G03G5/06147

ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER AND IMAGE FORMING APPARATUS

An electrophotographic photosensitive member (1) includes a conductive substrate (2) and a photosensitive layer (3) disposed directly or indirectly on the conductive substrate (2). The photosensitive layer (3) has a charge generating layer (3a) and a charge transport layer (3b) disposed in order from the conductive substrate (2). The charge generating layer (3a) contains a charge generating material. The charge transport layer (3b) contains a charge transport material, a binder resin, and a pigment that absorbs light having an irradiation wavelength. The binder resin includes a polyarylate resin including a repeating unit represented by general formula (1):

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In general formula (1), X and Y each represent, independently of one another, a divalent group represented by chemical formula (1-1). (1-2), (1-3), or (1-4):

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The pigment is a naphthalocyanine compound represented by general formula (2) or (3):

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PHOTOSENSITIVE BODY FOR ELECTROPHOTOGRAPHY, METHOD FOR PRODUCING THE SAME, AND ELECTROPHOTOGRAPHIC DEVICE INCLUDING THE SAME

The present invention provides an electrophotographic photoreceptor including a photosensitive layer containing an electron transport material, and having high pressure resistance and suppressed occurrence of a leak phenomenon, a method for producing the same, and an electrophotographic device using the same. The electrophotographic photoreceptor includes an electrically conductive support containing an aluminum alloy; an anodic oxide film formed on a surface of the electrically conductive support; and a photosensitive layer formed on the anodic oxide film. The photosensitive layer contains an electron transport material having an electron mobility of 10.sup.7 cm.sup.2/V/sec or more when field intensity is set to 20 V/m. The surface of the electrically conductive support having the anodic oxide film formed thereon has an admittance value that is 25 S or more and 60 S or less.

POSITIVE CHARGING ELECTROPHOTOGRAPHIC PHOTORECEPTOR, ELECTROPHOTOGRAPHIC CARTRIDGE AND IMAGE FORMING APPARATUS
20190384189 · 2019-12-19 · ·

The object of the present invention is to provide a positive charging electrophotographic photoreceptor having high sensitivity, low residual potential, and excellent chargeability, and relates to a positive charging electrophotographic photoreceptor including a conductive support, a photosensitive layer, and a protective layer in this order, the photosensitive layer containing a charge generation substance, a positive hole transport substance, and an electron transport substance in the same layer, in which the positive hole transport substance includes at least one of the compounds represented by any one of the following formulas (1) to (5), and a binder resin of the protective layer is an alcohol-soluble thermoplastic resin, providing that the symbols in the formula are defined in the specification.

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Polyarylate resin and electrophotographic photosensitive member
10509309 · 2019-12-17 · ·

A polyarylate resin is represented by general formula (1) shown below. In general formula (1), R.sup.1 represents a hydrogen atom or methyl group. R.sup.2 and R.sup.3 each represent a hydrogen atom or an alkyl group having a carbon number of at least 1 and no greater than 4. R.sup.2 and R.sup.3 are not the same as one another. When R.sup.1 represents a hydrogen atom, R.sup.2 and R.sup.3 are not bonded to one another. When R.sup.1 represents a methyl group, R.sup.2 and R.sup.3 are optionally bonded to one another to form a ring. r and s each represent a number greater than or equal to 0 and less than or equal to 49. t and u each represent a number greater than or equal to 1 and less than or equal to 50. r+s+t+u=100. r+t=s+u. ##STR00001##

Electrophotographic photosensitive member, process cartridge, and image forming apparatus
10509337 · 2019-12-17 · ·

An electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer having a single-layer structure. The photosensitive layer contains a charge generating material, an electron transport material, a polycarbonate resin, and a hole transport material. The electron transport material includes a compound having a halogen atom and represented by general formula (1), (2), (3), (4), or (5). The hole transport material includes a compound represented by general formula (20), (21), (22), (23), (24), (25), (26), or (27). A charge of calcium carbonate as measured by charging the calcium carbonate through friction with the photosensitive layer is at least +6.5 C/g. A Vickers hardness of the photosensitive layer at 45 C. is at least 17.0 HV. ##STR00001## ##STR00002## ##STR00003##

ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER AND METHOD FOR PRODUCING ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER

A method for producing an electrophotographic photosensitive member having a photosensitive layer and a protective layer above a support in this order includes: forming a coating film for a protective layer by coating a coating liquid for the protective layer for forming the protective layer on the photosensitive layer and curing the coating film for the protective layer, in which the coating liquid for the protective layer contains a solvent, a compound represented by a general formula (1), a compound represented by a general formula (2), and a compound represented by a general formula (3) at a specific ratio. In addition, in an electrophotographic photosensitive member having a photosensitive layer and a protective layer above a support in this order, the protective layer is obtained by curing a coating liquid for the protective layer.

Image forming apparatus having an irradiator irradiating a photoconductor

An image forming apparatus includes: a transferer that transfers a toner image formed on a surface of a photo-conductor onto an image carrier; and an irradiator that irradiates the surface of the photo-conductor before transfer with light such that a potential of an image area where the toner image has been formed and a potential of a non-image area where the toner image has not been formed in the photo-conductor before transfer satisfy formula (1):
0|Va||Vb|200 [V](1) where |Va| represents the potential of the image area after the surface of the photo-conductor before transfer is irradiated with light, and |Vb| represents the potential of the non-image area after the surface of the photo-conductor before transfer is irradiated with light.

PRODUCTION METHOD FOR ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER

A method for producing an electrophotographic photosensitive member includes an electrically conductive substrate and a photosensitive layer. The method includes applying an application liquid for photosensitive layer formation containing a solvent, a binder resin, and a hole transport material directly or indirectly onto the electrically conductive substrate, and removing a portion of the solvent, to form the photosensitive layer. The solvent contains a first solvent that is an alcohol having a carbon number of at least 1 and no greater than 3, and a second solvent other than the first solvent. The binder resin includes a polyarylate resin that is a polymerization product of monomers including a first monomer represented by general formula (1) and a second monomer represented by general formula (2),

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ELECTROPHOTOGRAPHIC PHOTORECEPTOR, ELECTROPHOTOGRAPHIC PHOTORECEPTOR CARTRIDGE AND IMAGE FORMING APPARATUS

An object of the present invention is to provide an electrophotographic photoreceptor which can prevent an increase in potential even using a fluorine resin in a charge transport layer, and can achieve both electrical properties and abrasion resistance, and present invention relates to a lamination type electrophotographic photoreceptor, in which a charge transport layer of the lamination type electrophotographic photoreceptor contains a compound having an E_homo of 4.550 eV or more based on structure optimization calculation by density functional calculation B3LYP/6-31G (d, p) and fluorine resin particles, and a content of the fluorine resin particles is 3% by weight to 20% by weight based on a total mass of the charge transport layer.

ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS

A photosensitive member (1) includes a conductive substrate (2) and a photosensitive layer (3). The photosensitive layer is a single-layer photosensitive layer (3c). The photosensitive layer contains a charge generating material, a hole transport material, an electron transport material, and a binder resin. The hole transport material includes a triphenylamine derivative represented by general formula (HT). The electron transport material includes a compound represented by general formula (ET1), (ET2), (ET3), (ET4), or (ET5). The binder resin includes a polyarylate resin represented by general formula (1)

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