Patent classifications
G03G5/0651
Electrophotographic photoreceptor, method for manufacturing same, and electrophotographic device
An electrophotographic photoreceptor, including a photosensitive layer formed on an electroconductive substrate. The photosensitive layer includes a charge-generating material and an electron-transporting material, and the electron-transporting material includes first and second electron-transporting materials. A difference in lowest unoccupied molecular orbital (LUMO) energy between the first electron-transporting material and the charge-generating material is in a range from 1.0 to 1.5 eV, and a difference in LUMO energy between the second electron-transporting material and the charge-generating material is in a range from 0.6 to 0.9 eV. A ratio of mass of the second electron-transporting material to a total of mass of the first electron-transporting material and the mass of the second electron-transporting material is in a range from 3 to 40%.
ELECTROPHOTOGRAPHIC PHOTOCONDUCTOR, METHOD OF MANUFACTURING THE SAME, AND ELECTROPHOTOGRAPHIC DEVICE
Provided are an electrophotographic photoconductor being resistant to abrasion even in long-term use, having highly sensitive electric characteristics, being capable of maintaining a high retention rate, and being capable of providing a stable image without filming, a method of manufacturing the same, and an electrophotographic device. The photoconductor includes an electroconductive substrate (1), a charge generation layer (3), and a charge transport layer (4); the charge transport layer contains a hole transport material, a resin binder, an electron transport material, and an inorganic oxide; the charge generation layer contains a charge generation material; the masses of the hole transport material, the resin binder, the electron transport material, and the inorganic oxide in the charge transport layer respectively denoted by a to d satisfy 1.5≤b/a≤5.7, 0.005≤c/a≤0.35, 0.05≤d/a≤0.70, a≥c+d, and c/d≥0.01; the hole transport material contains a compound expressed by formula (A-1); and the charge generation material contains titanyl phthalocyanine having an exothermic peak at 251±5° C., a half-value width of the exothermic peak equal to or less than 15° C., and a heating value equal to or greater than 1.0 mJ/mg when a temperature rise condition is 20° C./min in differential scanning calorimetry, and having an X-ray diffraction peak at 27.2±0.3°.
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IMAGE FORMING APPARATUS AND IMAGE FORMING METHOD
An image forming apparatus in which no image smearing occurs even under high-temperature and high-humidity conditions while durability and low-temperature fixability are maintained. The image forming apparatus comprises: an electrophotographic photosensitive member comprising a support and a photosensitive layer formed on the support; an image forming unit configured to form an electrostatic image on the electrophotographic photosensitive member; a developing unit comprising a toner and configured to supply the toner to the electrostatic image formed on the electrophotographic photosensitive member for forming a toner image; and a transferring unit configured to transfer the toner image from the electrophotographic photosensitive member, wherein a surface layer of the electrophotographic photosensitive member is a surface layer comprises a binder resin (A), the toner is a toner including toner particles each containing a binder resin (B) and a wax, and the binder resin (A) has a specific structure I.
Electrophotographic photosensitive member, process cartridge, and image forming apparatus
An electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer. The photosensitive layer is a single layer. The photosensitive layer contains a charge generating material, a hole transport material, an electron transport material, and a binder resin. The hole transport material includes a compound represented by chemical formula (1-1) or (1-2). The photosensitive layer further contains an n-type pigment. The n-type pigment is preferably an azo pigment or a perylene pigment. ##STR00001##
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, ELECTROPHOTOGRAPHIC APPARATUS, AND METHOD OF PRODUCING ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER
An electrophotographic photosensitive member that shows stable sensitivity even when repeatedly used. The electrophotographic photosensitive member is an electrophotographic photosensitive member including a support, an undercoat layer, a charge generating layer, and a charge transporting layer in the stated order, wherein the undercoat layer contains two kinds of electron transporting substances.
Photosensitive body for electrophotography, method for producing same and electrophotographic apparatus
An electrophotographic photoreceptor includes a conductive substrate; and a photosensitive layer arranged on the conductive substrate and containing, as a charge generating material, any one material selected from the group consisting of titanyl phthalocyanines, metal-free phthalocyanines, chlorogallium phthalocyanines and hydroxygallium phthalocyanines; and, as an electron transporting material, a naphthalene tetracarboxylic acid diimide compound represented by Formula (1) below, where R.sup.1 and R.sup.2 each represent a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, an alkylene group, an alkoxy group, an alkyl ester group, a phenyl group optionally having a substituent, a naphthyl group optionally having a substituent, or a halogen element; and R.sup.1 and R.sup.2 are optionally the same or different: ##STR00001##
The photoreceptor realizes a stable print density even in a low-temperature environment by suppressing a reduction in print density that is caused by potential fluctuation of the photoreceptor in the low-temperature environment.
Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus
An electrophotographic photosensitive member includes, in sequence, a support, a conductive layer, an undercoat layer, a charge generation layer, and a charge transport layer. The conductive layer is a cured film, and the cured film contains titanium oxide particles doped with niobium. The undercoat layer contains a cured product of a composition that contains an electron transport material having a polymerizable functional group and a resin functionalized with a carboxylic acid derivative.
ELECTROPHOTOGRAPHIC PHOTOCONDUCTOR, METHOD OF MANUFACTURING THE SAME, AND ELECTROPHOTOGRAPHIC DEVICE INCLUDING THE SAME
An electrophotographic photoconductor includes a conductive substrate; and a photosensitive layer provided on the conductive substrate and containing a charge generation material, a hole transport material, a first electron transport material, from 3% by mass to 40% by mass of a second electron transport material, a resin binder, and an inorganic oxide filler surface-treated with a silane coupling agent. In a dipole-dipole force component (a Hansen solubility parameter), the first electron transport material and the silane coupling agent have a difference of SPa<2.50; the second electron transport material and the silane coupling agent have a difference of SPb<2.50; and the first electron transport material and the second electron transport material have a difference of 0.30<SPc<1.00. In a London dispersion force component (a Hansen solubility parameter), the resin binder and the silane coupling agent have a difference of SPd<2.00.
Electrophotographic photosensitive member, process cartridge, and image forming apparatus
A photosensitive member (1) includes a conductive substrate (2) and a photosensitive layer (3). The photosensitive layer is a single-layer photosensitive layer (3c). The photosensitive layer contains a charge generating material, a hole transport material, an electron transport material, and a binder resin. The hole transport material includes a triphenylamine derivative represented by general formula (HT). The electron transport material includes a compound represented by general formula (ET1), (ET2), (ET3), (ET4), or (ET5). The binder resin includes a polyarylate resin represented by general formula (1) ##STR00001## ##STR00002##
Electrophotographic photosensitive member, process cartridge, and image forming apparatus
An electrophotographic photosensitive member (1) includes a conductive substrate (2) and a photosensitive layer (3). The photosensitive layer (3) is a single-layer photosensitive layer (3c) and contains a charge generating material, a hole transport material, an electron transport material, and a binder resin. The binder resin includes a polyarylate resin represented by general formula (1). ##STR00001##
In general formula (1), Q.sup.1, Q.sup.2, Q.sup.3, and Q.sup.4 each represent a methyl group or a hydrogen atom. r, s, t, and u each represent a number greater than or equal to 15 and less than or equal to 35. X and Y each represent a divalent group represented by chemical formula (2A), chemical formula (2B), chemical formula (2C), or chemical formula (2D), and X and Y are different from each other ##STR00002##