Patent classifications
G03G5/0659
Electrophotographic photoreceptor, process cartridge, and image forming apparatus
An electrophotographic photoreceptor includes a conductive substrate, an undercoat layer on the conductive substrate, and a photosensitive layer on the undercoat layer. The undercoat layer contains at least one perinone compound selected from the group consisting of a compound represented by general formula (1) below and a compound represented by general formula (2) below, an amine compound (A) having an ionization potential of 5.4 eV or more and 5.9 eV or less, and a binder resin, ##STR00001##
where: in general formula (1), R.sup.11, R.sup.12, R.sup.13, R.sup.14, R.sup.15, R.sup.16, R.sup.17, and R.sup.18 each independently represent a hydrogen atom, an alkyl group, an alkoxy group, an aralkyl group, an aryl group, an aryloxy group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkoxycarbonylalkyl group, an aryloxycarbonylalkyl group, or a halogen atom; R.sup.11 and R.sup.12 may be bonded to each other to form a ring, so may R.sup.12 and R.sup.13, and so may R.sup.13 and R.sup.14; and R.sup.15 and R.sup.16 may be bonded to each other to form a ring, so may R.sup.16 and R.sup.17, and so may R.sup.17 and R.sup.18, and in general formula (2), R.sup.21, R.sup.22, R.sup.23, R.sup.24, R.sup.25, R.sup.26, R.sup.27, and R.sup.28 each independently represent a hydrogen atom, an alkyl group, an alkoxy group, an aralkyl group, an aryl group, an aryloxy group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkoxycarbonylalkyl group, an aryloxycarbonylalkyl group, or a halogen atom; R.sup.21 and R.sup.22 may be bonded to each other to form a ring, so may R.sup.22 and R.sup.23, and so may R.sup.23 and R.sup.24; and R.sup.25 and R.sup.26 may be bonded to each other to form a ring, so may R.sup.26 and R.sup.27, and so may R.sup.27 and R.sup.28.
ELECTROPHOTOGRAPHIC PHOTORECEPTOR, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS
An electrophotographic photoreceptor includes a conductive substrate, an undercoating layer that is disposed on the conductive substrate, and a photosensitive layer that is disposed on the undercoating layer, in which the undercoating layer contains at least one perinone compound selected from the group consisting of a compound represented by Formula (1) and a compound represented by Formula (2) which are shown below, and polyurethane, contains at least one perinone compound selected from the group consisting of the compounds represented by Formulas (1) and (2), and at least one acceptor compound selected from the group consisting of compounds represented by Formula (3) to (15) which are shown in the specification, or contains a resin obtained by polymerizing a diallyl phthalate compound and a charge transporting material.
##STR00001##
Organoboron compounds and methods of making same
The invention provides organoboron precursors and facile photoirradiation and/or heating methods of making corresponding elimination products. Some elimination products are polycyclic aromatic molecules wherein a number of aromatic CC moieties have been replaced by a BN moiety to form azaborine compounds with interesting properties such as electronic, photophysical, luminescent, as well as chemical properties. Examples of polymer films that were doped with such compounds are shown wherein irradiated portions of the polymer film luminesce. The invention further provides methods of producing photoluminescence and electroluminescence, and uses of the compounds of the invention in luminescent probes, sensors, electroluminescent devices, hydrogen storage materials, optoelectronic materials, and bioactive molecules.
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE AND ELECTROPHOTOGRAPHIC APPARATUS
Provided is an electrophotographic photosensitive member including a support and a photosensitive layer, wherein the photosensitive layer contains two kinds of benzimidazoperylene compounds as electron transporting substances.
ELECTROPHOTOGRAPHIC PHOTORECEPTOR, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS
An electrophotographic photoreceptor includes a conductive substrate, an undercoat layer disposed on the conductive substrate, and a photosensitive layer disposed on the undercoat layer, in which the undercoat layer contains a binder resin and at least one perinone compound selected from the group consisting of a compound represented by Formula (1) and a compound represented by Formula (2), the photosensitive layer contains a polyester resin (1) having at least one dicarboxylic acid unit (A) selected from the group consisting of a dicarboxylic acid unit (A2) represented by Formula (A2), a dicarboxylic acid unit (A3) represented by Formula (A3), and a dicarboxylic acid unit (A4) represented by Formula (A4), and a diol unit (B) represented by Formula (B), and a mass proportion of the polyester resin (1) in the photosensitive layer is 15% by mass or greater,
##STR00001## in Formula (1), R.sup.11, R.sup.12, R.sup.13, R.sup.14, R.sup.15, R.sup.16, R.sup.17, and R.sup.18 each independently represent a hydrogen atom, an alkyl group, an alkoxy group, an aralkyl group, an aryl group, an aryloxy group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkoxycarbonylalkyl group, an aryloxycarbonylalkyl group, or a halogen atom, R.sup.11 and R.sup.12, R.sup.12 and R.sup.13, and R.sup.13 and R.sup.14 may be each independently linked to each other to form a ring, and R.sup.15 and R.sup.16, R.sup.16 and R.sup.17, and R.sup.17 and R.sup.18 may be each independently linked to each other to form a ring, in Formula (2), R.sup.21, R.sup.22, R.sup.23, R.sup.24, R.sup.25, R.sup.26, R.sup.27, and R.sup.28 each independently represent a hydrogen atom, an alkyl group, an alkoxy group, an aralkyl group, an aryl group, an aryloxy group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkoxycarbonylalkyl group, an aryloxycarbonylalkyl group, or a halogen atom, R.sup.21 and R.sup.22, R.sup.22 and R.sup.23, and R.sup.23 and R.sup.24 may be each independently linked to each other to form a ring, and R.sup.25 and R.sup.26, R.sup.26 and R.sup.27, and R.sup.27 and R.sup.28 may be each independently linked to each other to form a ring,
##STR00002## in Formula (A2), n.sup.201 and n.sup.202 each independently represent an integer of 0 or greater and 4 or less, and n.sup.201 pieces of Ra.sup.201's and n.sup.202 pieces of Ra.sup.202's each independently represent an alkyl group having 1 or more and 10 or less carbon atoms, an aryl group having 6 or more and 12 or less carbon atoms, or an alkoxy group having 1 or more and 6 or less carbon atoms, in Formula (A3), n.sup.301 and n.sup.302 each independently represent an integer of 0 or greater and 4 or less, and n.sup.301 pieces
Image forming apparatus
An image forming apparatus includes an electrophotographic photoreceptor that includes a conductive substrate, an undercoat layer provided on the conductive substrate, containing a binder resin and an electron transport material, and satisfying Expression 1-1, and a photosensitive layer provided on the undercoat layer, a charging device that charges a surface of the electrophotographic photoreceptor, an electrostatic latent image forming device that forms an electrostatic latent image on the charged surface of the electrophotographic photoreceptor, a developing device that develops the electrostatic latent image formed on the surface of the electrophotographic photoreceptor with a developer containing a toner to form a toner image, and a transfer device that transfers the toner image to a surface of a recording medium, in which a moving time of an outer peripheral surface of the electrophotographic photoreceptor, required from charging performed by the charging device to development performed by the developing device, is 90 msec or longer, Expression 1-1: 0.20E.sub.F1E.sub.LUMO10.60 (in Expression 1-1, E.sub.F1 represents a Fermi level of the undercoat layer, and E.sub.LUMO1 represents an energy level of LUMO of the undercoat layer).
IMAGE FORMING APPARATUS
An image forming apparatus includes an electrophotographic photoreceptor that includes a conductive substrate, an undercoat layer provided on the conductive substrate, containing a binder resin and an electron transport material, and satisfying Expression 1-1, and a photosensitive layer provided on the undercoat layer, a charging device that charges a surface of the electrophotographic photoreceptor, an electrostatic latent image forming device that forms an electrostatic latent image on the charged surface of the electrophotographic photoreceptor, a developing device that develops the electrostatic latent image formed on the surface of the electrophotographic photoreceptor with a developer containing a toner to form a toner image, and a transfer device that transfers the toner image to a surface of a recording medium, in which a moving time of an outer peripheral surface of the electrophotographic photoreceptor, required from charging performed by the charging device to development performed by the developing device, is 90 msec or longer,
0.20E.sub.F1E.sub.LUMO10.60Expression 1-1:
(in Expression 1-1, E.sub.F1 represents a Fermi level of the undercoat layer, and E.sub.LUMO1 represents an energy level of LUMO of the undercoat layer).
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, AND ELECTROPHOTOGRAPHIC APPARATUS
Provided is an electrophotographic photosensitive member including: a support; and a photosensitive layer. The photosensitive layer contains a binder resin, a charge generating material, an electron transporting material, and a hole transporting material. The binder resin contains a polyarylate resin having a particular structural unit. The hole transporting material contains a particular compound.
Electrophotographic photoreceptor, process cartridge, and image forming apparatus
An electrophotographic photoreceptor includes a conductive support; and an undercoat layer and a photosensitive layer stacked on the conductive support, in which the undercoat layer contains crystalline electron transport compound particles. In X-ray diffraction measurement performed on the undercoat layer in a thickness direction, a maximum intensity peak has a half-width of 5 or less, and a maximum value Nmax among orientation indices N expressed by equation (1) below is 1 or more and 3 or less: