electrophotographic apparatus. A surface layer of the electrophotographic photoreceptor contains a copolymer of a composition which contains resin particles containing fluorine atoms, a charge transport compound having 2 or more polymerizable functional groups, a compound represented by General Formula (1), and a resin having a structure represented by General Formula (2) and a structure represented by General Formula (3). The polymerizable functional groups t are independently selected from an acryloyloxy group and a methacryloyloxy group, and a content of the compound represented by General Formula (1) in the composition is 0.10% by mass or more.

##STR00001##

A dispersant-attached polytetrafluoroethylene particle includes a polytetrafluoroethylene particle; and a dispersant that contains a fluorine atom and is attached to a surface of the polytetrafluoroethylene particle. The dispersant-attached polytetrafluoroethylene particle has a particle size distribution index [D.sub.50-D.sub.10] of 50 nm or more.