The present disclosure provides an electrophotographic photosensitive member having a surface layer that is excellent in dispersibility of a fluorine atom-containing resin particle and suppresses a potential fluctuation at the time of repeated use. The electrophotographic photosensitive member having the surface layer, wherein the surface layer includes the fluorine atom-containing resin particle, a binder material, and a polymer A having a specific structural unit.

Provided is an electrophotographic photosensitive member including a surface layer, which is excellent in dispersibility of fluorine atom-containing resin particles and is suppressed from causing a ghost image. Specifically, provided is an electrophotographic photosensitive member including a surface layer, wherein the surface layer contains a fluorine atom-containing resin particle, a binder material, and a polymer A having specific structural units.

The present disclosure provides a process cartridge and an electrophotographic apparatus in which fogging is reduced so as to reduce an amount of toner consumed. A process cartridge configured to be detachably attachable to a main body of an electrophotographic apparatus includes a developing unit containing a toner, and an electrophotographic photosensitive member, wherein the toner is a toner that has a toner particle, and has a metal salt of a polyvalent acid at least on a part of a surface of the toner particle; wherein the metal salt of the polyvalent acid includes at least one kind of metal element selected from metal elements belonging to from Group 3 to Group 13, and a surface layer of the electrophotographic photosensitive member contains an acrylic resin or a methacrylic resin.

The present disclosure provides an electrophotographic photosensitive member having a surface layer in which an occurrence of the image deletion is suppressed; a process cartridge equipped with the electrophotographic photosensitive member; and an electrophotographic apparatus provided with the process cartridge. An electrophotographic photosensitive member has a surface layer that includes a copolymerized product of a composition including a metal oxide particle having a polymerizable functional group on a surface thereof and a polymerizable compound having a particular structure.

The process cartridge is a process cartridge to be removably mounted onto a main body of an electrophotographic apparatus, the process cartridge including: an electrophotographic photosensitive member; a toner; and a developing member, wherein the electrophotographic photosensitive member includes a surface layer that is a polymerized film of a composition containing at least one kind of monofunctional (meth)acrylic compound selected from the group consisting of: a monofunctional (meth)acrylic monomer; and a monofunctional (meth)acrylic oligomer, and at least one kind of tri- or higher functional (meth)acrylic compound selected from the group consisting of: a tri- or higher functional (meth)acrylic monomer; and a tri- or higher functional (meth)acrylic oligomer, wherein the toner contains a toner particle and a hydrotalcite particle as an external additive, and wherein the hydrotalcite particle contains fluorine in filter fitting analysis of STEM-EDS analysis.

A process cartridge detachably attachable to a main body of an electrophotographic apparatus, the process cartridge including an electrophotographic photosensitive member, a toner, and a developing member that feeds the toner to the electrophotographic photosensitive member, wherein the electrophotographic photosensitive member includes a surface layer containing a (meth)acrylic resin having a urethane structure, the toner includes a toner particle and a hydrotalcite particle as an external additive, and the hydrotalcite particle contains fluorine in filter fitting analysis in STEM-EDS analysis.

Provided is a process cartridge removably mountable onto a main body of an electrophotographic apparatus, the process cartridge comprising an electrophotographic photosensitive member, a toner, and a developing member configured to supply the toner to the electrophotographic photosensitive member, wherein, in filter fitting analysis in STEM-EDS analysis, a hydrotalcite particle comprises fluorine, and wherein, when a number-average primary particle diameter of a particle A is represented by “m” [nm], a content ratio of the particle A with respect to the surface layer is represented by “p” [vol %], and a number-average primary particle diameter of the hydrotalcite particle is represented by “h” [nm], the “m”, the “p”, and the “h” satisfy the following expressions, respectively:

5≤m≤300  Expression (1);

5≤p≤40  Expression (2); and

60≤h≤1,000  Expression (3).

An electrophotographic image forming apparatus in which streak-like banding to be formed in an electrophotographic photosensitive member is suppressed. The electrophotographic image forming apparatus includes an electrophotographic photosensitive member, which has a protective layer, and a developer carrying member for supplying a developer. The protective layer contains a cured product containing an aromatic ring and an ester group, by attenuated total reflection Fourier transform infrared spectroscopy, when a peak area based on C═C stretching vibration of the aromatic ring is represented by S1, and a peak area based on C═O stretching vibration of the ester group is represented by S2, an area ratio S1/S2 is 0.10 to 0.27, and a rotation speed ratio D1/D2 of a rotation speed D1 of the developer carrying member to a rotation speed D2 of the electrophotographic photosensitive member is 0.80 to 1.20.

An improved overcoat layer for an organic photoconductor drum of an electrophotographic image forming device is provided. The overcoat layer is prepared from a curable composition including a crosslinkable siloxane, an acrylic polymer with pigment affinic groups, nano metal oxide particles sized less than 400 nm in combination with a urethane acrylate resin having at least 6 functional groups. The outermost layer of an organic photoconductors is coated with the overcoat formulation of the present invention then cured. The resulting cured overcoated organic photoconductor has improved wear resistance and importantly does not negatively altering the electrophotographic properties of the organic photoconductor.

An improved overcoat layer for an organic photoconductor drum of an electrophotographic image forming device is provided. The overcoat layer is prepared from a curable composition including a crosslinkable siloxane, an acrylic polymer with pigment affinic groups, nano metal oxide particles sized less than 400 nm in combination with a urethane acrylate resin having at least 6 functional groups. The outermost layer of an organic photoconductors is coated with the overcoat formulation of the present invention then cured. The resulting cured overcoated organic photoconductor has improved wear resistance and importantly does not negatively altering the electrophotographic properties of the organic photoconductor.